METHOD FOR PREPARING SEGMENTED POLYOLEFIN COPOLYMERS

PURPOSE: A method for preparing segmented polyolefin copolymers is provided to easily synthesize segmented polyolefin copolymers through simple 2 step-reaction and to control a grafting efficiency as well as the length and number of a graft chain. CONSTITUTION: A method for preparing segmented polyo...

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Hauptverfasser: JOO, SANG IL, HONG, SUNG CHUL
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HONG, SUNG CHUL
description PURPOSE: A method for preparing segmented polyolefin copolymers is provided to easily synthesize segmented polyolefin copolymers through simple 2 step-reaction and to control a grafting efficiency as well as the length and number of a graft chain. CONSTITUTION: A method for preparing segmented polyolefin copolymers comprises the steps of: synthesizing vinyl polymers by polymerizing vinyl monomers using a trithiocarbonate-based chain transfer agent through a reversible addition-fragmentation chain transfer method; and grafting the synthesized vinyl polymer to the olefin polymer. The trithiocarbonate system chain transfer agent is a compound represented by chemical formula 1.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title METHOD FOR PREPARING SEGMENTED POLYOLEFIN COPOLYMERS
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