Nano-porous alloys with strong permanent magnetism and preparation method therefor
A kind of nano-porous Fe-Pt alloys with strong permanent magnetism and a preparation method therefor. The nano-porous Fe-Pt alloys have the composition of FewCoxPtyPdz and are composed of an ordered hard magnetic L10-FePt phase, and have an integrated doubly-connected nano-porous structure with pore...
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Zusammenfassung: | A kind of nano-porous Fe-Pt alloys with strong permanent magnetism and a preparation method therefor. The nano-porous Fe-Pt alloys have the composition of FewCoxPtyPdz and are composed of an ordered hard magnetic L10-FePt phase, and have an integrated doubly-connected nano-porous structure with pore sizes of 10-50 nm, and ligament thicknesses of 20-80 nm. Under an applied magnetic field of 50 kOe, the coercivity, magnetization intensity and remanence of the alloys are 13.4-18.5 kOe, 40.4-56.3 emu/g and 28.3-37.4 emu/g, respectively. The master alloy ingots are prepared using electric arc melting or induction melting; the alloy ribbons are prepared using the single-roller melt-spinning equipment; the precursors mainly containing nano-composite phases of hard magnetic L10-FePt and soft magnetic Fe2B are obtained directly by the melt-spinning or obtained by conducting vacuum annealing on the melt-spun ribbons; and the nano-porous Fe-Pt alloys with a single L10-FePt phase are obtained by the electrochemical dealloying technique, thereby filling in the technical blank of nano-porous metal materials with permanent magnetism. |
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