CELLULOSE ETHERS IN EMULSION POLYMERIZATION DISPERSIONS

A process is provided for preparing an acrylic copolymer latex having improved mechanical and shear stability comprising emulsion polymerizing at least one ethylenically unsaturated monomer having up to 23 carbons in the presence of, by weight based on the total monomer content, a) from about 0.05 p...

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Hauptverfasser: GIJSBERT KROON, BERNARDUS J. W. JANSSEN, WILLEMINA G. SALOMONS, DIRK KRUYTOFF
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creator GIJSBERT KROON
BERNARDUS J. W. JANSSEN
WILLEMINA G. SALOMONS
DIRK KRUYTOFF
description A process is provided for preparing an acrylic copolymer latex having improved mechanical and shear stability comprising emulsion polymerizing at least one ethylenically unsaturated monomer having up to 23 carbons in the presence of, by weight based on the total monomer content, a) from about 0.05 percent to about 5.0 percent of a protective colloid with a molecular weight of less than 75,000, and b) from about 0.01 percent to about 1.5 percent of a least one water soluble free radical polymerization initiator. This latex provides coating manufacturers the flexibility of either eliminating surfactants altogether from coating or to use small amounts thereof. Se proporciona un proceso para la preparacion de un látex de copolímeros acrílico que tiene una estabilidad mecánica y al esfuerzo cortante mejorada, que comprende una polimerizacion por emulsion de cuando menos un monomero etilénicamente no saturado que tiene hasta 23 átomos de carbono en presencia, en base al peso del contenido total de monomero, a) de aproximadamente 0.5% a aproximadamente 5.0% de un coloide protector con un peso molecular inferior a 75,000, y b) de aproximadamente 0.01% a aproximadamente 1.5% de cuando menos un iniciador de polimerizacion de radicales libres soluble en agua. Este látex ofrece a los fabricantes de revestimientos la flexibilidad o bien de eliminar totalmente los surfactantes del revestimiento o bien de usar pequeñas cantidades de los mismos.
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title CELLULOSE ETHERS IN EMULSION POLYMERIZATION DISPERSIONS
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