CATALYST FOR PREPARATION OF AN UNSATURATED CARBOXYLIC ACID BY GAS PHASE OXIDATION OF AN UNSATURATED ALDEHYDE

What is described is a catalyst for preparation of an .alpha.,.beta.-unsaturated carboxylic acid by gas phase oxidation of an a,? -unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q is at most 0.3 mg/mm2, where...

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Hauptverfasser: HAMMON, ULRICH, DOBNER, CORNELIA KATHARINA, KARPOV, ANDREY, DR.WALSDORFF,CHRISTIAN, MACHT, JOSEF, WELKER-NIEUWOUDT, CATHRIN ALEXANDRA, BORCHERT, HOLGER
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creator HAMMON, ULRICH
DOBNER, CORNELIA KATHARINA
KARPOV, ANDREY
DR.WALSDORFF,CHRISTIAN
MACHT, JOSEF
WELKER-NIEUWOUDT, CATHRIN ALEXANDRA
BORCHERT, HOLGER
description What is described is a catalyst for preparation of an .alpha.,.beta.-unsaturated carboxylic acid by gas phase oxidation of an a,? -unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an a,? -unsaturated carboxylic acid by gas phase oxidation of an a,? -unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.
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Also described are a process for preparing the catalyst and a process for preparing an a,? -unsaturated carboxylic acid by gas phase oxidation of an a,? -unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. 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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title CATALYST FOR PREPARATION OF AN UNSATURATED CARBOXYLIC ACID BY GAS PHASE OXIDATION OF AN UNSATURATED ALDEHYDE
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