TERT-BUTYLACETONE PRODUCTION PROCESS
FIELD: industrial organic synthesis. ^ SUBSTANCE: tert-butylacetone is prepared by cleavage of hydrochloric acid from pinacolin-phosphorus pentachloride reaction products obtained in presence of alkali metal alcoholate. Reaction is conducted in high-boiling indifferent solvent, in particular hydroca...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Patent |
| Sprache: | eng ; rus |
| Schlagworte: | |
| Online-Zugang: | Volltext bestellen |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | FIELD: industrial organic synthesis. ^ SUBSTANCE: tert-butylacetone is prepared by cleavage of hydrochloric acid from pinacolin-phosphorus pentachloride reaction products obtained in presence of alkali metal alcoholate. Reaction is conducted in high-boiling indifferent solvent, in particular hydrocarbons boiling above 120. Alcoholates can be selected from sodium and potassium butylate and amylate (with linear and branched structures). ^ EFFECT: increased yield of desired product, simplified process, and widened base of starting material including such an inexpensive reagent as phosphorus trichloride. ^ 5 cl, 4 ex |
|---|