HIGH-STRENGTH WATERPROOF ORGANOCOMPOSITE AND PREPARATION METHOD THEREOF

FIELD: manufacturing technology.SUBSTANCE: invention relates to production of light-weight high-strength water-resistant organocomposites based on fibrous fillers of ultrahigh molecular weight polyethylene (UHMWPE) and polymer binder and can be used in elements of structures in various engineering f...

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Hauptverfasser:	Natrusov Vladimir Ivanovich, Trofimov Aleksandr Nikolaevich, Kuznetsov Aleksej Aleksandrovich, Kosolapov Aleksej Fedorovich, Kolesnikov Artem Vladimirovich, Osipchik Vladimir Semenovich, Demikhov Sergej Viktorovich, Vetokhin Sergej JUrevich, SHkurenko Svetlana Ivanovna, Gilman Alla Borisovna, Egorov Aleksandr Ivanovich, Bajdakov Boris Vladimirovich, SHatskaja Tatjana Evgenevna, Galitsyn Vladimir Petrovich, Beljaeva Evgenija Alekseevna, KHarchenko Evgenij Fedorovich, ZHuravlev Nikolaj JUrevich
Format:	Patent
Sprache:	eng ; rus
Schlagworte:	AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR GENERAL PROCESSES OF COMPOUNDING LAUNDERING MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS MANUFACTURE OR TREATMENT OF NANOSTRUCTURES MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES METALLURGY NANOTECHNOLOGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES TEXTILES THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING TREATMENT OF TEXTILES OR THE LIKE TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS WORKING-UP
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Zusammenfassung:	FIELD: manufacturing technology.SUBSTANCE: invention relates to production of light-weight high-strength water-resistant organocomposites based on fibrous fillers of ultrahigh molecular weight polyethylene (UHMWPE) and polymer binder and can be used in elements of structures in various engineering fields: aviation, machine-shipbuilding, chemical and defense, etc. Disclosed is a high-strength waterproof organocomposite made of fibrous filler based on high-strength high-modulus multi-filament polyethylene fibres and polymer binder based on epoxy resin with amine curing agent. Surface of filler is pretreated in barrier discharge plasma with impact of pulse barrier discharge in air at atmospheric pressure when exposed to alternating voltage with frequency of 10-50 kHz, with specific power of discharge of 50-500 W/m, at rate of treatment of 0.3-7 m/min. Method then comprises treatment with acetone of a solution suspensions metal-containing nanostructures in carbon-polymer media. Filler is then dried, impregnated with polymer binder prepared by mechanical mixing of components, and organic composite is moulded with hardening temperature not higher than 75 °C. As epoxy resin of polymer binder, organocomposite contains a mixture of epoxy-diane (A) and epoxy-aliphatic (B) oligomers in ratio A:B from 10:1.3 to 10:3. As amine curing agent - eutectic mixture of metaphenylenediamine (MPDA) and 4,4′-diaminodiphenylmethane (4,4′-DADPM) at following weight ratio from 22:78 to 78:22; and additionally contains a mixture of oligoester-cyclocarbonates, urethane prepolymer. Ratio of components in organocomposite, pts.wt: fibre filler - 250-700; epoxy-diane oligomer (A) - 100; epoxy-aliphatic oligomer (B) - 13-30; mixture of oligoester-cyclocarbonates - 10-20; urethane prepolymer - 5-25; eutectic mixture MPDA + 4,4′-DADPM - 28-45.EFFECT: invention improves physical and mechanical properties and water resistance of organic composite while providing environmental friendliness and simple process during implementation of industrial production.7 cl, 1 dwg, 3 tbl, 6 ex Изобретение относится к области создания легких высокопрочных водостойких органокомпозитов на основе волокнистых наполнителей из сверхвысокомолекулярного полиэтилена (СВМПЭ) и полимерного связующего и может быть использовано в элементах конструкций в различных областях техники: авиационной, машино-судостроительной, химической, оборонной и др.Предлагается высокопрочный водостойкий органокомпозит, выполненный из волокнист