PHOSPHORIC ACID ESTER DERIVATIVE AND INSECTICIDAL MITICIDE CONTAINING THE DERIVATIVE
PURPOSE:To provide a new phosphoric acid ester derivative useful as an insecticidal miticide, having long residual effect of miticidal activity and extremely low toxicity to warm-blooded animal and exhibiting strong activity against insects and mites resistant to organic phosphorus pesticides. CONST...
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creator | TAKAO HISASHI |
description | PURPOSE:To provide a new phosphoric acid ester derivative useful as an insecticidal miticide, having long residual effect of miticidal activity and extremely low toxicity to warm-blooded animal and exhibiting strong activity against insects and mites resistant to organic phosphorus pesticides. CONSTITUTION:The compound of formula I (R to R are lower alkyl; X and X are H or halogen; Y is 0 or S), e.g. 0-ethyl S-n-propyl 0-[4-(alpha- trifluoromethyl-alpha-methoxy) methyl] phenyl phosphoro-thioate. The compound can be produced by reacting a phenol derivative of formula II with a phosphoric acid chloride of formula III in an organic solvent (e.g. benzere) in the presence of an acid acceptor (e.g. pyridine) usually at 0-50 deg.C. The compound of formula II used as a raw material is obtained e.g. by reacting a compound of formula IV with a compound of formula V in the presence of a base such as potassium carbonate. |
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CONSTITUTION:The compound of formula I (R to R are lower alkyl; X and X are H or halogen; Y is 0 or S), e.g. 0-ethyl S-n-propyl 0-[4-(alpha- trifluoromethyl-alpha-methoxy) methyl] phenyl phosphoro-thioate. The compound can be produced by reacting a phenol derivative of formula II with a phosphoric acid chloride of formula III in an organic solvent (e.g. benzere) in the presence of an acid acceptor (e.g. pyridine) usually at 0-50 deg.C. The compound of formula II used as a raw material is obtained e.g. by reacting a compound of formula IV with a compound of formula V in the presence of a base such as potassium carbonate.</description><language>eng</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; AGRICULTURE ; ANIMAL HUSBANDRY ; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES ; CHEMISTRY ; FISHING ; FORESTRY ; HUMAN NECESSITIES ; HUNTING ; METALLURGY ; ORGANIC CHEMISTRY ; PEST REPELLANTS OR ATTRACTANTS ; PLANT GROWTH REGULATORS ; PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF ; TRAPPING</subject><creationdate>1992</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19921020&DB=EPODOC&CC=JP&NR=H04295489A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25563,76418</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19921020&DB=EPODOC&CC=JP&NR=H04295489A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>TAKAO HISASHI</creatorcontrib><title>PHOSPHORIC ACID ESTER DERIVATIVE AND INSECTICIDAL MITICIDE CONTAINING THE DERIVATIVE</title><description>PURPOSE:To provide a new phosphoric acid ester derivative useful as an insecticidal miticide, having long residual effect of miticidal activity and extremely low toxicity to warm-blooded animal and exhibiting strong activity against insects and mites resistant to organic phosphorus pesticides. CONSTITUTION:The compound of formula I (R to R are lower alkyl; X and X are H or halogen; Y is 0 or S), e.g. 0-ethyl S-n-propyl 0-[4-(alpha- trifluoromethyl-alpha-methoxy) methyl] phenyl phosphoro-thioate. The compound can be produced by reacting a phenol derivative of formula II with a phosphoric acid chloride of formula III in an organic solvent (e.g. benzere) in the presence of an acid acceptor (e.g. pyridine) usually at 0-50 deg.C. 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CONSTITUTION:The compound of formula I (R to R are lower alkyl; X and X are H or halogen; Y is 0 or S), e.g. 0-ethyl S-n-propyl 0-[4-(alpha- trifluoromethyl-alpha-methoxy) methyl] phenyl phosphoro-thioate. The compound can be produced by reacting a phenol derivative of formula II with a phosphoric acid chloride of formula III in an organic solvent (e.g. benzere) in the presence of an acid acceptor (e.g. pyridine) usually at 0-50 deg.C. The compound of formula II used as a raw material is obtained e.g. by reacting a compound of formula IV with a compound of formula V in the presence of a base such as potassium carbonate.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM AGRICULTURE ANIMAL HUSBANDRY BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES CHEMISTRY FISHING FORESTRY HUMAN NECESSITIES HUNTING METALLURGY ORGANIC CHEMISTRY PEST REPELLANTS OR ATTRACTANTS PLANT GROWTH REGULATORS PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF TRAPPING |
title | PHOSPHORIC ACID ESTER DERIVATIVE AND INSECTICIDAL MITICIDE CONTAINING THE DERIVATIVE |
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