FLUOROALKYLATING AGENT

Problem to be Solved - It is intended to provide an industrially preferable fluoroalkylating agent and use thereof. Solution - The present invention provides a fluoroalkylating agent represented by the general formula (1) wherein R1 is a C1 to C8 fluoroalkyl group; R2 and R3 are each independently a...

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Hauptverfasser:	YOSHIOKA KOTARO, KAWAZOE KENTARO
Format:	Patent
Sprache:	eng
Schlagworte:	CHEMISTRY HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY
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creator	YOSHIOKA KOTARO KAWAZOE KENTARO
description	Problem to be Solved - It is intended to provide an industrially preferable fluoroalkylating agent and use thereof. Solution - The present invention provides a fluoroalkylating agent represented by the general formula (1) wherein R1 is a C1 to C8 fluoroalkyl group; R2 and R3 are each independently a C1 to C12 alkyl group or the like; Y1 to Y4 are each independently a hydrogen atom, a halogen atom, or the like; and X- is a monovalent anion. A compound of the general formula (3): R4-S-R1 having an introduced C1 to C8 fluoroalkyl group is easily obtained by reacting a compound of the general formula (2): R4-S-Z wherein R4 is a hydrocarbon group or the like; and Z is a leaving group, with the compound of the general formula (1).
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Solution - The present invention provides a fluoroalkylating agent represented by the general formula (1) wherein R1 is a C1 to C8 fluoroalkyl group; R2 and R3 are each independently a C1 to C12 alkyl group or the like; Y1 to Y4 are each independently a hydrogen atom, a halogen atom, or the like; and X- is a monovalent anion. A compound of the general formula (3): R4-S-R1 having an introduced C1 to C8 fluoroalkyl group is easily obtained by reacting a compound of the general formula (2): R4-S-Z wherein R4 is a hydrocarbon group or the like; and Z is a leaving group, with the compound of the general formula (1).</description><language>eng</language><subject>CHEMISTRY ; HETEROCYCLIC COMPOUNDS ; METALLURGY ; ORGANIC CHEMISTRY</subject><creationdate>2020</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20201229&DB=EPODOC&CC=MY&NR=181576A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76290</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20201229&DB=EPODOC&CC=MY&NR=181576A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>YOSHIOKA KOTARO</creatorcontrib><creatorcontrib>KAWAZOE KENTARO</creatorcontrib><title>FLUOROALKYLATING AGENT</title><description>Problem to be Solved - It is intended to provide an industrially preferable fluoroalkylating agent and use thereof. Solution - The present invention provides a fluoroalkylating agent represented by the general formula (1) wherein R1 is a C1 to C8 fluoroalkyl group; R2 and R3 are each independently a C1 to C12 alkyl group or the like; Y1 to Y4 are each independently a hydrogen atom, a halogen atom, or the like; and X- is a monovalent anion. A compound of the general formula (3): R4-S-R1 having an introduced C1 to C8 fluoroalkyl group is easily obtained by reacting a compound of the general formula (2): R4-S-Z wherein R4 is a hydrocarbon group or the like; and Z is a leaving group, with the compound of the general formula (1).</description><subject>CHEMISTRY</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2020</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZBBz8wn1D_J39PGO9HEM8fRzV3B0d_UL4WFgTUvMKU7lhdLcDHJuriHOHrqpBfnxqcUFicmpeakl8b6RhhaGpuZmjsYEFQAAHfgeTw</recordid><startdate>20201229</startdate><enddate>20201229</enddate><creator>YOSHIOKA KOTARO</creator><creator>KAWAZOE KENTARO</creator><scope>EVB</scope></search><sort><creationdate>20201229</creationdate><title>FLUOROALKYLATING AGENT</title><author>YOSHIOKA KOTARO ; KAWAZOE KENTARO</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_MY181576A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2020</creationdate><topic>CHEMISTRY</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><toplevel>online_resources</toplevel><creatorcontrib>YOSHIOKA KOTARO</creatorcontrib><creatorcontrib>KAWAZOE KENTARO</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>YOSHIOKA KOTARO</au><au>KAWAZOE KENTARO</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>FLUOROALKYLATING AGENT</title><date>2020-12-29</date><risdate>2020</risdate><abstract>Problem to be Solved - It is intended to provide an industrially preferable fluoroalkylating agent and use thereof. Solution - The present invention provides a fluoroalkylating agent represented by the general formula (1) wherein R1 is a C1 to C8 fluoroalkyl group; R2 and R3 are each independently a C1 to C12 alkyl group or the like; Y1 to Y4 are each independently a hydrogen atom, a halogen atom, or the like; and X- is a monovalent anion. A compound of the general formula (3): R4-S-R1 having an introduced C1 to C8 fluoroalkyl group is easily obtained by reacting a compound of the general formula (2): R4-S-Z wherein R4 is a hydrocarbon group or the like; and Z is a leaving group, with the compound of the general formula (1).</abstract><oa>free_for_read</oa></addata></record>
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subjects	CHEMISTRY HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY
title	FLUOROALKYLATING AGENT
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