접촉 산화 방법 및 공역 디엔의 제조 방법

본 발명은, 관식 반응기를 이용해 분자상 산소로 기상 접촉 부분 산화 할 때, 몰리브덴 복합 산화물계 촉매의 성능 열화를 억제하는 것을 목적으로 한다. 본 발명은, 반응 원료 공급구측으로부터 순서대로, Mo 화합물을 함유하는 Mo 화합물층 및 Mo 복합 산화물 촉매를 함유하는 복합 산화물 촉매층이 배치된 관식 반응기를 이용해 440℃인 혼합 기체(공기 75 체적% 및 수증기 25 체적%)의 유통 하에 있어서 상기 Mo 화합물의 Mo 휘산량이 상기 Mo 복합 산화물 촉매의 Mo 휘산량보다도 큰 접촉 산화 방법에 관한 것이다. An o...

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Hauptverfasser: KAMEO HIROSHI, HINOISHI HIROKI, IWAKAI KAZUYUKI, YAMAGUCHI TETSUFUMI
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creator KAMEO HIROSHI
HINOISHI HIROKI
IWAKAI KAZUYUKI
YAMAGUCHI TETSUFUMI
description 본 발명은, 관식 반응기를 이용해 분자상 산소로 기상 접촉 부분 산화 할 때, 몰리브덴 복합 산화물계 촉매의 성능 열화를 억제하는 것을 목적으로 한다. 본 발명은, 반응 원료 공급구측으로부터 순서대로, Mo 화합물을 함유하는 Mo 화합물층 및 Mo 복합 산화물 촉매를 함유하는 복합 산화물 촉매층이 배치된 관식 반응기를 이용해 440℃인 혼합 기체(공기 75 체적% 및 수증기 25 체적%)의 유통 하에 있어서 상기 Mo 화합물의 Mo 휘산량이 상기 Mo 복합 산화물 촉매의 Mo 휘산량보다도 큰 접촉 산화 방법에 관한 것이다. An object of the present invention is to suppress performance deterioration of a molybdenum composite oxide-based catalyst at the time of performing gas-phase catalytic partial oxidation with molecular oxygen by using a tubular reactor. The present invention relates to a catalytic oxidation method using a tubular reactor in which a Mo compound layer containing a Mo compound and a composite oxide catalyst layer containing a Mo composite oxide catalyst are arranged in this order from a reaction raw material supply port side and under a flow of a mixed gas (75 vol% of air and 25 vol% of water vapor) at 440°C, a Mo sublimation amount of the Mo compound is larger than a Mo sublimation amount of the Mo composite oxide catalyst under the same conditions.
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An object of the present invention is to suppress performance deterioration of a molybdenum composite oxide-based catalyst at the time of performing gas-phase catalytic partial oxidation with molecular oxygen by using a tubular reactor. The present invention relates to a catalytic oxidation method using a tubular reactor in which a Mo compound layer containing a Mo compound and a composite oxide catalyst layer containing a Mo composite oxide catalyst are arranged in this order from a reaction raw material supply port side and under a flow of a mixed gas (75 vol% of air and 25 vol% of water vapor) at 440°C, a Mo sublimation amount of the Mo compound is larger than a Mo sublimation amount of the Mo composite oxide catalyst under the same conditions.</abstract><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title 접촉 산화 방법 및 공역 디엔의 제조 방법
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