METHOD OF PHENOL ALLYLATION

FIELD: chemistry. ^ SUBSTANCE: method of allylation of phenols, which have one hydrogen atom in ortho-position with respect to hydroxyl group, is carried out with terpene allyl alcohol with heating in presence of catalyst. As catalyst of alkylation process organo-aluminium compounds, selected from g...

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Hauptverfasser:	TIMUSHEVA IRINA VITAL'EVNA, CHUKICHEVA IRINA JUR'EVNA, KOROLEVA ALLA AL'BERTOVNA, KUCHIN ALEKSANDR VASIL'EVICH
Format:	Patent
Sprache:	eng ; rus
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMISTRY METALLURGY ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:	FIELD: chemistry. ^ SUBSTANCE: method of allylation of phenols, which have one hydrogen atom in ortho-position with respect to hydroxyl group, is carried out with terpene allyl alcohol with heating in presence of catalyst. As catalyst of alkylation process organo-aluminium compounds, selected from group of alkoxides of aluminium of asymmetric (mixed) or symmetric (full) type, are used, molar ratio of phenol to alcohol being 1:1. Obtained prenylphenols are widely used as physiologically acive substances. ^ EFFECT: obtaining prenylated phenols with high yield and content of ortho-prenylphenols. ^ 3 cl, 5 ex