Steam reforming catalyst for hydrocarbon-containing gas hydrogen production apparatus and hydrogen production method

[과제] 수증기 존재 하에서 탄화수소 함유 가스의 수증기 개질하여 수소 가스를 얻기 위한 촉매로서, 수소 가스에 높은 전환율, 암모니아 가스와 탄소 석출을 방지하고 장시간 반응 내구성 우수하고 또한 저비용 화가 가능한 촉매를 제공한다. 본 발명 상기 과제는 탈황된 탄화수소 함유 가스를 수증기 개질하는 촉매로서 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 1 - 10 중량부 세륨 (Ce) 를 포함한 활성 보조 재료로 수식된 수식 담체에 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 0.1 - 0.3 중량부 로듐 (...

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Hauptverfasser: NAKAMURA HIROSHI, IDA JUNKO, REICHINGER MARKUS, ITAMI HIROHIKO
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IDA JUNKO
REICHINGER MARKUS
ITAMI HIROHIKO
description [과제] 수증기 존재 하에서 탄화수소 함유 가스의 수증기 개질하여 수소 가스를 얻기 위한 촉매로서, 수소 가스에 높은 전환율, 암모니아 가스와 탄소 석출을 방지하고 장시간 반응 내구성 우수하고 또한 저비용 화가 가능한 촉매를 제공한다. 본 발명 상기 과제는 탈황된 탄화수소 함유 가스를 수증기 개질하는 촉매로서 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 1 - 10 중량부 세륨 (Ce) 를 포함한 활성 보조 재료로 수식된 수식 담체에 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 0.1 - 0.3 중량부 로듐 (Rh)과 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 0.01 - 0.3 중량부의 백금 (Pt)을 포함하는 활성 금속을 담지한 수증기 개질 촉매에 의해 해결된다. Problem to be Solved To provide a catalyst for obtaining hydrogen gas by steam reforming of a hydrocarbon-containing gas in the presence of steam, the catalyst having a high ratio of conversion into hydrogen gas, being capable of preventing deposition of ammonia gas or carbon, having excellent stability even after being reacted for a long time, and allowing a reduction in costs. Solution The foregoing problem is solved by steam reforming catalyst, comprising active metals supported on an ±-alumina carrier, wherein the active metals comprise 0.1 to 0.3 parts by weight of rhodium (Rh) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and 0.01 to 0.3 parts by weigh of platinum (Pt) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and the ±-alumina carrier is a carrier modified with a promoter comprising 1 to 10 parts by weight of cerium (Ce) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and wherein said catalyst is for steam reforming of a desulfurized hydrocarbon-containing gas.
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fullrecord <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_KR20170093127A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>KR20170093127A</sourcerecordid><originalsourceid>FETCH-epo_espacenet_KR20170093127A3</originalsourceid><addsrcrecordid>eNqNyrsKwkAQheFtLER9hwHrwCYpgqWIItipfRh3JxdIZpbdSZG3V9HSwurAf76l0ZsSjhCpkTj23IJDxWFOCq8A3eyjOIwP4cwJK_b8Ni2mz9USQ4jiJ6e9MGAIGFGnBMj-pxhJO_Frs2hwSLT57spsT8f74ZxRkJpSQEdMWl-uhc0ra3dlXlT78j_1BGxdRyY</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>Steam reforming catalyst for hydrocarbon-containing gas hydrogen production apparatus and hydrogen production method</title><source>esp@cenet</source><creator>NAKAMURA HIROSHI ; IDA JUNKO ; REICHINGER MARKUS ; ITAMI HIROHIKO</creator><creatorcontrib>NAKAMURA HIROSHI ; IDA JUNKO ; REICHINGER MARKUS ; ITAMI HIROHIKO</creatorcontrib><description>[과제] 수증기 존재 하에서 탄화수소 함유 가스의 수증기 개질하여 수소 가스를 얻기 위한 촉매로서, 수소 가스에 높은 전환율, 암모니아 가스와 탄소 석출을 방지하고 장시간 반응 내구성 우수하고 또한 저비용 화가 가능한 촉매를 제공한다. 본 발명 상기 과제는 탈황된 탄화수소 함유 가스를 수증기 개질하는 촉매로서 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 1 - 10 중량부 세륨 (Ce) 를 포함한 활성 보조 재료로 수식된 수식 담체에 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 0.1 - 0.3 중량부 로듐 (Rh)과 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 0.01 - 0.3 중량부의 백금 (Pt)을 포함하는 활성 금속을 담지한 수증기 개질 촉매에 의해 해결된다. Problem to be Solved To provide a catalyst for obtaining hydrogen gas by steam reforming of a hydrocarbon-containing gas in the presence of steam, the catalyst having a high ratio of conversion into hydrogen gas, being capable of preventing deposition of ammonia gas or carbon, having excellent stability even after being reacted for a long time, and allowing a reduction in costs. Solution The foregoing problem is solved by steam reforming catalyst, comprising active metals supported on an ±-alumina carrier, wherein the active metals comprise 0.1 to 0.3 parts by weight of rhodium (Rh) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and 0.01 to 0.3 parts by weigh of platinum (Pt) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and the ±-alumina carrier is a carrier modified with a promoter comprising 1 to 10 parts by weight of cerium (Ce) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and wherein said catalyst is for steam reforming of a desulfurized hydrocarbon-containing gas.</description><language>eng ; kor</language><subject>BASIC ELECTRIC ELEMENTS ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; COMPOUNDS THEREOF ; ELECTRICITY ; INORGANIC CHEMISTRY ; METALLURGY ; NON-METALLIC ELEMENTS ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2017</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20170814&amp;DB=EPODOC&amp;CC=KR&amp;NR=20170093127A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20170814&amp;DB=EPODOC&amp;CC=KR&amp;NR=20170093127A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>NAKAMURA HIROSHI</creatorcontrib><creatorcontrib>IDA JUNKO</creatorcontrib><creatorcontrib>REICHINGER MARKUS</creatorcontrib><creatorcontrib>ITAMI HIROHIKO</creatorcontrib><title>Steam reforming catalyst for hydrocarbon-containing gas hydrogen production apparatus and hydrogen production method</title><description>[과제] 수증기 존재 하에서 탄화수소 함유 가스의 수증기 개질하여 수소 가스를 얻기 위한 촉매로서, 수소 가스에 높은 전환율, 암모니아 가스와 탄소 석출을 방지하고 장시간 반응 내구성 우수하고 또한 저비용 화가 가능한 촉매를 제공한다. 본 발명 상기 과제는 탈황된 탄화수소 함유 가스를 수증기 개질하는 촉매로서 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 1 - 10 중량부 세륨 (Ce) 를 포함한 활성 보조 재료로 수식된 수식 담체에 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 0.1 - 0.3 중량부 로듐 (Rh)과 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 0.01 - 0.3 중량부의 백금 (Pt)을 포함하는 활성 금속을 담지한 수증기 개질 촉매에 의해 해결된다. Problem to be Solved To provide a catalyst for obtaining hydrogen gas by steam reforming of a hydrocarbon-containing gas in the presence of steam, the catalyst having a high ratio of conversion into hydrogen gas, being capable of preventing deposition of ammonia gas or carbon, having excellent stability even after being reacted for a long time, and allowing a reduction in costs. Solution The foregoing problem is solved by steam reforming catalyst, comprising active metals supported on an ±-alumina carrier, wherein the active metals comprise 0.1 to 0.3 parts by weight of rhodium (Rh) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and 0.01 to 0.3 parts by weigh of platinum (Pt) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and the ±-alumina carrier is a carrier modified with a promoter comprising 1 to 10 parts by weight of cerium (Ce) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and wherein said catalyst is for steam reforming of a desulfurized hydrocarbon-containing gas.</description><subject>BASIC ELECTRIC ELEMENTS</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>COMPOUNDS THEREOF</subject><subject>ELECTRICITY</subject><subject>INORGANIC CHEMISTRY</subject><subject>METALLURGY</subject><subject>NON-METALLIC ELEMENTS</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2017</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNyrsKwkAQheFtLER9hwHrwCYpgqWIItipfRh3JxdIZpbdSZG3V9HSwurAf76l0ZsSjhCpkTj23IJDxWFOCq8A3eyjOIwP4cwJK_b8Ni2mz9USQ4jiJ6e9MGAIGFGnBMj-pxhJO_Frs2hwSLT57spsT8f74ZxRkJpSQEdMWl-uhc0ra3dlXlT78j_1BGxdRyY</recordid><startdate>20170814</startdate><enddate>20170814</enddate><creator>NAKAMURA HIROSHI</creator><creator>IDA JUNKO</creator><creator>REICHINGER MARKUS</creator><creator>ITAMI HIROHIKO</creator><scope>EVB</scope></search><sort><creationdate>20170814</creationdate><title>Steam reforming catalyst for hydrocarbon-containing gas hydrogen production apparatus and hydrogen production method</title><author>NAKAMURA HIROSHI ; IDA JUNKO ; REICHINGER MARKUS ; ITAMI HIROHIKO</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_KR20170093127A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; kor</language><creationdate>2017</creationdate><topic>BASIC ELECTRIC ELEMENTS</topic><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>COMPOUNDS THEREOF</topic><topic>ELECTRICITY</topic><topic>INORGANIC CHEMISTRY</topic><topic>METALLURGY</topic><topic>NON-METALLIC ELEMENTS</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>NAKAMURA HIROSHI</creatorcontrib><creatorcontrib>IDA JUNKO</creatorcontrib><creatorcontrib>REICHINGER MARKUS</creatorcontrib><creatorcontrib>ITAMI HIROHIKO</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>NAKAMURA HIROSHI</au><au>IDA JUNKO</au><au>REICHINGER MARKUS</au><au>ITAMI HIROHIKO</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Steam reforming catalyst for hydrocarbon-containing gas hydrogen production apparatus and hydrogen production method</title><date>2017-08-14</date><risdate>2017</risdate><abstract>[과제] 수증기 존재 하에서 탄화수소 함유 가스의 수증기 개질하여 수소 가스를 얻기 위한 촉매로서, 수소 가스에 높은 전환율, 암모니아 가스와 탄소 석출을 방지하고 장시간 반응 내구성 우수하고 또한 저비용 화가 가능한 촉매를 제공한다. 본 발명 상기 과제는 탈황된 탄화수소 함유 가스를 수증기 개질하는 촉매로서 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 1 - 10 중량부 세륨 (Ce) 를 포함한 활성 보조 재료로 수식된 수식 담체에 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 0.1 - 0.3 중량부 로듐 (Rh)과 α-알루미나 담체 100 중량부에 대하여 금속 환산 시 0.01 - 0.3 중량부의 백금 (Pt)을 포함하는 활성 금속을 담지한 수증기 개질 촉매에 의해 해결된다. Problem to be Solved To provide a catalyst for obtaining hydrogen gas by steam reforming of a hydrocarbon-containing gas in the presence of steam, the catalyst having a high ratio of conversion into hydrogen gas, being capable of preventing deposition of ammonia gas or carbon, having excellent stability even after being reacted for a long time, and allowing a reduction in costs. Solution The foregoing problem is solved by steam reforming catalyst, comprising active metals supported on an ±-alumina carrier, wherein the active metals comprise 0.1 to 0.3 parts by weight of rhodium (Rh) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and 0.01 to 0.3 parts by weigh of platinum (Pt) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and the ±-alumina carrier is a carrier modified with a promoter comprising 1 to 10 parts by weight of cerium (Ce) based on the content of the metal, relative to 100 parts by weight of the ±-alumina carrier, and wherein said catalyst is for steam reforming of a desulfurized hydrocarbon-containing gas.</abstract><oa>free_for_read</oa></addata></record>
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subjects BASIC ELECTRIC ELEMENTS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS THEREOF
ELECTRICITY
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
THEIR RELEVANT APPARATUS
TRANSPORTING
title Steam reforming catalyst for hydrocarbon-containing gas hydrogen production apparatus and hydrogen production method
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