METHOD OF PREPARING CATALYST FOR PROPYLENE, ISOBUTYLENE OR TERTIARY BUTANOL GASEOUS OXIDATION

A catalyst used for producing, by catalytic gas phase oxidation of a C3-C5 olefin or tertiary alcohol, the corresponding unsaturated aldehyde and unsaturated carboxylic acid, said catalyst characterized by comprising molybdenum, iron and bismuth and having a specific surface area in the range from 1...

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Hauptverfasser: SINITI UTIDA,JP, KHIDEO ONODERA,JP, YUKIO AOKI,JP, MASAKHIRO VADA,JP, TATSUYA KAVADZIRI,JP
Format: Patent
Sprache:eng
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Zusammenfassung:A catalyst used for producing, by catalytic gas phase oxidation of a C3-C5 olefin or tertiary alcohol, the corresponding unsaturated aldehyde and unsaturated carboxylic acid, said catalyst characterized by comprising molybdenum, iron and bismuth and having a specific surface area in the range from 1 to 20m /gr, a pore volume in the range from 0.1 to 1.0 cc/gr and a pore diameter distribution in which the pore diameters are collectively distributed in the range of each of from 1 to 10 microns and from 0.1 to 1 (exclusive) micron; and a process for preparing said catalyst by charging an unfired material powder into a centrifugal flow coating device to form particles having the average particle diameter of 2 to 10mm and then firing the particles.