PHOSPHORIC ACID ESTER DERIVATIVE AND INSECTICIDAL MITICIDE CONTAINING THE DERIVATIVE

PURPOSE:To provide a new phosphoric acid ester derivative useful as an insecticidal miticide, having long residual effect of miticidal activity and extremely low toxicity to warm-blooded animal and exhibiting strong activity against insects and mites resistant to organic phosphorus pesticides. CONST...

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1. Verfasser: TAKAO HISASHI
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description PURPOSE:To provide a new phosphoric acid ester derivative useful as an insecticidal miticide, having long residual effect of miticidal activity and extremely low toxicity to warm-blooded animal and exhibiting strong activity against insects and mites resistant to organic phosphorus pesticides. CONSTITUTION:The compound of formula I (R to R are lower alkyl; X and X are H or halogen; Y is 0 or S), e.g. 0-ethyl S-n-propyl 0-[4-(alpha- trifluoromethyl-alpha-methoxy) methyl] phenyl phosphoro-thioate. The compound can be produced by reacting a phenol derivative of formula II with a phosphoric acid chloride of formula III in an organic solvent (e.g. benzere) in the presence of an acid acceptor (e.g. pyridine) usually at 0-50 deg.C. The compound of formula II used as a raw material is obtained e.g. by reacting a compound of formula IV with a compound of formula V in the presence of a base such as potassium carbonate.
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CONSTITUTION:The compound of formula I (R to R are lower alkyl; X and X are H or halogen; Y is 0 or S), e.g. 0-ethyl S-n-propyl 0-[4-(alpha- trifluoromethyl-alpha-methoxy) methyl] phenyl phosphoro-thioate. The compound can be produced by reacting a phenol derivative of formula II with a phosphoric acid chloride of formula III in an organic solvent (e.g. benzere) in the presence of an acid acceptor (e.g. pyridine) usually at 0-50 deg.C. 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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
AGRICULTURE
ANIMAL HUSBANDRY
BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES
CHEMISTRY
FISHING
FORESTRY
HUMAN NECESSITIES
HUNTING
METALLURGY
ORGANIC CHEMISTRY
PEST REPELLANTS OR ATTRACTANTS
PLANT GROWTH REGULATORS
PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF
TRAPPING
title PHOSPHORIC ACID ESTER DERIVATIVE AND INSECTICIDAL MITICIDE CONTAINING THE DERIVATIVE
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