PRODUCTION OF ALKYL AROMATIC HYDROCARBON FROM LOWER ISOOLEFIN

PURPOSE:To catalytically make lower olefin into a middle fraction containing a large amount of alkyl aromatic hydrocarbon almost without changing the aromatic hydrocarbon by bringing the lower isoolefin into contact with silica alumina catalyst in the presence of an aromatic hydrocarbon. CONSTITUTIO...

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Hauptverfasser: YAMANE MAMORU, HATAKEYAMA KOJI
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creator YAMANE MAMORU
HATAKEYAMA KOJI
description PURPOSE:To catalytically make lower olefin into a middle fraction containing a large amount of alkyl aromatic hydrocarbon almost without changing the aromatic hydrocarbon by bringing the lower isoolefin into contact with silica alumina catalyst in the presence of an aromatic hydrocarbon. CONSTITUTION:=10C alkyl aromatic hydrocarbon (B) by polymerization and ring formation of the isoolefin and alkylation. The amount of the reaction product B is at least four times as much as the amount of the consumption of the component A and at least 90% of the component A added at the initial stage is recovered. The component A and the lower isoolefin are fed in the weight ratio of 0.2-2.5/1 and a catalyst heat-treated under contact of steam and oxygen is used as the catalyst.
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CONSTITUTION:&lt;=7C isoolefin is brought into contact with silica alumina catalyst in the presence of 6-8C aromatic hydrocarbon (A) (e.g. benzene or toluene) at 90-220 deg.C under 0-50kg/cm G to give &gt;=10C alkyl aromatic hydrocarbon (B) by polymerization and ring formation of the isoolefin and alkylation. The amount of the reaction product B is at least four times as much as the amount of the consumption of the component A and at least 90% of the component A added at the initial stage is recovered. 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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title PRODUCTION OF ALKYL AROMATIC HYDROCARBON FROM LOWER ISOOLEFIN
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