Method for the preparation of styrenic fluoropolymers

Method for the preparation of styrenic fluoropolymers

A method for the preparation of a fluoropolymer by means of emulsion polymerization of areaction mixture in an aqueous medium is disclosed wherein the reaction mixture includes a fluoromonomer having the structure of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substit...

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Hauptverfasser: WANG, BIN, ZHANG, DONG, GERMROTH, TED C, KUO, THAUMING, JING, JIAO-KAI, MCWILLIAMS, DOUGLAS S, HARRIS, FRANK W, ZHENG, XIAO-LIANG
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Sprache:chi ; eng
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CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
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creator WANG, BIN
ZHANG, DONG
GERMROTH, TED C
KUO, THAUMING
JING, JIAO-KAI
MCWILLIAMS, DOUGLAS S
HARRIS, FRANK W
ZHENG, XIAO-LIANG
description A method for the preparation of a fluoropolymer by means of emulsion polymerization of areaction mixture in an aqueous medium is disclosed wherein the reaction mixture includes a fluoromonomer having the structure of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring; (b) an emulsion stabilizer combination comprising: (i) an anionic surfactant; and, (ii)a cationic surfactant or a non-ionic surfactant; and, (c) a free-radical initiator.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Method for the preparation of styrenic fluoropolymers
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