POSITIVE ELECTRODE ACTIVE MATERIAL FOR SECONDARY BATTERY AND METHOD FOR MANUFACTURING THE SAME
An objective of the present invention is to provide a positive electrode active material capable of accomplishing a higher energy density by increasing the density and the positive electrode density of positive active material powers. The positive electrode active material for the secondary battery...
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Zusammenfassung: | An objective of the present invention is to provide a positive electrode active material capable of accomplishing a higher energy density by increasing the density and the positive electrode density of positive active material powers. The positive electrode active material for the secondary battery contains a type 1 compound or a type 2 compound expressed as Li[Li_xMn_yM_(1-x-y)]O_2. The positive electrode active material includes the form of secondary particles obtained by agglomerating first particles. When the positive electrode active material powders are pressurized with the pressure of 62 MPa, the density of pressurizing the powders is at least 2.7 g/cm^3. The size of a crystallite obtained from the diffraction line 104 by X-ray diffraction of the positive electrode active material is 20 nm or more and 30 nm or less.
양극 활물질 분체 자체의 밀도 및 양극 밀도를 높여 이차전지로서 높은 에너지 밀도를 달성할 수 있는 양극 활물질을 제공하는 것을 과제로 한다. 이차전지용 양극 활물질로서, 화학식 Li[LiMnM]O로 표시되는 1종 또는 2종 이상의 화합물을 함유하고, 상기 양극 활물질은 1차 입자가 응집된 2차 입자의 형태를 이루고, 62㎫의 압력으로 상기 양극 활물질 분체를 가압했을 때의 분체 가압 밀도가 2.7 g/㎤ 이상이고, 상기 양극 활물질의 X선 회절에 의한 회절선 (104)로부터 구한 결정자 사이즈가 20㎚ 이상 30㎚ 이하인, 이차전지용 양극 활물질에 의해 달성된다. |
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