MICROBIOCIDE AND METHOD OF STABILIZING 3-ISOTHIAZOLINE

A composition comprising (a) One or more 3-isothiazolones of the formula: wherein Y is a (C1-C18)alkyl or (C3-C12), preferably (C5-C8), cycloalkyl each optionally substituted with one or more of hydroxy, halo, cyano, alkylamino, dialkylamine, arylamino, carboxy, carbalkoxy, alkoxy, aryloxy, alkylthi...

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Hauptverfasser: LAW ANDREW B, WILLINGHAM GARY L
Format: Patent
Sprache:eng
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Zusammenfassung:A composition comprising (a) One or more 3-isothiazolones of the formula: wherein Y is a (C1-C18)alkyl or (C3-C12), preferably (C5-C8), cycloalkyl each optionally substituted with one or more of hydroxy, halo, cyano, alkylamino, dialkylamine, arylamino, carboxy, carbalkoxy, alkoxy, aryloxy, alkylthio, haloalkoxy, cycloalkylamino, carbamoxy, or isothiazolonyl; an unsubstituted or halo-substituted (C2-C8), preferably (C2-C4) alkenyl or alkynyl; a (C7-C10)aralkyl optionally substituted with one or more of halogen, (C1-C4)alkyl or (C1-C4)alkoxy; or an aryl optionally substituted with one or more of halogen, nitro, (C1-C4)alkyl, (C1-C4)alkyl-acylamino, carb(C1-C4)alkoxy or sulfamyl; and X and X1 are each independently hydrogen, chloro, or methyl; and (b) a metal salt comprising a copper, zinc, manganese, ferrous or ferric salt, the anion of which is an organic carboxylic acid of at least six carbon atoms, EDTA, 8-hydroxyquinolinate, gluconate, o-phenanthroline, quinolinate N,N-bis(2-hydroxy-5-sulfobenzyl) glycine, a lignosulfonate polymer, or a polyacrylate; and (c) a locus to be protected against the growth of algae, bacteria, or fungi, said locus being of: (i) a metal working fluid (MWF) comprising at least one component selected from the group consisting of an alkanolamine, a petroleum sulfonate emulsifier, a boric acid ester or boric acid amide, a corrosion inhibitor, and a fatty acid; (ii) cooling tower water comprising corrosion inhibitors or scale inhibitors; (iii) laundry dish water; (iv) a cosmetic formulation; (v) a fuel system; (vi) an emulsion; (vii) a solid protective or decorative film; (viii) a film-forming, substantially non-wood-penetrating, organic polymeric paint vehicle in the case where the salt is a manganese, ferrous or ferric salt is disclosed, together with a method of stabilizing 3-isothiazolones in such loci using said metal salts.