CERAMIC MOULD WITH A PHOTO-CATALYTIC ACTIVE, AIR PURIFYING, TRANSPARENT SURFACE COATING AND METHOD OF MANUFACTURING SAME

The ceramic molded body e.g. roofing tile, brick, clinker and/or facade panel, made of oxide-ceramic base material with capillary structure, comprises a transparent air-cleaning surface coating, which comprises peptized photocatalytic-active particles (1) and/or photocatalytic-active particles, whic...

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Hauptverfasser: EDUARD GAST, ALEXANDER STOLL, CARSTEN ACKERHANS, DETLEF BAHNEMANN, JULIA STÖTZNER
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creator EDUARD GAST
ALEXANDER STOLL
CARSTEN ACKERHANS
DETLEF BAHNEMANN
JULIA STÖTZNER
description The ceramic molded body e.g. roofing tile, brick, clinker and/or facade panel, made of oxide-ceramic base material with capillary structure, comprises a transparent air-cleaning surface coating, which comprises peptized photocatalytic-active particles (1) and/or photocatalytic-active particles, which are surrounded by a layer from peptized particles. The peptized photocatalytic active particles and/or photocatalytic active particles are formed as primary aggregates. The photocatalytic active particles comprise a band-gap of 3.0-3.5 eV and are producible by a sulfate pulping method. The ceramic molded body e.g. roofing tile, brick, clinker and/or facade panel, made of oxide-ceramic base material with capillary structure, comprises a transparent air-cleaning surface coating, which comprises peptized photocatalytic-active particles (1) and/or photocatalytic-active particles, which are surrounded by a layer from peptized particles. The peptized photocatalytic active particles and/or photocatalytic active particles are formed as primary aggregates. The photocatalytic active particles comprise a band-gap of 3.0-3.5 eV and are producible by a sulfate pulping method. The surface coating further comprises peptized non-photocatalytic active particles, non-photocatalytic active particles (3), which are surrounded by a layer from peptized particles and/or non-peptized non-photocatalytic active particles. The photocatalytic active particles and the non-photocatalytic active particles measured without peptization comprise average particle size of 2-20 nm and 10-15 nm respectively. A peptide layer (2) having a thickness of 1-2 nm is arranged on the non photocatalytic active peptized particles and/or on the photo-catalytic-active peptized particles. The surface coating comprises titanium dioxide-particle, which is surrounded by a completely or partially closed layer from peptized aluminum oxide-particle and/or peptized titanium dioxide-particle. Metatitanic acid-containing layer (4) is arranged between the titanium dioxide-particle and the closed layer and/or between the titanium dioxide-particle and the peptide layer. The titanium dioxide-particle, the metatitanic acid-containing layer and the closed layer form the primary aggregate with an average particle size of 35-45 nm. The surface coating has an average particle size of 2-5 nm and a thickness of 20-200 nm, and comprises an organic or inorganic bonding agent. The weight ratio of bonding agent to the photocatalytic-a
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The peptized photocatalytic active particles and/or photocatalytic active particles are formed as primary aggregates. The photocatalytic active particles comprise a band-gap of 3.0-3.5 eV and are producible by a sulfate pulping method. The ceramic molded body e.g. roofing tile, brick, clinker and/or facade panel, made of oxide-ceramic base material with capillary structure, comprises a transparent air-cleaning surface coating, which comprises peptized photocatalytic-active particles (1) and/or photocatalytic-active particles, which are surrounded by a layer from peptized particles. The peptized photocatalytic active particles and/or photocatalytic active particles are formed as primary aggregates. The photocatalytic active particles comprise a band-gap of 3.0-3.5 eV and are producible by a sulfate pulping method. The surface coating further comprises peptized non-photocatalytic active particles, non-photocatalytic active particles (3), which are surrounded by a layer from peptized particles and/or non-peptized non-photocatalytic active particles. The photocatalytic active particles and the non-photocatalytic active particles measured without peptization comprise average particle size of 2-20 nm and 10-15 nm respectively. A peptide layer (2) having a thickness of 1-2 nm is arranged on the non photocatalytic active peptized particles and/or on the photo-catalytic-active peptized particles. The surface coating comprises titanium dioxide-particle, which is surrounded by a completely or partially closed layer from peptized aluminum oxide-particle and/or peptized titanium dioxide-particle. Metatitanic acid-containing layer (4) is arranged between the titanium dioxide-particle and the closed layer and/or between the titanium dioxide-particle and the peptide layer. The titanium dioxide-particle, the metatitanic acid-containing layer and the closed layer form the primary aggregate with an average particle size of 35-45 nm. The surface coating has an average particle size of 2-5 nm and a thickness of 20-200 nm, and comprises an organic or inorganic bonding agent. The weight ratio of bonding agent to the photocatalytic-active particle is 1:1 to 1:0.6. An engobe or a glaze is arranged between the oxide-ceramic base material with capillary structure and the surface coating. The mass ratio of the photocatalytic particle to the non-photocatalytic-active particles is 3:6 to 4:6. The peptide- and/or metatitanic acid-containing layer are removed by heating at 300-600[deg] C. An independent claim is included for method for the production of a rough-ceramic molded article e.g. a roofing tile, brick, clinker and/or facade panel from oxide-ceramic base material.</description><language>eng ; por</language><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2017</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20170714&amp;DB=EPODOC&amp;CC=PT&amp;NR=2072118T$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20170714&amp;DB=EPODOC&amp;CC=PT&amp;NR=2072118T$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>EDUARD GAST</creatorcontrib><creatorcontrib>ALEXANDER STOLL</creatorcontrib><creatorcontrib>CARSTEN ACKERHANS</creatorcontrib><creatorcontrib>DETLEF BAHNEMANN</creatorcontrib><creatorcontrib>JULIA STÖTZNER</creatorcontrib><title>CERAMIC MOULD WITH A PHOTO-CATALYTIC ACTIVE, AIR PURIFYING, TRANSPARENT SURFACE COATING AND METHOD OF MANUFACTURING SAME</title><description>The ceramic molded body e.g. roofing tile, brick, clinker and/or facade panel, made of oxide-ceramic base material with capillary structure, comprises a transparent air-cleaning surface coating, which comprises peptized photocatalytic-active particles (1) and/or photocatalytic-active particles, which are surrounded by a layer from peptized particles. The peptized photocatalytic active particles and/or photocatalytic active particles are formed as primary aggregates. The photocatalytic active particles comprise a band-gap of 3.0-3.5 eV and are producible by a sulfate pulping method. The ceramic molded body e.g. roofing tile, brick, clinker and/or facade panel, made of oxide-ceramic base material with capillary structure, comprises a transparent air-cleaning surface coating, which comprises peptized photocatalytic-active particles (1) and/or photocatalytic-active particles, which are surrounded by a layer from peptized particles. The peptized photocatalytic active particles and/or photocatalytic active particles are formed as primary aggregates. The photocatalytic active particles comprise a band-gap of 3.0-3.5 eV and are producible by a sulfate pulping method. The surface coating further comprises peptized non-photocatalytic active particles, non-photocatalytic active particles (3), which are surrounded by a layer from peptized particles and/or non-peptized non-photocatalytic active particles. The photocatalytic active particles and the non-photocatalytic active particles measured without peptization comprise average particle size of 2-20 nm and 10-15 nm respectively. A peptide layer (2) having a thickness of 1-2 nm is arranged on the non photocatalytic active peptized particles and/or on the photo-catalytic-active peptized particles. The surface coating comprises titanium dioxide-particle, which is surrounded by a completely or partially closed layer from peptized aluminum oxide-particle and/or peptized titanium dioxide-particle. Metatitanic acid-containing layer (4) is arranged between the titanium dioxide-particle and the closed layer and/or between the titanium dioxide-particle and the peptide layer. The titanium dioxide-particle, the metatitanic acid-containing layer and the closed layer form the primary aggregate with an average particle size of 35-45 nm. The surface coating has an average particle size of 2-5 nm and a thickness of 20-200 nm, and comprises an organic or inorganic bonding agent. The weight ratio of bonding agent to the photocatalytic-active particle is 1:1 to 1:0.6. An engobe or a glaze is arranged between the oxide-ceramic base material with capillary structure and the surface coating. The mass ratio of the photocatalytic particle to the non-photocatalytic-active particles is 3:6 to 4:6. The peptide- and/or metatitanic acid-containing layer are removed by heating at 300-600[deg] C. 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The peptized photocatalytic active particles and/or photocatalytic active particles are formed as primary aggregates. The photocatalytic active particles comprise a band-gap of 3.0-3.5 eV and are producible by a sulfate pulping method. The ceramic molded body e.g. roofing tile, brick, clinker and/or facade panel, made of oxide-ceramic base material with capillary structure, comprises a transparent air-cleaning surface coating, which comprises peptized photocatalytic-active particles (1) and/or photocatalytic-active particles, which are surrounded by a layer from peptized particles. The peptized photocatalytic active particles and/or photocatalytic active particles are formed as primary aggregates. The photocatalytic active particles comprise a band-gap of 3.0-3.5 eV and are producible by a sulfate pulping method. The surface coating further comprises peptized non-photocatalytic active particles, non-photocatalytic active particles (3), which are surrounded by a layer from peptized particles and/or non-peptized non-photocatalytic active particles. The photocatalytic active particles and the non-photocatalytic active particles measured without peptization comprise average particle size of 2-20 nm and 10-15 nm respectively. A peptide layer (2) having a thickness of 1-2 nm is arranged on the non photocatalytic active peptized particles and/or on the photo-catalytic-active peptized particles. The surface coating comprises titanium dioxide-particle, which is surrounded by a completely or partially closed layer from peptized aluminum oxide-particle and/or peptized titanium dioxide-particle. Metatitanic acid-containing layer (4) is arranged between the titanium dioxide-particle and the closed layer and/or between the titanium dioxide-particle and the peptide layer. The titanium dioxide-particle, the metatitanic acid-containing layer and the closed layer form the primary aggregate with an average particle size of 35-45 nm. The surface coating has an average particle size of 2-5 nm and a thickness of 20-200 nm, and comprises an organic or inorganic bonding agent. The weight ratio of bonding agent to the photocatalytic-active particle is 1:1 to 1:0.6. An engobe or a glaze is arranged between the oxide-ceramic base material with capillary structure and the surface coating. The mass ratio of the photocatalytic particle to the non-photocatalytic-active particles is 3:6 to 4:6. The peptide- and/or metatitanic acid-containing layer are removed by heating at 300-600[deg] C. An independent claim is included for method for the production of a rough-ceramic molded article e.g. a roofing tile, brick, clinker and/or facade panel from oxide-ceramic base material.</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title CERAMIC MOULD WITH A PHOTO-CATALYTIC ACTIVE, AIR PURIFYING, TRANSPARENT SURFACE COATING AND METHOD OF MANUFACTURING SAME
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