PREPARATION OF TRANSPARENT RESIN HAVING HIGH REFRACTIVE INDEX

PURPOSE:To obtain a transparent resin having high refractive index, high impact strength, and low fluctuation of the refractive index, and suitable as various lenses, by melting or melting and solidifying a polymerizable compound having a specific structural formula and solid at normal temperature,...

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Hauptverfasser: IIDA NOBUHITO, SAKATA KANJI
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creator IIDA NOBUHITO
SAKATA KANJI
description PURPOSE:To obtain a transparent resin having high refractive index, high impact strength, and low fluctuation of the refractive index, and suitable as various lenses, by melting or melting and solidifying a polymerizable compound having a specific structural formula and solid at normal temperature, and polymerizing the compound under light irradiation. CONSTITUTION:The objective resin can be produced by (1) melting or melting and solidifying a polymerizable compound of formula (R is H or CH3; X is Cl or Br; n is 1 or 2; m is 1-4) which is a bifunctional monomer solid at normal temperature and generally insoluble in other polymerizable liquid compound at high concentration, (2) filling the compound in various molds, and (3) polymerizing under the radiation of light such as ultraviolet ray, visible light, etc. The polymerization is preferably carried out in the presence of
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CONSTITUTION:The objective resin can be produced by (1) melting or melting and solidifying a polymerizable compound of formula (R is H or CH3; X is Cl or Br; n is 1 or 2; m is 1-4) which is a bifunctional monomer solid at normal temperature and generally insoluble in other polymerizable liquid compound at high concentration, (2) filling the compound in various molds, and (3) polymerizing under the radiation of light such as ultraviolet ray, visible light, etc. The polymerization is preferably carried out in the presence of &lt;=2wt% of a polymerization accelerator. EFFECT:It has high degree of crosslinking and excellent hardness, and is free from internal strain. 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CONSTITUTION:The objective resin can be produced by (1) melting or melting and solidifying a polymerizable compound of formula (R is H or CH3; X is Cl or Br; n is 1 or 2; m is 1-4) which is a bifunctional monomer solid at normal temperature and generally insoluble in other polymerizable liquid compound at high concentration, (2) filling the compound in various molds, and (3) polymerizing under the radiation of light such as ultraviolet ray, visible light, etc. The polymerization is preferably carried out in the presence of &lt;=2wt% of a polymerization accelerator. EFFECT:It has high degree of crosslinking and excellent hardness, and is free from internal strain. USE:Glasses for sight correction etc.</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
CONTACT LENSES
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
OPTICAL ELEMENTS, SYSTEMS, OR APPARATUS
OPTICS
ORGANIC MACROMOLECULAR COMPOUNDS
PHYSICS
SPECTACLES
SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURESAS SPECTACLES
THEIR PREPARATION OR CHEMICAL WORKING-UP
title PREPARATION OF TRANSPARENT RESIN HAVING HIGH REFRACTIVE INDEX
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