METHOD OF REGENERATING AND REUSING COBALT AND TUNGSTEN FROM REACTION WATERS (VERSIONS)

FIELD: waste disposal. SUBSTANCE: invention relates to processing of carboxylic acids' and other compounds' production waste. Reaction solutions are treated with alkali-earth metal hydroxide to precipitate cobalt and tungsten. Precipitate is successively treated with strong inorganic acid...

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Hauptverfasser: ANDREA GARDANO, SAURO STROLOGO, MARKO FOA
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creator ANDREA GARDANO
SAURO STROLOGO
MARKO FOA
description FIELD: waste disposal. SUBSTANCE: invention relates to processing of carboxylic acids' and other compounds' production waste. Reaction solutions are treated with alkali-earth metal hydroxide to precipitate cobalt and tungsten. Precipitate is successively treated with strong inorganic acid to form soluble cobalt salt. The latter is separated from tungstic acid precipitate. In another embodiment of invention, solution is treated with alkali metal hydroxide to precipitate and isolate cobaltous hydroxide. Alkali solution is then treated with alkali-earth metal compound to form alkali- earth metal tungstate, which is treated with strong inorganic acid to produce tungstic acid. EFFECT: enabled reuse of tungsten and cobalt. 19 cl, 4 ex
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SUBSTANCE: invention relates to processing of carboxylic acids' and other compounds' production waste. Reaction solutions are treated with alkali-earth metal hydroxide to precipitate cobalt and tungsten. Precipitate is successively treated with strong inorganic acid to form soluble cobalt salt. The latter is separated from tungstic acid precipitate. In another embodiment of invention, solution is treated with alkali metal hydroxide to precipitate and isolate cobaltous hydroxide. Alkali solution is then treated with alkali-earth metal compound to form alkali- earth metal tungstate, which is treated with strong inorganic acid to produce tungstic acid. 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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
FERROUS OR NON-FERROUS ALLOYS
INORGANIC CHEMISTRY
METALLURGY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRETREATMENT OF RAW MATERIALS
PRODUCTION AND REFINING OF METALS
THEIR RELEVANT APPARATUS
TRANSPORTING
TREATMENT OF ALLOYS OR NON-FERROUS METALS
title METHOD OF REGENERATING AND REUSING COBALT AND TUNGSTEN FROM REACTION WATERS (VERSIONS)
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