ALKYL SULFONIC ACID ESTERS OF 1,3,2-OXAZAPHOBPHACYCLIC COMPOUNDS

Procedure for the preparation of esters of alcoholylsulfonic acid of combinations of 1, 3, 2 cycles of axasafosfa, of the general formula I **(See formula)** where R signifies a halogen atom, preferably a chlorine atom or a lower alcoholic sulfonic acid group with a straight or 1-6 carbon derived lo...

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Hauptverfasser: JURGEN POTEL, FRIEDRICH BOURSEAUX, NORBERT BROCK, HERBERT ARNOLD
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creator JURGEN POTEL
FRIEDRICH BOURSEAUX
NORBERT BROCK
HERBERT ARNOLD
description Procedure for the preparation of esters of alcoholylsulfonic acid of combinations of 1, 3, 2 cycles of axasafosfa, of the general formula I **(See formula)** where R signifies a halogen atom, preferably a chlorine atom or a lower alcoholic sulfonic acid group with a straight or 1-6 carbon derived lower alcohol chain, R1, R2 signify hydrogen or a molecular lower alkylene residue with 1 -4 carbon atoms that a halogen atom can carry, preferably a chlorine atom or a group of straight chain or lower alcohol derived lower alcohol sulphonic acid, where R1 and R2 can be the same or different and the group of alcoholic acid lower sulfonic acid is found at least once in the molecule of formula I and alk means a straight-chain or derivative alkylene group with two or three carbon atoms in the chain and branching with 3 or 4 carbon atoms in total, X means oxygen or sulfur, z hydrogen or a lower alcohol group with 1-4 carbon atoms and m means 2 or 3, characterized by the fact that A) a combination of the general formula IV **(See formula)** where R3 has the same meaning as R in formula I, or is a hydroxy group, R4 has the same meaning as R1 in formula Io is a lower molecular alkylene residue with 1-4 carbon atoms, bearing a hydroxy group -, alk and X have the same meaning as in formula I and X1 is a halogen atom, preferably a chlorine atom, reacted a combination of the general formula V **(See formula)** where R5 has the same meaning as R4 in formula IV and 2 and m has the same meaning as in formula I, or B) a combination of the general formula VI **(See formula)** where R3 and R4 have the same meaning as in formula IV and alk has the same meaning as in formula I, it reacts with a combination of general formula VII **(See formula)** where X1 has the same meaning as in formula IV, R5 has the same meaning as in formula V and X, Z and m have the same meaning as in formula I or C) a combination of the general formula VIII **(See formula)** where R5 has the same meaning as in formula V and X, Z, m and alk have the same meaning as in formula I, it reacts with a combination of general formula IX **(See formula)** where R3 has the same meaning as in formula IV, and in the combinations obtained from formula X **(See formula)** in which one or more of the substituents R3, R4 and R5 are a hydroxy group or carry this group, the hydroxy groups are transformed in a manner known per se into a halogen atom or in the group -OSO2R6 where R6 is a straight or derived lower alcohol group w
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FRIEDRICH BOURSEAUX ; NORBERT BROCK ; HERBERT ARNOLD</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_MY7700155A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>1977</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>CHEMISTRY</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><toplevel>online_resources</toplevel><creatorcontrib>JURGEN POTEL</creatorcontrib><creatorcontrib>FRIEDRICH BOURSEAUX</creatorcontrib><creatorcontrib>NORBERT BROCK</creatorcontrib><creatorcontrib>HERBERT ARNOLD</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>JURGEN POTEL</au><au>FRIEDRICH BOURSEAUX</au><au>NORBERT BROCK</au><au>HERBERT ARNOLD</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>ALKYL SULFONIC ACID ESTERS OF 1,3,2-OXAZAPHOBPHACYCLIC COMPOUNDS</title><date>1977-12-31</date><risdate>1977</risdate><abstract>Procedure for the preparation of esters of alcoholylsulfonic acid of combinations of 1, 3, 2 cycles of axasafosfa, of the general formula I **(See formula)** where R signifies a halogen atom, preferably a chlorine atom or a lower alcoholic sulfonic acid group with a straight or 1-6 carbon derived lower alcohol chain, R1, R2 signify hydrogen or a molecular lower alkylene residue with 1 -4 carbon atoms that a halogen atom can carry, preferably a chlorine atom or a group of straight chain or lower alcohol derived lower alcohol sulphonic acid, where R1 and R2 can be the same or different and the group of alcoholic acid lower sulfonic acid is found at least once in the molecule of formula I and alk means a straight-chain or derivative alkylene group with two or three carbon atoms in the chain and branching with 3 or 4 carbon atoms in total, X means oxygen or sulfur, z hydrogen or a lower alcohol group with 1-4 carbon atoms and m means 2 or 3, characterized by the fact that A) a combination of the general formula IV **(See formula)** where R3 has the same meaning as R in formula I, or is a hydroxy group, R4 has the same meaning as R1 in formula Io is a lower molecular alkylene residue with 1-4 carbon atoms, bearing a hydroxy group -, alk and X have the same meaning as in formula I and X1 is a halogen atom, preferably a chlorine atom, reacted a combination of the general formula V **(See formula)** where R5 has the same meaning as R4 in formula IV and 2 and m has the same meaning as in formula I, or B) a combination of the general formula VI **(See formula)** where R3 and R4 have the same meaning as in formula IV and alk has the same meaning as in formula I, it reacts with a combination of general formula VII **(See formula)** where X1 has the same meaning as in formula IV, R5 has the same meaning as in formula V and X, Z and m have the same meaning as in formula I or C) a combination of the general formula VIII **(See formula)** where R5 has the same meaning as in formula V and X, Z, m and alk have the same meaning as in formula I, it reacts with a combination of general formula IX **(See formula)** where R3 has the same meaning as in formula IV, and in the combinations obtained from formula X **(See formula)** in which one or more of the substituents R3, R4 and R5 are a hydroxy group or carry this group, the hydroxy groups are transformed in a manner known per se into a halogen atom or in the group -OSO2R6 where R6 is a straight or derived lower alcohol group with 1-6 carbon atoms and in combinations of formula X, in which none of the substituents R3, R4, and R5 are or carry an atom of a hydroxy group and one or more substituents R3, R4 and R5 are or carry a halogen atom, one or more of these halogen atoms is exchanged with the group -OSO2R6 by reaction for a combination of the general formula XI MeOS02R6 XI where R6 has the above meaning and Me is a metal of the first or second main or secondary group of the periodic system. 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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title ALKYL SULFONIC ACID ESTERS OF 1,3,2-OXAZAPHOBPHACYCLIC COMPOUNDS
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