HYDROCONVERSION OF A HYDROCARBON-BASED HEAVY FEEDSTOCK IN A HYBRID EBULLATED-ENTRAINED BED, COMPRISING PREMIXING SAID FEEDSTOCK WITH AN ORGANIC ADDITIVE

The present invention relates to a process for the hydroconversion of a heavy feedstock comprising: (a) preparing a first conditioned feedstock (103) by mixing said hydrocarbon-based heavy feedstock (101) with an organic chemical compound (102) comprising at least one carboxylic acid function and/or...

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Hauptverfasser: CORRE Thibaut, SILVERMAN Brett Matthew, PARASHER Sukesh, MARQUES Joao, BARBIER Jeremie, MOUNTAINLAND David M
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Sprache:eng ; spa
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creator CORRE Thibaut
SILVERMAN Brett Matthew
PARASHER Sukesh
MARQUES Joao
BARBIER Jeremie
MOUNTAINLAND David M
description The present invention relates to a process for the hydroconversion of a heavy feedstock comprising: (a) preparing a first conditioned feedstock (103) by mixing said hydrocarbon-based heavy feedstock (101) with an organic chemical compound (102) comprising at least one carboxylic acid function and/or at least one ester function and/or an acid anhydride function; (b) preparing a second conditioned feedstock (105) by mixing a catalyst precursor composition (104) with the first conditioned feedstock such that a colloidal or molecular catalyst is formed when said feedstock is reacted with sulphur; (c) heating the second conditioned feedstock in at least one preheater; (d) introducing the heated second conditioned feedstock (106) into at least one hybrid ebullated-entrained bed reactor comprising a porous supported hydroconversion catalyst and operating said reactor in the presence of hydrogen and under hydroconversion conditions in order to produce an upgraded material (107), wherein the colloidal or molecular catalyst is formed during step (c) and/or (d). La presente invención se refiere a un proceso de hidroconversión de una materia prima de petróleo pesado que comprende: (a) preparar una primera materia prima acondicionada (103) mezclando la materia prima pesada a base de hidrocarburos (101) con un compuesto químico orgánico (102) que comprende al menos una función de ácido carboxílico y/o al menos una función de éster y/o una función de anhídrido de ácido; (b) preparar una segunda materia prima acondicionada (105) mezclando una composición del precursor del catalizador (104) con la primera materia prima acondicionada de tal manera que se forme un catalizador coloidal o molecular cuando reaccione con el azufre; (c) calentar la segunda materia prima acondicionada en al menos un precalentador; (d) introducir la segunda materia prima acondicionada calentada (106) en al menos un reactor híbrido de lecho en ebullición-con arrastre que comprende un catalizador soportado poroso de hidroconversión y operar el reactor en la presencia de hidrógeno y bajo las condiciones de hidroconversión para producir un material mejorado (107), formándose el catalizador coloidal o molecular durante la etapa (c) y/o (d).
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(b) preparing a second conditioned feedstock (105) by mixing a catalyst precursor composition (104) with the first conditioned feedstock such that a colloidal or molecular catalyst is formed when said feedstock is reacted with sulphur; (c) heating the second conditioned feedstock in at least one preheater; (d) introducing the heated second conditioned feedstock (106) into at least one hybrid ebullated-entrained bed reactor comprising a porous supported hydroconversion catalyst and operating said reactor in the presence of hydrogen and under hydroconversion conditions in order to produce an upgraded material (107), wherein the colloidal or molecular catalyst is formed during step (c) and/or (d). La presente invención se refiere a un proceso de hidroconversión de una materia prima de petróleo pesado que comprende: (a) preparar una primera materia prima acondicionada (103) mezclando la materia prima pesada a base de hidrocarburos (101) con un compuesto químico orgánico (102) que comprende al menos una función de ácido carboxílico y/o al menos una función de éster y/o una función de anhídrido de ácido; (b) preparar una segunda materia prima acondicionada (105) mezclando una composición del precursor del catalizador (104) con la primera materia prima acondicionada de tal manera que se forme un catalizador coloidal o molecular cuando reaccione con el azufre; (c) calentar la segunda materia prima acondicionada en al menos un precalentador; (d) introducir la segunda materia prima acondicionada calentada (106) en al menos un reactor híbrido de lecho en ebullición-con arrastre que comprende un catalizador soportado poroso de hidroconversión y operar el reactor en la presencia de hidrógeno y bajo las condiciones de hidroconversión para producir un material mejorado (107), formándose el catalizador coloidal o molecular durante la etapa (c) y/o (d).</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMISTRY
CRACKING HYDROCARBON OILS
FUELS
LUBRICANTS
METALLURGY
MINERAL WAXES
PEAT
PETROLEUM, GAS OR COKE INDUSTRIES
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
title HYDROCONVERSION OF A HYDROCARBON-BASED HEAVY FEEDSTOCK IN A HYBRID EBULLATED-ENTRAINED BED, COMPRISING PREMIXING SAID FEEDSTOCK WITH AN ORGANIC ADDITIVE
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