INTEGRATED SERPENTINITE PROCESSING METHOD RESULTING IN PURE SILICA PRODUCTION

FIELD: industrial inorganic synthesis. ^ SUBSTANCE: invention comprises processing of serpentinite to produce following commercial products: pure silica, magnesium compounds, including magnesium chloride, magnesium metal, carnallite, iron- and nickel-containing concentrates. Serpentinite is leached...

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Hauptverfasser: FREJDLINA R.G, GULJAKIN A.I, TETERIN V.V, KOZLOV JU.A, KOCHELAEV V.A, SHCHELKONOGOV A.A, JAKOVLEVA S.A, SHIROKOV JU.I, SABUROV L.N
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creator FREJDLINA R.G
GULJAKIN A.I
TETERIN V.V
KOZLOV JU.A
KOCHELAEV V.A
SHCHELKONOGOV A.A
JAKOVLEVA S.A
SHIROKOV JU.I
SABUROV L.N
description FIELD: industrial inorganic synthesis. ^ SUBSTANCE: invention comprises processing of serpentinite to produce following commercial products: pure silica, magnesium compounds, including magnesium chloride, magnesium metal, carnallite, iron- and nickel-containing concentrates. Serpentinite is leached with hydrochloric acid solution containing 10-21% HCl at 60-100 and liquid-to-solids ratio (3-10):1 for 2 to 6 h under discontinuous or continuous countercurrent conditions to yield magnesium chloride solution and silica. The former is purified via two-step neutralization: first with brucite or caustic magnesite at 80-90 to pH 3.5-4.0 and then with sodium hydroxide solution to pH 6-7 including addition of sodium sulfide or hydrosulfide. ^ EFFECT: increased purity of silica product and enlarged number of commercial products and/or semiproducts. ^ 4 cl
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subjects CHEMISTRY
COMPOUNDS THEREOF
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
title INTEGRATED SERPENTINITE PROCESSING METHOD RESULTING IN PURE SILICA PRODUCTION
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