Polymeric ionomer separation membranes and methods of use

A separation membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., a first liquid) from a mixture comprising the first fluid (e.g., first liquid) and a second fluid (e.g., second liquid), wherein the separation membrane includes a polymeric ionomer that has a highly fluorina...

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Hauptverfasser: Hanson, Eric J, David, Moses M, Yandrasits, Michael A, Zhou, Jinsheng, Funkenbusch, Eric F, Shirk, Ryan C, Seitz, David S, Mizuno, Kazuhiko
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creator Hanson, Eric J
David, Moses M
Yandrasits, Michael A
Zhou, Jinsheng
Funkenbusch, Eric F
Shirk, Ryan C
Seitz, David S
Mizuno, Kazuhiko
description A separation membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., a first liquid) from a mixture comprising the first fluid (e.g., first liquid) and a second fluid (e.g., second liquid), wherein the separation membrane includes a polymeric ionomer that has a highly fluorinated backbone and recurring pendant groups according to the following formula (Formula I): -O-Rf-[-SO2-N−(Z+)-SO2-R-]m-[SO2]n-Q wherein: Rf is a perfluorinated organic linking group; R is an organic linking group; Z+ is H+, a monovalent cation, or a multivalent cation; Q is H, F, -NH2, -NH2, -O−Y+, or -CxF2x+1; Y+ is H+, a monovalent cation, or a multivalent cation; x=1 to 4; m=0 to 6; and n=0 or 1; with the proviso that at least one of morn must be non-zero.
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subjects BLASTING
COMBUSTION ENGINES
CONTROLLING COMBUSTION ENGINES
HEATING
HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
LIGHTING
MECHANICAL ENGINEERING
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
SUPPLYING COMBUSTION ENGINES IN GENERAL, WITH COMBUSTIBLEMIXTURES OR CONSTITUENTS THEREOF
TRANSPORTING
WEAPONS
title Polymeric ionomer separation membranes and methods of use
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