2,6-Diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer having adsorption properties
The invention relates to coordination chemistry, namely to a coordination polymer of cobalt(II) with the Schiff base - 2,6-diacetylpyridine bis(isonicotinoylhydrazone), which has adsorption properties.According to the invention, claimed is 2,6-diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(...
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creator | BULHAC Ion ŞOVA Sergiu BOUROŞ Pavlina DANILESCU Olga PETUHOV Oleg |
description | The invention relates to coordination chemistry, namely to a coordination polymer of cobalt(II) with the Schiff base - 2,6-diacetylpyridine bis(isonicotinoylhydrazone), which has adsorption properties.According to the invention, claimed is 2,6-diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer of the formula {[Co(L)]·5.75H2O}n, produced in solvothermal conditions at a temperature of 120°C, for 48 hours, in a dimethylformamide/methanol solvent mixture. The polymer has a porous structure with a specific surface of 841 m2/g calculated according to the BET equation and has adsorption properties.
Invenţia se referă la chimia coordinativă şi anume la un polimer coordinativ al cobaltului(II) cu baza Schiff - 2,6-diacetilpiridină bis(izonicotinoilhidrazonă), care manifestă proprietăţi adsorbtive.Conform invenţiei, se revendică polimerul coordinativ 2,6-diacetilpiridinbis(izonicotinoilhidrazonato)(2-)cobalt(II)-apă(1/5,75) cu formula {[Co(L)]·5,75H2O}n, obţinut în condiţii solvotermale la temperatura de 120°C, timp de 48 ore, într-un amestec de solvenţi dimetilformamidă/metanol. Polimerul posedă o reţea cristalină poroasă cu o suprafaţă specifică de 841 m2/g calculată după ecuaţia BET şi manifestă proprietăţi adsorbtive.
Изобретение относится к координационной химии, а именно к координационному полимеру кобальта(II) с основанием Шиффа - 2,6-диацетилпиридин бис-(изоникотиноилгидразон), который обладает адсорбционными свойствами.Согласно изобретению, заявляется координационный полимер 2,6-диацетилпиридинбис (изоникотиноилгидразонато)(2-)кобальт(II)-вода(1/5,75) формулы {[Co(L)]·5,75H2O}n, полученный в сольвотермальных условиях при температуре 120°С, в течении 48 ч, в смеси растворителей диметилформамид/метанол. Полимер имеет пористую структуру с удельной поверхностью 841 м2/г, расчитанная по уравнению БЕТ и обладает адсорбционными свойствами. |
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fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_MD4672B1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>MD4672B1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_MD4672B13</originalsourceid><addsrcrecordid>eNqFjrEKwjAUALs4iPoJQscGrNJq212r2MHNXV7Tp30Q80ISlLj46xZ0d7rh4Lhx9M4XZVoTSPRBmWCpI40tuYQca5LsSXNQfegsvFiDZ5HkqZDcgvJJ04j0CR5tkq2KZVWIWDLboQCeWMeGVbijjXt4kL7F0Dm25mssG7Se0E2j0RWUw9mPk2h-2J93xxQNX9CZYUyjv5zqTVnl22z9z38AKK5Ghw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>2,6-Diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer having adsorption properties</title><source>esp@cenet</source><creator>BULHAC Ion ; ŞOVA Sergiu ; BOUROŞ Pavlina ; DANILESCU Olga ; PETUHOV Oleg</creator><creatorcontrib>BULHAC Ion ; ŞOVA Sergiu ; BOUROŞ Pavlina ; DANILESCU Olga ; PETUHOV Oleg</creatorcontrib><description>The invention relates to coordination chemistry, namely to a coordination polymer of cobalt(II) with the Schiff base - 2,6-diacetylpyridine bis(isonicotinoylhydrazone), which has adsorption properties.According to the invention, claimed is 2,6-diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer of the formula {[Co(L)]·5.75H2O}n, produced in solvothermal conditions at a temperature of 120°C, for 48 hours, in a dimethylformamide/methanol solvent mixture. The polymer has a porous structure with a specific surface of 841 m2/g calculated according to the BET equation and has adsorption properties.
Invenţia se referă la chimia coordinativă şi anume la un polimer coordinativ al cobaltului(II) cu baza Schiff - 2,6-diacetilpiridină bis(izonicotinoilhidrazonă), care manifestă proprietăţi adsorbtive.Conform invenţiei, se revendică polimerul coordinativ 2,6-diacetilpiridinbis(izonicotinoilhidrazonato)(2-)cobalt(II)-apă(1/5,75) cu formula {[Co(L)]·5,75H2O}n, obţinut în condiţii solvotermale la temperatura de 120°C, timp de 48 ore, într-un amestec de solvenţi dimetilformamidă/metanol. Polimerul posedă o reţea cristalină poroasă cu o suprafaţă specifică de 841 m2/g calculată după ecuaţia BET şi manifestă proprietăţi adsorbtive.
Изобретение относится к координационной химии, а именно к координационному полимеру кобальта(II) с основанием Шиффа - 2,6-диацетилпиридин бис-(изоникотиноилгидразон), который обладает адсорбционными свойствами.Согласно изобретению, заявляется координационный полимер 2,6-диацетилпиридинбис (изоникотиноилгидразонато)(2-)кобальт(II)-вода(1/5,75) формулы {[Co(L)]·5,75H2O}n, полученный в сольвотермальных условиях при температуре 120°С, в течении 48 ч, в смеси растворителей диметилформамид/метанол. Полимер имеет пористую структуру с удельной поверхностью 841 м2/г, расчитанная по уравнению БЕТ и обладает адсорбционными свойствами.</description><language>eng ; rum ; rus</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; HETEROCYCLIC COMPOUNDS ; METALLURGY ; ORGANIC CHEMISTRY ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; SEPARATION ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2020</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20200131&DB=EPODOC&CC=MD&NR=4672B1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20200131&DB=EPODOC&CC=MD&NR=4672B1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>BULHAC Ion</creatorcontrib><creatorcontrib>ŞOVA Sergiu</creatorcontrib><creatorcontrib>BOUROŞ Pavlina</creatorcontrib><creatorcontrib>DANILESCU Olga</creatorcontrib><creatorcontrib>PETUHOV Oleg</creatorcontrib><title>2,6-Diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer having adsorption properties</title><description>The invention relates to coordination chemistry, namely to a coordination polymer of cobalt(II) with the Schiff base - 2,6-diacetylpyridine bis(isonicotinoylhydrazone), which has adsorption properties.According to the invention, claimed is 2,6-diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer of the formula {[Co(L)]·5.75H2O}n, produced in solvothermal conditions at a temperature of 120°C, for 48 hours, in a dimethylformamide/methanol solvent mixture. The polymer has a porous structure with a specific surface of 841 m2/g calculated according to the BET equation and has adsorption properties.
Invenţia se referă la chimia coordinativă şi anume la un polimer coordinativ al cobaltului(II) cu baza Schiff - 2,6-diacetilpiridină bis(izonicotinoilhidrazonă), care manifestă proprietăţi adsorbtive.Conform invenţiei, se revendică polimerul coordinativ 2,6-diacetilpiridinbis(izonicotinoilhidrazonato)(2-)cobalt(II)-apă(1/5,75) cu formula {[Co(L)]·5,75H2O}n, obţinut în condiţii solvotermale la temperatura de 120°C, timp de 48 ore, într-un amestec de solvenţi dimetilformamidă/metanol. Polimerul posedă o reţea cristalină poroasă cu o suprafaţă specifică de 841 m2/g calculată după ecuaţia BET şi manifestă proprietăţi adsorbtive.
Изобретение относится к координационной химии, а именно к координационному полимеру кобальта(II) с основанием Шиффа - 2,6-диацетилпиридин бис-(изоникотиноилгидразон), который обладает адсорбционными свойствами.Согласно изобретению, заявляется координационный полимер 2,6-диацетилпиридинбис (изоникотиноилгидразонато)(2-)кобальт(II)-вода(1/5,75) формулы {[Co(L)]·5,75H2O}n, полученный в сольвотермальных условиях при температуре 120°С, в течении 48 ч, в смеси растворителей диметилформамид/метанол. Полимер имеет пористую структуру с удельной поверхностью 841 м2/г, расчитанная по уравнению БЕТ и обладает адсорбционными свойствами.</description><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>SEPARATION</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2020</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqFjrEKwjAUALs4iPoJQscGrNJq212r2MHNXV7Tp30Q80ISlLj46xZ0d7rh4Lhx9M4XZVoTSPRBmWCpI40tuYQca5LsSXNQfegsvFiDZ5HkqZDcgvJJ04j0CR5tkq2KZVWIWDLboQCeWMeGVbijjXt4kL7F0Dm25mssG7Se0E2j0RWUw9mPk2h-2J93xxQNX9CZYUyjv5zqTVnl22z9z38AKK5Ghw</recordid><startdate>20200131</startdate><enddate>20200131</enddate><creator>BULHAC Ion</creator><creator>ŞOVA Sergiu</creator><creator>BOUROŞ Pavlina</creator><creator>DANILESCU Olga</creator><creator>PETUHOV Oleg</creator><scope>EVB</scope></search><sort><creationdate>20200131</creationdate><title>2,6-Diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer having adsorption properties</title><author>BULHAC Ion ; ŞOVA Sergiu ; BOUROŞ Pavlina ; DANILESCU Olga ; PETUHOV Oleg</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_MD4672B13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; rum ; rus</language><creationdate>2020</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>SEPARATION</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>BULHAC Ion</creatorcontrib><creatorcontrib>ŞOVA Sergiu</creatorcontrib><creatorcontrib>BOUROŞ Pavlina</creatorcontrib><creatorcontrib>DANILESCU Olga</creatorcontrib><creatorcontrib>PETUHOV Oleg</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>BULHAC Ion</au><au>ŞOVA Sergiu</au><au>BOUROŞ Pavlina</au><au>DANILESCU Olga</au><au>PETUHOV Oleg</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>2,6-Diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer having adsorption properties</title><date>2020-01-31</date><risdate>2020</risdate><abstract>The invention relates to coordination chemistry, namely to a coordination polymer of cobalt(II) with the Schiff base - 2,6-diacetylpyridine bis(isonicotinoylhydrazone), which has adsorption properties.According to the invention, claimed is 2,6-diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer of the formula {[Co(L)]·5.75H2O}n, produced in solvothermal conditions at a temperature of 120°C, for 48 hours, in a dimethylformamide/methanol solvent mixture. The polymer has a porous structure with a specific surface of 841 m2/g calculated according to the BET equation and has adsorption properties.
Invenţia se referă la chimia coordinativă şi anume la un polimer coordinativ al cobaltului(II) cu baza Schiff - 2,6-diacetilpiridină bis(izonicotinoilhidrazonă), care manifestă proprietăţi adsorbtive.Conform invenţiei, se revendică polimerul coordinativ 2,6-diacetilpiridinbis(izonicotinoilhidrazonato)(2-)cobalt(II)-apă(1/5,75) cu formula {[Co(L)]·5,75H2O}n, obţinut în condiţii solvotermale la temperatura de 120°C, timp de 48 ore, într-un amestec de solvenţi dimetilformamidă/metanol. Polimerul posedă o reţea cristalină poroasă cu o suprafaţă specifică de 841 m2/g calculată după ecuaţia BET şi manifestă proprietăţi adsorbtive.
Изобретение относится к координационной химии, а именно к координационному полимеру кобальта(II) с основанием Шиффа - 2,6-диацетилпиридин бис-(изоникотиноилгидразон), который обладает адсорбционными свойствами.Согласно изобретению, заявляется координационный полимер 2,6-диацетилпиридинбис (изоникотиноилгидразонато)(2-)кобальт(II)-вода(1/5,75) формулы {[Co(L)]·5,75H2O}n, полученный в сольвотермальных условиях при температуре 120°С, в течении 48 ч, в смеси растворителей диметилформамид/метанол. Полимер имеет пористую структуру с удельной поверхностью 841 м2/г, расчитанная по уравнению БЕТ и обладает адсорбционными свойствами.</abstract><oa>free_for_read</oa></addata></record> |
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title | 2,6-Diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer having adsorption properties |
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