7-CARBOXY-9,10-DIHYDROPHENANTHRENE DERIVATIVE

NEW MATERIAL:A 7-carboxy-9,10-dihydrophenanthrene derivative expressed by formulaI(R is H or acyl). EXAMPLE:2-(4'-n-Butylcyclohexylyloxy)-7-carboxy-9,10-dihydrophenanthrene. USE:A colorless intermediate raw material for namatic liquid crystals, useful as electrooptical display materials and sta...

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Bibliographische Detailangaben
Hauptverfasser: ARAI KAZUE, IIDA HIROTADA, YAMADA YOSHIJI, HORI BUNICHI, NAKANE HISASHI
Format: Patent
Sprache:eng
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Zusammenfassung:NEW MATERIAL:A 7-carboxy-9,10-dihydrophenanthrene derivative expressed by formulaI(R is H or acyl). EXAMPLE:2-(4'-n-Butylcyclohexylyloxy)-7-carboxy-9,10-dihydrophenanthrene. USE:A colorless intermediate raw material for namatic liquid crystals, useful as electrooptical display materials and stable to moisture, air, light, etc. PROCESS:A compound expressed by formula II as a starting raw material is passed through steps 1-7 to give a 2-hydroxy-7-carboxy-9,10-dihydrophenanthrene expressed by formula (G). The OH group at the 2-position of the resultant compound is then acylated to afford the aimed compound expressed by formulaI.