Process for removing heavy metals from hydrocarbons
This invention provides a process for removing mercury, from a mercury-containing hydrocarbon fluid. More specifically, the invention relates to a process for the removal of mercury from a mercury-containing hydrocarbon fluid feed comprising the steps of: (i) contacting the mercury-containing hydroc...
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creator | Kuah, Yong Cheun Holbrey, John David Atkins, Martin Philip |
description | This invention provides a process for removing mercury, from a mercury-containing hydrocarbon fluid. More specifically, the invention relates to a process for the removal of mercury from a mercury-containing hydrocarbon fluid feed comprising the steps of: (i) contacting the mercury-containing hydrocarbon fluid feed with a metal perhalide having the following formula: [M]+[X]− wherein: [M]+ represents one or more metal cations wherein the metal has an atomic number greater than 36; an atomic radius of at least 50 pm and a 1st ionization energy of less than 750 kJmol−1; [X]− represents one or more perhalide anions; and (ii) obtaining a hydrocarbon fluid product having a reduced mercury content compared to mercury-containing hydrocarbon fluid feed. |
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More specifically, the invention relates to a process for the removal of mercury from a mercury-containing hydrocarbon fluid feed comprising the steps of: (i) contacting the mercury-containing hydrocarbon fluid feed with a metal perhalide having the following formula: [M]+[X]− wherein: [M]+ represents one or more metal cations wherein the metal has an atomic number greater than 36; an atomic radius of at least 50 pm and a 1st ionization energy of less than 750 kJmol−1; [X]− represents one or more perhalide anions; and (ii) obtaining a hydrocarbon fluid product having a reduced mercury content compared to mercury-containing hydrocarbon fluid feed.</description><language>eng</language><subject>CHEMISTRY ; CRACKING HYDROCARBON OILS ; FUELS ; LUBRICANTS ; METALLURGY ; MINERAL WAXES ; PEAT ; PERFORMING OPERATIONS ; PETROLEUM, GAS OR COKE INDUSTRIES ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION ; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES ; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS ; REFORMING OF NAPHTHA ; SEPARATION ; TECHNICAL GASES CONTAINING CARBON MONOXIDE ; TRANSPORTING</subject><creationdate>2020</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20200324&DB=EPODOC&CC=US&NR=10597587B2$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20200324&DB=EPODOC&CC=US&NR=10597587B2$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Kuah, Yong Cheun</creatorcontrib><creatorcontrib>Holbrey, John David</creatorcontrib><creatorcontrib>Atkins, Martin Philip</creatorcontrib><title>Process for removing heavy metals from hydrocarbons</title><description>This invention provides a process for removing mercury, from a mercury-containing hydrocarbon fluid. More specifically, the invention relates to a process for the removal of mercury from a mercury-containing hydrocarbon fluid feed comprising the steps of: (i) contacting the mercury-containing hydrocarbon fluid feed with a metal perhalide having the following formula: [M]+[X]− wherein: [M]+ represents one or more metal cations wherein the metal has an atomic number greater than 36; an atomic radius of at least 50 pm and a 1st ionization energy of less than 750 kJmol−1; [X]− represents one or more perhalide anions; and (ii) obtaining a hydrocarbon fluid product having a reduced mercury content compared to mercury-containing hydrocarbon fluid feed.</description><subject>CHEMISTRY</subject><subject>CRACKING HYDROCARBON OILS</subject><subject>FUELS</subject><subject>LUBRICANTS</subject><subject>METALLURGY</subject><subject>MINERAL WAXES</subject><subject>PEAT</subject><subject>PERFORMING OPERATIONS</subject><subject>PETROLEUM, GAS OR COKE INDUSTRIES</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</subject><subject>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</subject><subject>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</subject><subject>REFORMING OF NAPHTHA</subject><subject>SEPARATION</subject><subject>TECHNICAL GASES CONTAINING CARBON MONOXIDE</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2020</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZDAOKMpPTi0uVkjLL1IoSs3NL8vMS1fISE0sq1TITS1JzAHKFOXnKmRUpgAVJhYl5ecV8zCwpgElUnmhNDeDoptriLOHbmpBfnxqcUFicmpeakl8aLChgamluamFuZORMTFqACvkLRQ</recordid><startdate>20200324</startdate><enddate>20200324</enddate><creator>Kuah, Yong Cheun</creator><creator>Holbrey, John David</creator><creator>Atkins, Martin Philip</creator><scope>EVB</scope></search><sort><creationdate>20200324</creationdate><title>Process for removing heavy metals from hydrocarbons</title><author>Kuah, Yong Cheun ; Holbrey, John David ; Atkins, Martin Philip</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US10597587B23</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2020</creationdate><topic>CHEMISTRY</topic><topic>CRACKING HYDROCARBON OILS</topic><topic>FUELS</topic><topic>LUBRICANTS</topic><topic>METALLURGY</topic><topic>MINERAL WAXES</topic><topic>PEAT</topic><topic>PERFORMING OPERATIONS</topic><topic>PETROLEUM, GAS OR COKE INDUSTRIES</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</topic><topic>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</topic><topic>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</topic><topic>REFORMING OF NAPHTHA</topic><topic>SEPARATION</topic><topic>TECHNICAL GASES CONTAINING CARBON MONOXIDE</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>Kuah, Yong Cheun</creatorcontrib><creatorcontrib>Holbrey, John David</creatorcontrib><creatorcontrib>Atkins, Martin Philip</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Kuah, Yong Cheun</au><au>Holbrey, John David</au><au>Atkins, Martin Philip</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Process for removing heavy metals from hydrocarbons</title><date>2020-03-24</date><risdate>2020</risdate><abstract>This invention provides a process for removing mercury, from a mercury-containing hydrocarbon fluid. More specifically, the invention relates to a process for the removal of mercury from a mercury-containing hydrocarbon fluid feed comprising the steps of: (i) contacting the mercury-containing hydrocarbon fluid feed with a metal perhalide having the following formula: [M]+[X]− wherein: [M]+ represents one or more metal cations wherein the metal has an atomic number greater than 36; an atomic radius of at least 50 pm and a 1st ionization energy of less than 750 kJmol−1; [X]− represents one or more perhalide anions; and (ii) obtaining a hydrocarbon fluid product having a reduced mercury content compared to mercury-containing hydrocarbon fluid feed.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | CHEMISTRY CRACKING HYDROCARBON OILS FUELS LUBRICANTS METALLURGY MINERAL WAXES PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA SEPARATION TECHNICAL GASES CONTAINING CARBON MONOXIDE TRANSPORTING |
title | Process for removing heavy metals from hydrocarbons |
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