ORGANIC REACTION USING SOLID ACID CATALYST

PURPOSE:To carry out an organic reaction such as esterification, hydration, hydrolysis, etc. using a solid acid catalyst in a short time in high yield, by bringing a reaction raw material into contact with a solid acid catalyst first so that a liquid-phase reaction not followed by distillation is do...

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Hauptverfasser: CHIWA MAKOTO, IWATSUKA TAKESHI
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creator CHIWA MAKOTO
IWATSUKA TAKESHI
description PURPOSE:To carry out an organic reaction such as esterification, hydration, hydrolysis, etc. using a solid acid catalyst in a short time in high yield, by bringing a reaction raw material into contact with a solid acid catalyst first so that a liquid-phase reaction not followed by distillation is done, subjecting it to a gas-liquid phase reaction followed by distillation in the presence of a solid acid catalyst. CONSTITUTION:In carrying out an organic reaction using a solid acid catalyst, all or part of a reaction raw material is brought into contact with a solid acid catalyst (preferably strongly acidic cation exchange resin having
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CONSTITUTION:In carrying out an organic reaction using a solid acid catalyst, all or part of a reaction raw material is brought into contact with a solid acid catalyst (preferably strongly acidic cation exchange resin having &lt;=1mm. particle size in spherical or crushed state, or highly acidic cation exchange fiber having &lt;=100mu diameter) to do a gaseous-phase reaction not followed by distillation during the reaction. The reaction raw material after the liquid-phase reaction is subjected to a gas-liquid phase reaction followed by distillation during the reaction in the presence of a solid acid catalyst (preferably strongly acidic cation exchange fiber having &lt;=100mu diameter). When the residue of the reaction raw material remains, it is brought into contact with part of the raw material of the liquid-phase reaction by the latter gas-liquid phase reaction in counter flow to carry out the organic reaction. 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CONSTITUTION:In carrying out an organic reaction using a solid acid catalyst, all or part of a reaction raw material is brought into contact with a solid acid catalyst (preferably strongly acidic cation exchange resin having &lt;=1mm. particle size in spherical or crushed state, or highly acidic cation exchange fiber having &lt;=100mu diameter) to do a gaseous-phase reaction not followed by distillation during the reaction. The reaction raw material after the liquid-phase reaction is subjected to a gas-liquid phase reaction followed by distillation during the reaction in the presence of a solid acid catalyst (preferably strongly acidic cation exchange fiber having &lt;=100mu diameter). When the residue of the reaction raw material remains, it is brought into contact with part of the raw material of the liquid-phase reaction by the latter gas-liquid phase reaction in counter flow to carry out the organic reaction. 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CONSTITUTION:In carrying out an organic reaction using a solid acid catalyst, all or part of a reaction raw material is brought into contact with a solid acid catalyst (preferably strongly acidic cation exchange resin having &lt;=1mm. particle size in spherical or crushed state, or highly acidic cation exchange fiber having &lt;=100mu diameter) to do a gaseous-phase reaction not followed by distillation during the reaction. The reaction raw material after the liquid-phase reaction is subjected to a gas-liquid phase reaction followed by distillation during the reaction in the presence of a solid acid catalyst (preferably strongly acidic cation exchange fiber having &lt;=100mu diameter). When the residue of the reaction raw material remains, it is brought into contact with part of the raw material of the liquid-phase reaction by the latter gas-liquid phase reaction in counter flow to carry out the organic reaction. EFFECT:Merits are shown by combination of both means.</abstract><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title ORGANIC REACTION USING SOLID ACID CATALYST
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