FREMGANGSMAATE FOR AA FJERNE ILLELUKTENDE, SVOVELHOLDIGE FORBINDELSER SOM H2S, MERCAPTANER OG/ELLER ORGANISKE SULFIDER, FRA GASSTROEMMER INNEHOLDENDE OXYGEN, OG AKTIVERT CARBON FOR ANVENDELSE DERVED

1501571 Purifying O 2 -containing malodorant gas CALGON CORP 15 April 1976 [22 April 1975] 15641/76 Heading CIA [Also in Division B1] Sulphur containing compounds (viz. H 2 S, mercaptans and organic sulphides R-S-R1 where R and R' is each a C 1-5 alkyl group and the total number of C atoms in R...

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Hauptverfasser: WAGNER, NORMAN JOSEPH, JOYCE, RONALD STONE, SINHA, RABINDRA KUMAR
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SINHA, RABINDRA KUMAR
description 1501571 Purifying O 2 -containing malodorant gas CALGON CORP 15 April 1976 [22 April 1975] 15641/76 Heading CIA [Also in Division B1] Sulphur containing compounds (viz. H 2 S, mercaptans and organic sulphides R-S-R1 where R and R' is each a C 1-5 alkyl group and the total number of C atoms in R and R' is not greater than 8) are removed from gas streams containing O 2 by contacting the gas stream with an activated C impregnated with 0À5 to 20 wt. per cent NaOH and 4-50 wt. per cent moisture (i.e., essentially pure H 2 O held within the activated C by adsorption), the activating being used as adsorbent for the S- containing compounds. As an additional step, NaOH may be used to regenerate the activated C which has become saturated with H 2 S and the other malodorous S-containing compounds. NaOH treatment may be undertaken by soaking the unused or loaded activated C in its own volume of an aqueous NaOH solution of from 5 to 60% by wt. concentration; the C may be in granular form, e.g., between 4 and 10 U.S. sieve size, and have pore diameters 10 to 80 Š. Typically, O 2 is present in the gas stream in amounts at least 5 vol. per cent: the O 2 normally being derived from air.
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H 2 S, mercaptans and organic sulphides R-S-R1 where R and R' is each a C 1-5 alkyl group and the total number of C atoms in R and R' is not greater than 8) are removed from gas streams containing O 2 by contacting the gas stream with an activated C impregnated with 0À5 to 20 wt. per cent NaOH and 4-50 wt. per cent moisture (i.e., essentially pure H 2 O held within the activated C by adsorption), the activating being used as adsorbent for the S- containing compounds. As an additional step, NaOH may be used to regenerate the activated C which has become saturated with H 2 S and the other malodorous S-containing compounds. NaOH treatment may be undertaken by soaking the unused or loaded activated C in its own volume of an aqueous NaOH solution of from 5 to 60% by wt. concentration; the C may be in granular form, e.g., between 4 and 10 U.S. sieve size, and have pore diameters 10 to 80 Š. 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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
THEIR RELEVANT APPARATUS
TRANSPORTING
title FREMGANGSMAATE FOR AA FJERNE ILLELUKTENDE, SVOVELHOLDIGE FORBINDELSER SOM H2S, MERCAPTANER OG/ELLER ORGANISKE SULFIDER, FRA GASSTROEMMER INNEHOLDENDE OXYGEN, OG AKTIVERT CARBON FOR ANVENDELSE DERVED
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