Polymerization initiating system and method to produce highly reactive olefin functional polymers

A method for producing highly reactive olefin polymers wherein at least 50 mol. % of the polymer chains have terminal double bonds, from an impurity-containing isobutylene or a mixed C4 hydrocarbyl feedstock containing isobutylene in which the water content of the feedstock is controlled to be at le...

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Hauptverfasser: Weber, Jeremy, Emert, Jacob, Skourlis, Thomas, Faust, Rudolf, Severt, Richard J, Dimitrov, Philip
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creator Weber, Jeremy
Emert, Jacob
Skourlis, Thomas
Faust, Rudolf
Severt, Richard J
Dimitrov, Philip
description A method for producing highly reactive olefin polymers wherein at least 50 mol. % of the polymer chains have terminal double bonds, from an impurity-containing isobutylene or a mixed C4 hydrocarbyl feedstock containing isobutylene in which the water content of the feedstock is controlled to be at least equal to the content of polar impurities in the feedstock, and less than the concentration at which the water causes a decrease in vinylidene end-group selectivity.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Polymerization initiating system and method to produce highly reactive olefin functional polymers
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