PHENYLACETIC ACID DERIVATIVES, THEIR INTERMEDIATES, AND AGENTS CONTAINING THEREOF

organic synthesis. SUBSTANCE: invention provides novel phenylacetic acid derivatives of general formula I: (I), in which X denotes NOCH3, CHOCH3 and CHCH2CH3; R1 hydrogen or C1-C4-alkyl; R2 halogen, C1-C4-alkyl, or C1- C4-alkoxy; m= 0 or 1; R3 denotes hydrogen, amino, halogen, C1-C4-alkyl, C1- C4-ha...

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Hauptverfasser: VASSILIOS GRAMMENOS, RAJNKHARD KIRSTGEN, AL'BREKHT KHARREUS, GERBERT BAJER, GIZELA LORENTS, EHBERKHARD AMMERMANN, KHUBERT ZAUTER, FRANTS REL, RUT MJULLER
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creator VASSILIOS GRAMMENOS
RAJNKHARD KIRSTGEN
AL'BREKHT KHARREUS
GERBERT BAJER
GIZELA LORENTS
EHBERKHARD AMMERMANN
KHUBERT ZAUTER
FRANTS REL
RUT MJULLER
description organic synthesis. SUBSTANCE: invention provides novel phenylacetic acid derivatives of general formula I: (I), in which X denotes NOCH3, CHOCH3 and CHCH2CH3; R1 hydrogen or C1-C4-alkyl; R2 halogen, C1-C4-alkyl, or C1- C4-alkoxy; m= 0 or 1; R3 denotes hydrogen, amino, halogen, C1-C4-alkyl, C1- C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-alkylamino, or di- C1- C4-alkylamino; R4 cyano, halogen, C1-C6-alkyl, C1-C6-alkoxy, C2-C6- alkenyl, C2-C6-alkenyloxy, or C2-C6-alkinyl; provided that hydrocarbon moieties of above-indicated groups can be partially or completely halogenated or can bear one to three substituents selected from cyano, C1- C6-alkoxy, C1-C6-alkoxycarbonyl, phenyl, and dioxan (cyclic radicals can be partially or completely halogenated), C3-C6-cycloalkyl, C3-C6-cycloalkenyl, aryl, isoxazolyl, pyridyl, dioxolanyl, benzoxazolyl, thienyl, oxazolyl, furyl, oxyranyl, pyrazolyl, thiazolyl, pyrimidyloxy or tetrahydropyranyl, provided that cyclic radicals can be partially or completely halogenated or can bear one to three substituents selected from nitro, C1-C6-alkyl, C1-C6- alkoxy, C1-C6-haloalkyl, C1-C6-alkylamino, di-C1-C6-alkylamino and aryl; R5 denotes hydrogen, C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkinyl, provided that these radicals can be partially or completely halogenated or can bear one to three substituents selected from cyano, hydroxy, aminocarbonyl, C1-C6-alkyl, C2-C6-alkenyl, C1-C6-alkoxycarbonyl, C1-C6- alkylamino, benzyl, aryl, aryloxy, thienyl, pyrrolyl, oxazolyl, furyl, thiazolyl, oxadiazolyl, and isoxazolyl, cyclic radicals themselves can be partially or completely halogenated or can bear one to three substituents selected from nitro, hydroxy, C1-C4-alkyl, C1-C4-haloakyl, and C3-C6- cycloalkyl; on condition that X cannot be NOCH3 and CHOCH3, when R4 is unsubstituted C1-C4-alkyl, unsubstituted C3-C6-cycloalkyl, substituted or unsubstituted phenyl, or unsubstituted thienyl; or X cannot be CHOCH3, when R3 is hydrogen and R5 is C1-C10-alkyl; as well as salts or above-indicated compounds. Compound I show fungicidal activity. EFFECT: extended choice of active fungicides. 8 cl, 16 tbl, 10 ex
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SUBSTANCE: invention provides novel phenylacetic acid derivatives of general formula I: (I), in which X denotes NOCH3, CHOCH3 and CHCH2CH3; R1 hydrogen or C1-C4-alkyl; R2 halogen, C1-C4-alkyl, or C1- C4-alkoxy; m= 0 or 1; R3 denotes hydrogen, amino, halogen, C1-C4-alkyl, C1- C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-alkylamino, or di- C1- C4-alkylamino; R4 cyano, halogen, C1-C6-alkyl, C1-C6-alkoxy, C2-C6- alkenyl, C2-C6-alkenyloxy, or C2-C6-alkinyl; provided that hydrocarbon moieties of above-indicated groups can be partially or completely halogenated or can bear one to three substituents selected from cyano, C1- C6-alkoxy, C1-C6-alkoxycarbonyl, phenyl, and dioxan (cyclic radicals can be partially or completely halogenated), C3-C6-cycloalkyl, C3-C6-cycloalkenyl, aryl, isoxazolyl, pyridyl, dioxolanyl, benzoxazolyl, thienyl, oxazolyl, furyl, oxyranyl, pyrazolyl, thiazolyl, pyrimidyloxy or tetrahydropyranyl, provided that cyclic radicals can be partially or completely halogenated or can bear one to three substituents selected from nitro, C1-C6-alkyl, C1-C6- alkoxy, C1-C6-haloalkyl, C1-C6-alkylamino, di-C1-C6-alkylamino and aryl; R5 denotes hydrogen, C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkinyl, provided that these radicals can be partially or completely halogenated or can bear one to three substituents selected from cyano, hydroxy, aminocarbonyl, C1-C6-alkyl, C2-C6-alkenyl, C1-C6-alkoxycarbonyl, C1-C6- alkylamino, benzyl, aryl, aryloxy, thienyl, pyrrolyl, oxazolyl, furyl, thiazolyl, oxadiazolyl, and isoxazolyl, cyclic radicals themselves can be partially or completely halogenated or can bear one to three substituents selected from nitro, hydroxy, C1-C4-alkyl, C1-C4-haloakyl, and C3-C6- cycloalkyl; on condition that X cannot be NOCH3 and CHOCH3, when R4 is unsubstituted C1-C4-alkyl, unsubstituted C3-C6-cycloalkyl, substituted or unsubstituted phenyl, or unsubstituted thienyl; or X cannot be CHOCH3, when R3 is hydrogen and R5 is C1-C10-alkyl; as well as salts or above-indicated compounds. Compound I show fungicidal activity. 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SUBSTANCE: invention provides novel phenylacetic acid derivatives of general formula I: (I), in which X denotes NOCH3, CHOCH3 and CHCH2CH3; R1 hydrogen or C1-C4-alkyl; R2 halogen, C1-C4-alkyl, or C1- C4-alkoxy; m= 0 or 1; R3 denotes hydrogen, amino, halogen, C1-C4-alkyl, C1- C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-alkylamino, or di- C1- C4-alkylamino; R4 cyano, halogen, C1-C6-alkyl, C1-C6-alkoxy, C2-C6- alkenyl, C2-C6-alkenyloxy, or C2-C6-alkinyl; provided that hydrocarbon moieties of above-indicated groups can be partially or completely halogenated or can bear one to three substituents selected from cyano, C1- C6-alkoxy, C1-C6-alkoxycarbonyl, phenyl, and dioxan (cyclic radicals can be partially or completely halogenated), C3-C6-cycloalkyl, C3-C6-cycloalkenyl, aryl, isoxazolyl, pyridyl, dioxolanyl, benzoxazolyl, thienyl, oxazolyl, furyl, oxyranyl, pyrazolyl, thiazolyl, pyrimidyloxy or tetrahydropyranyl, provided that cyclic radicals can be partially or completely halogenated or can bear one to three substituents selected from nitro, C1-C6-alkyl, C1-C6- alkoxy, C1-C6-haloalkyl, C1-C6-alkylamino, di-C1-C6-alkylamino and aryl; R5 denotes hydrogen, C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkinyl, provided that these radicals can be partially or completely halogenated or can bear one to three substituents selected from cyano, hydroxy, aminocarbonyl, C1-C6-alkyl, C2-C6-alkenyl, C1-C6-alkoxycarbonyl, C1-C6- alkylamino, benzyl, aryl, aryloxy, thienyl, pyrrolyl, oxazolyl, furyl, thiazolyl, oxadiazolyl, and isoxazolyl, cyclic radicals themselves can be partially or completely halogenated or can bear one to three substituents selected from nitro, hydroxy, C1-C4-alkyl, C1-C4-haloakyl, and C3-C6- cycloalkyl; on condition that X cannot be NOCH3 and CHOCH3, when R4 is unsubstituted C1-C4-alkyl, unsubstituted C3-C6-cycloalkyl, substituted or unsubstituted phenyl, or unsubstituted thienyl; or X cannot be CHOCH3, when R3 is hydrogen and R5 is C1-C10-alkyl; as well as salts or above-indicated compounds. Compound I show fungicidal activity. 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SUBSTANCE: invention provides novel phenylacetic acid derivatives of general formula I: (I), in which X denotes NOCH3, CHOCH3 and CHCH2CH3; R1 hydrogen or C1-C4-alkyl; R2 halogen, C1-C4-alkyl, or C1- C4-alkoxy; m= 0 or 1; R3 denotes hydrogen, amino, halogen, C1-C4-alkyl, C1- C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-alkylamino, or di- C1- C4-alkylamino; R4 cyano, halogen, C1-C6-alkyl, C1-C6-alkoxy, C2-C6- alkenyl, C2-C6-alkenyloxy, or C2-C6-alkinyl; provided that hydrocarbon moieties of above-indicated groups can be partially or completely halogenated or can bear one to three substituents selected from cyano, C1- C6-alkoxy, C1-C6-alkoxycarbonyl, phenyl, and dioxan (cyclic radicals can be partially or completely halogenated), C3-C6-cycloalkyl, C3-C6-cycloalkenyl, aryl, isoxazolyl, pyridyl, dioxolanyl, benzoxazolyl, thienyl, oxazolyl, furyl, oxyranyl, pyrazolyl, thiazolyl, pyrimidyloxy or tetrahydropyranyl, provided that cyclic radicals can be partially or completely halogenated or can bear one to three substituents selected from nitro, C1-C6-alkyl, C1-C6- alkoxy, C1-C6-haloalkyl, C1-C6-alkylamino, di-C1-C6-alkylamino and aryl; R5 denotes hydrogen, C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkinyl, provided that these radicals can be partially or completely halogenated or can bear one to three substituents selected from cyano, hydroxy, aminocarbonyl, C1-C6-alkyl, C2-C6-alkenyl, C1-C6-alkoxycarbonyl, C1-C6- alkylamino, benzyl, aryl, aryloxy, thienyl, pyrrolyl, oxazolyl, furyl, thiazolyl, oxadiazolyl, and isoxazolyl, cyclic radicals themselves can be partially or completely halogenated or can bear one to three substituents selected from nitro, hydroxy, C1-C4-alkyl, C1-C4-haloakyl, and C3-C6- cycloalkyl; on condition that X cannot be NOCH3 and CHOCH3, when R4 is unsubstituted C1-C4-alkyl, unsubstituted C3-C6-cycloalkyl, substituted or unsubstituted phenyl, or unsubstituted thienyl; or X cannot be CHOCH3, when R3 is hydrogen and R5 is C1-C10-alkyl; as well as salts or above-indicated compounds. Compound I show fungicidal activity. EFFECT: extended choice of active fungicides. 8 cl, 16 tbl, 10 ex</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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language eng ; rus
recordid cdi_epo_espacenet_RU2165411C2
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
AGRICULTURE
ANIMAL HUSBANDRY
BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES
CHEMISTRY
FISHING
FORESTRY
HETEROCYCLIC COMPOUNDS
HUMAN NECESSITIES
HUNTING
METALLURGY
ORGANIC CHEMISTRY
PEST REPELLANTS OR ATTRACTANTS
PLANT GROWTH REGULATORS
PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF
TRAPPING
title PHENYLACETIC ACID DERIVATIVES, THEIR INTERMEDIATES, AND AGENTS CONTAINING THEREOF
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