Production and use of polyester carbonates
A transesterification process for producing polyester is disclosed. In a first stage of the process there is heated, in an inert gas atmosphere, a first mixture containing at least one dihydroxy compound and at least one diaryl carbonate to form an oligocondensate. In a second stage there is added t...
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creator | ALEWELT, WOLFGANG BUNZEL, LOTHAR KRATSCHMER, SILKE WILMS, RENATE |
description | A transesterification process for producing polyester is disclosed. In a first stage of the process there is heated, in an inert gas atmosphere, a first mixture containing at least one dihydroxy compound and at least one diaryl carbonate to form an oligocondensate. In a second stage there is added to the oligocondensate at least one dicarboxylic acid to form a second mixture. The second mixture is heated to a temperature not higher than 290 DEG C in the presence of a quaternary onium compound as catalyst to form polyester carbonate. Hydroxyaryl formed throughout the process is distilled-off under reduced pressure. |
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In a first stage of the process there is heated, in an inert gas atmosphere, a first mixture containing at least one dihydroxy compound and at least one diaryl carbonate to form an oligocondensate. In a second stage there is added to the oligocondensate at least one dicarboxylic acid to form a second mixture. The second mixture is heated to a temperature not higher than 290 DEG C in the presence of a quaternary onium compound as catalyst to form polyester carbonate. 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subjects | AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G CHEMISTRY COMPOSITIONS BASED THEREON GENERAL PROCESSES OF COMPOUNDING MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP WORKING-UP |
title | Production and use of polyester carbonates |
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