NON-AQUEOUS DISPERSION RESIN COMPOSITION AND PAINT COMPOSITION COMPRISING THE SAME
The present invention relates to a method for a nano-size non-aqueous dispersion resin and to a paint composition using the same. The non-aqueous dispersion resin according to the present invention is a resin synthesized by making caprolactone-modified acrylic monomer, an acrylic multifunctional mon...
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| creator | PARK, JONG MYUNG KIM, JUNG TEAG MIN, JAE KYU JUNG, HO SU |
| description | The present invention relates to a method for a nano-size non-aqueous dispersion resin and to a paint composition using the same. The non-aqueous dispersion resin according to the present invention is a resin synthesized by making caprolactone-modified acrylic monomer, an acrylic multifunctional monomer and an acrylic monofunctional monomer react in the presence of an initiator and a solvent via solution polymerization method, wherein the particle size of the resin is 100 nm or smaller. The non-aqueous dispersion resin according to the present invention reduces the VOCs of paint as the non-aqueous dispersion resin has viscosity lowered while exhibiting excellent miscibility with paint resin when added to the paint. In addition, the non-aqueous dispersion resin can improve the scratch resistance, acid resistance and chipping resistance of a membrane by being involved in curing reaction.
본 발명은 나노사이즈의 비수분산 수지의 제조방법 및 이를 이용한 도료조성물에 관한 것이다.본 발명에 따른 비수분산 수지는, 카프로락톤 변성 아크릴계 모노머, 에틸렌성 불포화기를 1개 갖는 아크릴계 모노머 및 에틸렌성 불포화기를 2개 이상 갖는 아크릴계 모노머를 개시제 및 용매 존재하에서 용액중합법을 통해서 반응시켜 합성된 수지로서, 상기 카프로락톤 변성 아크릴계 모노머는, 전체 모노머 함량에 대하여 30~99㏖%이고, 상기 에틸렌성 불포화기를 2개 이상 갖는 아크릴계 모노머는, 전체 모노머 함량에 대하여 1~20㏖%이며, 상기 수지 입자의 크기는 100㎚ 이하인 것을 특징으로 한다.본 발명에 따른 비수분산 수지는 도표에 첨가될 경우, 도료 수지와 양호한 상용성을 나타내면서 점도를 낮추어, 도료의 VOC를 저감시킬 뿐 아니라, 경화반응에 참여하여 도막의 내스크래치성, 내산성, 내치핑성을 개선할 수 있다. |
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본 발명은 나노사이즈의 비수분산 수지의 제조방법 및 이를 이용한 도료조성물에 관한 것이다.본 발명에 따른 비수분산 수지는, 카프로락톤 변성 아크릴계 모노머, 에틸렌성 불포화기를 1개 갖는 아크릴계 모노머 및 에틸렌성 불포화기를 2개 이상 갖는 아크릴계 모노머를 개시제 및 용매 존재하에서 용액중합법을 통해서 반응시켜 합성된 수지로서, 상기 카프로락톤 변성 아크릴계 모노머는, 전체 모노머 함량에 대하여 30~99㏖%이고, 상기 에틸렌성 불포화기를 2개 이상 갖는 아크릴계 모노머는, 전체 모노머 함량에 대하여 1~20㏖%이며, 상기 수지 입자의 크기는 100㎚ 이하인 것을 특징으로 한다.본 발명에 따른 비수분산 수지는 도표에 첨가될 경우, 도료 수지와 양호한 상용성을 나타내면서 점도를 낮추어, 도료의 VOC를 저감시킬 뿐 아니라, 경화반응에 참여하여 도막의 내스크래치성, 내산성, 내치핑성을 개선할 수 있다.</description><language>eng ; kor</language><subject>ADHESIVES ; CHEMICAL PAINT OR INK REMOVERS ; CHEMISTRY ; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS ; COMPOSITIONS BASED THEREON ; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS ; CORRECTING FLUIDS ; DYES ; FILLING PASTES ; INKS ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; ORGANIC MACROMOLECULAR COMPOUNDS ; PAINTS ; PASTES OR SOLIDS FOR COLOURING OR PRINTING ; POLISHES ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; USE OF MATERIALS THEREFOR ; WOODSTAINS</subject><creationdate>2014</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20140925&DB=EPODOC&CC=KR&NR=20140113766A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76289</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20140925&DB=EPODOC&CC=KR&NR=20140113766A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>PARK, JONG MYUNG</creatorcontrib><creatorcontrib>KIM, JUNG TEAG</creatorcontrib><creatorcontrib>MIN, JAE KYU</creatorcontrib><creatorcontrib>JUNG, HO SU</creatorcontrib><title>NON-AQUEOUS DISPERSION RESIN COMPOSITION AND PAINT COMPOSITION COMPRISING THE SAME</title><description>The present invention relates to a method for a nano-size non-aqueous dispersion resin and to a paint composition using the same. The non-aqueous dispersion resin according to the present invention is a resin synthesized by making caprolactone-modified acrylic monomer, an acrylic multifunctional monomer and an acrylic monofunctional monomer react in the presence of an initiator and a solvent via solution polymerization method, wherein the particle size of the resin is 100 nm or smaller. The non-aqueous dispersion resin according to the present invention reduces the VOCs of paint as the non-aqueous dispersion resin has viscosity lowered while exhibiting excellent miscibility with paint resin when added to the paint. In addition, the non-aqueous dispersion resin can improve the scratch resistance, acid resistance and chipping resistance of a membrane by being involved in curing reaction.
본 발명은 나노사이즈의 비수분산 수지의 제조방법 및 이를 이용한 도료조성물에 관한 것이다.본 발명에 따른 비수분산 수지는, 카프로락톤 변성 아크릴계 모노머, 에틸렌성 불포화기를 1개 갖는 아크릴계 모노머 및 에틸렌성 불포화기를 2개 이상 갖는 아크릴계 모노머를 개시제 및 용매 존재하에서 용액중합법을 통해서 반응시켜 합성된 수지로서, 상기 카프로락톤 변성 아크릴계 모노머는, 전체 모노머 함량에 대하여 30~99㏖%이고, 상기 에틸렌성 불포화기를 2개 이상 갖는 아크릴계 모노머는, 전체 모노머 함량에 대하여 1~20㏖%이며, 상기 수지 입자의 크기는 100㎚ 이하인 것을 특징으로 한다.본 발명에 따른 비수분산 수지는 도표에 첨가될 경우, 도료 수지와 양호한 상용성을 나타내면서 점도를 낮추어, 도료의 VOC를 저감시킬 뿐 아니라, 경화반응에 참여하여 도막의 내스크래치성, 내산성, 내치핑성을 개선할 수 있다.</description><subject>ADHESIVES</subject><subject>CHEMICAL PAINT OR INK REMOVERS</subject><subject>CHEMISTRY</subject><subject>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</subject><subject>CORRECTING FLUIDS</subject><subject>DYES</subject><subject>FILLING PASTES</subject><subject>INKS</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>NATURAL RESINS</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PAINTS</subject><subject>PASTES OR SOLIDS FOR COLOURING OR PRINTING</subject><subject>POLISHES</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>USE OF MATERIALS THEREFOR</subject><subject>WOODSTAINS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2014</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZAjy8_fTdQwMdfUPDVZw8QwOcA0K9vT3UwhyDfb0U3D29w3wD_YMAYk4-rkoBDh6-oWgiILYQZ5Ate4KIR6uCsGOvq48DKxpiTnFqbxQmptB2c01xNlDN7UgPz61uCAxOTUvtSTeO8jIwNDEwNDQ2NzMzNGYOFUA0ycw6A</recordid><startdate>20140925</startdate><enddate>20140925</enddate><creator>PARK, JONG MYUNG</creator><creator>KIM, JUNG TEAG</creator><creator>MIN, JAE KYU</creator><creator>JUNG, HO SU</creator><scope>EVB</scope></search><sort><creationdate>20140925</creationdate><title>NON-AQUEOUS DISPERSION RESIN COMPOSITION AND PAINT COMPOSITION COMPRISING THE SAME</title><author>PARK, JONG MYUNG ; KIM, JUNG TEAG ; MIN, JAE KYU ; JUNG, HO SU</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_KR20140113766A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; kor</language><creationdate>2014</creationdate><topic>ADHESIVES</topic><topic>CHEMICAL PAINT OR INK REMOVERS</topic><topic>CHEMISTRY</topic><topic>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</topic><topic>CORRECTING FLUIDS</topic><topic>DYES</topic><topic>FILLING PASTES</topic><topic>INKS</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>NATURAL RESINS</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PAINTS</topic><topic>PASTES OR SOLIDS FOR COLOURING OR PRINTING</topic><topic>POLISHES</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>USE OF MATERIALS THEREFOR</topic><topic>WOODSTAINS</topic><toplevel>online_resources</toplevel><creatorcontrib>PARK, JONG MYUNG</creatorcontrib><creatorcontrib>KIM, JUNG TEAG</creatorcontrib><creatorcontrib>MIN, JAE KYU</creatorcontrib><creatorcontrib>JUNG, HO SU</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>PARK, JONG MYUNG</au><au>KIM, JUNG TEAG</au><au>MIN, JAE KYU</au><au>JUNG, HO SU</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>NON-AQUEOUS DISPERSION RESIN COMPOSITION AND PAINT COMPOSITION COMPRISING THE SAME</title><date>2014-09-25</date><risdate>2014</risdate><abstract>The present invention relates to a method for a nano-size non-aqueous dispersion resin and to a paint composition using the same. The non-aqueous dispersion resin according to the present invention is a resin synthesized by making caprolactone-modified acrylic monomer, an acrylic multifunctional monomer and an acrylic monofunctional monomer react in the presence of an initiator and a solvent via solution polymerization method, wherein the particle size of the resin is 100 nm or smaller. The non-aqueous dispersion resin according to the present invention reduces the VOCs of paint as the non-aqueous dispersion resin has viscosity lowered while exhibiting excellent miscibility with paint resin when added to the paint. In addition, the non-aqueous dispersion resin can improve the scratch resistance, acid resistance and chipping resistance of a membrane by being involved in curing reaction.
본 발명은 나노사이즈의 비수분산 수지의 제조방법 및 이를 이용한 도료조성물에 관한 것이다.본 발명에 따른 비수분산 수지는, 카프로락톤 변성 아크릴계 모노머, 에틸렌성 불포화기를 1개 갖는 아크릴계 모노머 및 에틸렌성 불포화기를 2개 이상 갖는 아크릴계 모노머를 개시제 및 용매 존재하에서 용액중합법을 통해서 반응시켜 합성된 수지로서, 상기 카프로락톤 변성 아크릴계 모노머는, 전체 모노머 함량에 대하여 30~99㏖%이고, 상기 에틸렌성 불포화기를 2개 이상 갖는 아크릴계 모노머는, 전체 모노머 함량에 대하여 1~20㏖%이며, 상기 수지 입자의 크기는 100㎚ 이하인 것을 특징으로 한다.본 발명에 따른 비수분산 수지는 도표에 첨가될 경우, 도료 수지와 양호한 상용성을 나타내면서 점도를 낮추어, 도료의 VOC를 저감시킬 뿐 아니라, 경화반응에 참여하여 도막의 내스크래치성, 내산성, 내치핑성을 개선할 수 있다.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | ADHESIVES CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS CORRECTING FLUIDS DYES FILLING PASTES INKS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING POLISHES THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF MATERIALS THEREFOR WOODSTAINS |
| title | NON-AQUEOUS DISPERSION RESIN COMPOSITION AND PAINT COMPOSITION COMPRISING THE SAME |
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