METHOD FOR RECOVERING TRANSURANIUM ELEMENT FROM SPENT NUCLEAR FUEL

PROBLEM TO BE SOLVED: To simplify the recovery step of transuraunium element and reduce waste solvent and wastes. SOLUTION: A spent nuclear fuel is dissolved in a nitrate acid (S100), the dissolved liquid is subject to electrolitic oxidation, and U, Np, Pu, and Am are oxidized at hexa valence by usi...

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Hauptverfasser: KIHARA YOSHIYUKI, TSUDOKORO AKIO, OKADA TAKASHI
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creator KIHARA YOSHIYUKI
TSUDOKORO AKIO
OKADA TAKASHI
description PROBLEM TO BE SOLVED: To simplify the recovery step of transuraunium element and reduce waste solvent and wastes. SOLUTION: A spent nuclear fuel is dissolved in a nitrate acid (S100), the dissolved liquid is subject to electrolitic oxidation, and U, Np, Pu, and Am are oxidized at hexa valence by using Ce as an oxidizing catalyst, and further they are cooled to crystallize a hexavalent nitrate salt and separate it from a mother liquor (S104). The mother liquor is heated and condensed (S114). The separated mixed deposit is dissolved in a nitrate once (S106) and only an uranyl nitrate is deposited by cooling it (S108), and then it is separated from a mixing liquid of U, Np, Pu, and Am (S110). The uranyl nitrate is dissolved in a nitrate acid (S112). The nitrate solution is added with the heated and condensed mother liquor to prepare a mixing solution. The mixing solution is electrolytically oxidixed so as to oxidize the remaining U, Np, Pu, and Am at hexa valence and cool them, thereby precipitate the remaining U, Np, Pu, and Am together thanks to uranyl nitrate and separating them from high-level radiation waste.
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The mixing solution is electrolytically oxidixed so as to oxidize the remaining U, Np, Pu, and Am at hexa valence and cool them, thereby precipitate the remaining U, Np, Pu, and Am together thanks to uranyl nitrate and separating them from high-level radiation waste.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record>
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subjects APPARATUS THEREFOR
CHEMISTRY
CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATERTREATMENT OR WASTE MANAGEMENT
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
DECONTAMINATION ARRANGEMENTS THEREFOR
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
INORGANIC CHEMISTRY
METALLURGY
NUCLEAR ENGINEERING
NUCLEAR PHYSICS
NUCLEAR REACTORS
PHYSICS
PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULARRADIATION OR PARTICLE BOMBARDMENT
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
TREATING RADIOACTIVELY CONTAMINATED MATERIAL
title METHOD FOR RECOVERING TRANSURANIUM ELEMENT FROM SPENT NUCLEAR FUEL
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