PETROLEUM FRACTION HYDROFINING PROCESS

FIELD: petroleum processing. ^ SUBSTANCE: invention, in particular, relates to petroleum fraction hydrofining process utilizing presulfided catalysts. Hydrofining process is described involving contacting petroleum fractions with presulfided catalyst containing alumina-carried cobalt, molybdenum, ph...

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Hauptverfasser: REZNICHENKO IRINA DMITRIEVNA, ALIEV RAMIZ RZA OGLY, ELSHIN ANATOLIJ IVANOVICH, KUKS IGOR' VITAL'EVICH, KRJACHEK SERGEJ LAVRENT'EVICH, KASTERIN VLADIMIR NIKOLAEVICH, TROFIMOVA MARINA VITAL'EVNA, TSELJUTINA MARINA IVANOVNA
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creator REZNICHENKO IRINA DMITRIEVNA
ALIEV RAMIZ RZA OGLY
ELSHIN ANATOLIJ IVANOVICH
KUKS IGOR' VITAL'EVICH
KRJACHEK SERGEJ LAVRENT'EVICH
KASTERIN VLADIMIR NIKOLAEVICH
TROFIMOVA MARINA VITAL'EVNA
TSELJUTINA MARINA IVANOVNA
description FIELD: petroleum processing. ^ SUBSTANCE: invention, in particular, relates to petroleum fraction hydrofining process utilizing presulfided catalysts. Hydrofining process is described involving contacting petroleum fractions with presulfided catalyst containing alumina-carried cobalt, molybdenum, phosphorus, and boron, said process being conducted at 320-340°C, pressure 3.0-5.0 MPa, volumetric feed supply rate 1.0-6.0 h-1, normalized volumetric hydrogen-containing gas-to-feed ratio (500-1000):1 in presence of catalyst sulfided outside of reactor. Sulfidizing of catalyst is accomplished with hydrogen sulfide at 80-500°C and volumetric hydrogen sulfide flow rate 0.02-6.0 h-1. Chemical composition of catalyst is the following, wt %: MoS2 8.0-17.0, Co3S2 1.5-4.0, P2O3 2.5-5.0, B2O3 0.3-1.0, La2O3 1.0-5.0, and aluminum oxide - the balance. ^ EFFECT: simplified process. ^ 2 cl, 1 tbl, 3 ex
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Hydrofining process is described involving contacting petroleum fractions with presulfided catalyst containing alumina-carried cobalt, molybdenum, phosphorus, and boron, said process being conducted at 320-340°C, pressure 3.0-5.0 MPa, volumetric feed supply rate 1.0-6.0 h-1, normalized volumetric hydrogen-containing gas-to-feed ratio (500-1000):1 in presence of catalyst sulfided outside of reactor. Sulfidizing of catalyst is accomplished with hydrogen sulfide at 80-500°C and volumetric hydrogen sulfide flow rate 0.02-6.0 h-1. Chemical composition of catalyst is the following, wt %: MoS2 8.0-17.0, Co3S2 1.5-4.0, P2O3 2.5-5.0, B2O3 0.3-1.0, La2O3 1.0-5.0, and aluminum oxide - the balance. ^ EFFECT: simplified process. ^ 2 cl, 1 tbl, 3 ex</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
CRACKING HYDROCARBON OILS
FUELS
LUBRICANTS
METALLURGY
MINERAL WAXES
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR RELEVANT APPARATUS
TRANSPORTING
title PETROLEUM FRACTION HYDROFINING PROCESS
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