A PROCESS FOR PREPARING PROPYLENE OXIDE

The present invention is related to a process for preparing propylene oxide, comprising (i) providing a stream comprising propene, hydrogen peroxide or a source of hydrogen peroxide, water, and an organic solvent; (ii) passing the liquid feed stream provided in (i) into an epoxidation zone comprisin...

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Hauptverfasser: MUELLER, CHRISTIAN, MUELLER, ULRICH, URBANCZYK, DANIEL, KELLER, TOBIAS, PARVULESCU, ANDREI-NICOLAE, WITZL, WERNER, KRAMP, MARVIN, SCHELLING, HEINER, LUECKE, KARSTEN, METZEN, BERND, RIEDEL, DOMINIC, WEGERLE, ULRIKE, WOERZ, NICOLAI TONIO, WEIDENBACH, MEINOLF, TELES, JOAQUIM HENRIQUE, WEBER, MARKUS
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creator MUELLER, CHRISTIAN
MUELLER, ULRICH
URBANCZYK, DANIEL
KELLER, TOBIAS
PARVULESCU, ANDREI-NICOLAE
WITZL, WERNER
KRAMP, MARVIN
SCHELLING, HEINER
LUECKE, KARSTEN
METZEN, BERND
RIEDEL, DOMINIC
WEGERLE, ULRIKE
WOERZ, NICOLAI TONIO
WEIDENBACH, MEINOLF
TELES, JOAQUIM HENRIQUE
WEBER, MARKUS
description The present invention is related to a process for preparing propylene oxide, comprising (i) providing a stream comprising propene, hydrogen peroxide or a source of hydrogen peroxide, water, and an organic solvent; (ii) passing the liquid feed stream provided in (i) into an epoxidation zone comprising an epoxidation catalyst comprising a titanium zeolite, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propene, propylene oxide, water, and the organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propylene oxide, water, organic solvent, and propene; (iv) separating propene from the effluent stream by distillation, comprising (iv.1) subjecting the effluent stream to distillation conditions in a distillation unit, obtaining a gaseous top stream S0 enriched in propene compared to the effluent stream subjected to distillation conditions, and a liquid bottoms stream S01 enriched in propylene oxide, water and organic solvent compared to the effluent stream subjected to distillation conditions; (iv.2) returning a condensed portion of the stream S0 to an upper part of the distillation unit.
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(ii) passing the liquid feed stream provided in (i) into an epoxidation zone comprising an epoxidation catalyst comprising a titanium zeolite, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propene, propylene oxide, water, and the organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propylene oxide, water, organic solvent, and propene; (iv) separating propene from the effluent stream by distillation, comprising (iv.1) subjecting the effluent stream to distillation conditions in a distillation unit, obtaining a gaseous top stream S0 enriched in propene compared to the effluent stream subjected to distillation conditions, and a liquid bottoms stream S01 enriched in propylene oxide, water and organic solvent compared to the effluent stream subjected to distillation conditions; (iv.2) returning a condensed portion of the stream S0 to an upper part of the distillation unit.</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
THEIR RELEVANT APPARATUS
TRANSPORTING
title A PROCESS FOR PREPARING PROPYLENE OXIDE
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