PROCEDIMIENTO PARA LA PREPARACION CONJUNTA DE ACIDOS CARBOXILICOS Y ANHIDRIDOS DE ACIDO CARBOXILICOS,ASI COMO EVENTUALMENTE ESTERES DE ACIDO CARBOXILICO
1. A process for the common preparation of carboxylic acids and carboxylic anhydrides and, if appropriate, carboxylic acid esters of the general formulae RCOOH, RCOOCOR and RCOOR respectively, by reacting a dialkyl ether of the general formula ROR and an alcohol of the general formula ROH with carbo...
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creator | PETER HORSTERMANN HEINZ ERPENBACH KLAUS GEHRMANN |
description | 1. A process for the common preparation of carboxylic acids and carboxylic anhydrides and, if appropriate, carboxylic acid esters of the general formulae RCOOH, RCOOCOR and RCOOR respectively, by reacting a dialkyl ether of the general formula ROR and an alcohol of the general formula ROH with carbon monoxide, optionally containing up to 10% by volume of hydrogen, in the presence of a catalyst system comprising carbonyl complexes of noble metals of group VIII of the Periodic Table ; an alkali metal iodide, organophosphonium iodide or organoammonium iodide ; an alkyl iodide of the general formula RI and, if appropriate, compounds of carbonyl forming non-noble metals of groups IV, V, VI, VII or VIII of the Periodic Table, where R in each case denotes the same alkyl radical having 1 to 4 carbon atoms, which comprises employing the dialkyl ether and the alcohol in the molar ratio 9 : 1 to 1 : 9 and carrying out the reaction under anhydrous conditions at temperatures of from 50 to 250 degrees C and pressures of from 0.1 to 120 bar. |
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A process for the common preparation of carboxylic acids and carboxylic anhydrides and, if appropriate, carboxylic acid esters of the general formulae RCOOH, RCOOCOR and RCOOR respectively, by reacting a dialkyl ether of the general formula ROR and an alcohol of the general formula ROH with carbon monoxide, optionally containing up to 10% by volume of hydrogen, in the presence of a catalyst system comprising carbonyl complexes of noble metals of group VIII of the Periodic Table ; an alkali metal iodide, organophosphonium iodide or organoammonium iodide ; an alkyl iodide of the general formula RI and, if appropriate, compounds of carbonyl forming non-noble metals of groups IV, V, VI, VII or VIII of the Periodic Table, where R in each case denotes the same alkyl radical having 1 to 4 carbon atoms, which comprises employing the dialkyl ether and the alcohol in the molar ratio 9 : 1 to 1 : 9 and carrying out the reaction under anhydrous conditions at temperatures of from 50 to 250 degrees C and pressures of from 0.1 to 120 bar.</description><edition>5</edition><language>spa</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; APPARATUS THEREFOR ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; GENERAL METHODS OF ORGANIC CHEMISTRY ; METALLURGY ; ORGANIC CHEMISTRY ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>1991</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19911015&DB=EPODOC&CC=MX&NR=163194B$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,777,882,25545,76296</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19911015&DB=EPODOC&CC=MX&NR=163194B$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>PETER HORSTERMANN</creatorcontrib><creatorcontrib>HEINZ ERPENBACH</creatorcontrib><creatorcontrib>KLAUS GEHRMANN</creatorcontrib><title>PROCEDIMIENTO PARA LA PREPARACION CONJUNTA DE ACIDOS CARBOXILICOS Y ANHIDRIDOS DE ACIDO CARBOXILICOS,ASI COMO EVENTUALMENTE ESTERES DE ACIDO CARBOXILICO</title><description>1. A process for the common preparation of carboxylic acids and carboxylic anhydrides and, if appropriate, carboxylic acid esters of the general formulae RCOOH, RCOOCOR and RCOOR respectively, by reacting a dialkyl ether of the general formula ROR and an alcohol of the general formula ROH with carbon monoxide, optionally containing up to 10% by volume of hydrogen, in the presence of a catalyst system comprising carbonyl complexes of noble metals of group VIII of the Periodic Table ; an alkali metal iodide, organophosphonium iodide or organoammonium iodide ; an alkyl iodide of the general formula RI and, if appropriate, compounds of carbonyl forming non-noble metals of groups IV, V, VI, VII or VIII of the Periodic Table, where R in each case denotes the same alkyl radical having 1 to 4 carbon atoms, which comprises employing the dialkyl ether and the alcohol in the molar ratio 9 : 1 to 1 : 9 and carrying out the reaction under anhydrous conditions at temperatures of from 50 to 250 degrees C and pressures of from 0.1 to 120 bar.</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>APPARATUS THEREFOR</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>GENERAL METHODS OF ORGANIC CHEMISTRY</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1991</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZJgREOTv7Ori6evp6hfirxDgGOSo4OOoEBDkCmI6e_r7KTj7-3mF-oU4Kri4KgBFXPyDFZwdg5z8Izx9PJ2BnEgFRz8PT5cgsAxMDYoSHcdgT6Axvv4KrmFAa0IdfXyBlKuCa3CIa5Ardk08DKxpiTnFqbxQmptBzs01xNlDN7UgPz61uCAxOTUvtSTeN8LQzNjQ0sTJmKACALubQXo</recordid><startdate>19911015</startdate><enddate>19911015</enddate><creator>PETER HORSTERMANN</creator><creator>HEINZ ERPENBACH</creator><creator>KLAUS GEHRMANN</creator><scope>EVB</scope></search><sort><creationdate>19911015</creationdate><title>PROCEDIMIENTO PARA LA PREPARACION CONJUNTA DE ACIDOS CARBOXILICOS Y ANHIDRIDOS DE ACIDO CARBOXILICOS,ASI COMO EVENTUALMENTE ESTERES DE ACIDO CARBOXILICO</title><author>PETER HORSTERMANN ; HEINZ ERPENBACH ; KLAUS GEHRMANN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_MX163194B3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>spa</language><creationdate>1991</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>APPARATUS THEREFOR</topic><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>GENERAL METHODS OF ORGANIC CHEMISTRY</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>PETER HORSTERMANN</creatorcontrib><creatorcontrib>HEINZ ERPENBACH</creatorcontrib><creatorcontrib>KLAUS GEHRMANN</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>PETER HORSTERMANN</au><au>HEINZ ERPENBACH</au><au>KLAUS GEHRMANN</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>PROCEDIMIENTO PARA LA PREPARACION CONJUNTA DE ACIDOS CARBOXILICOS Y ANHIDRIDOS DE ACIDO CARBOXILICOS,ASI COMO EVENTUALMENTE ESTERES DE ACIDO CARBOXILICO</title><date>1991-10-15</date><risdate>1991</risdate><abstract>1. A process for the common preparation of carboxylic acids and carboxylic anhydrides and, if appropriate, carboxylic acid esters of the general formulae RCOOH, RCOOCOR and RCOOR respectively, by reacting a dialkyl ether of the general formula ROR and an alcohol of the general formula ROH with carbon monoxide, optionally containing up to 10% by volume of hydrogen, in the presence of a catalyst system comprising carbonyl complexes of noble metals of group VIII of the Periodic Table ; an alkali metal iodide, organophosphonium iodide or organoammonium iodide ; an alkyl iodide of the general formula RI and, if appropriate, compounds of carbonyl forming non-noble metals of groups IV, V, VI, VII or VIII of the Periodic Table, where R in each case denotes the same alkyl radical having 1 to 4 carbon atoms, which comprises employing the dialkyl ether and the alcohol in the molar ratio 9 : 1 to 1 : 9 and carrying out the reaction under anhydrous conditions at temperatures of from 50 to 250 degrees C and pressures of from 0.1 to 120 bar.</abstract><edition>5</edition><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING |
title | PROCEDIMIENTO PARA LA PREPARACION CONJUNTA DE ACIDOS CARBOXILICOS Y ANHIDRIDOS DE ACIDO CARBOXILICOS,ASI COMO EVENTUALMENTE ESTERES DE ACIDO CARBOXILICO |
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