JP2575430B
In a process for producing poly (p-phenylenesulfide) from an alkali metal sulfide and a p-dihalobenzene, a product polymer of an advantageously increased molecular weight is obtained by: providing a mixture comprising an alkali metal sulfide, a polar aprotic solvent, a sodium salt of an aliphatic ca...
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| creator | KATO RIICHI INOE HIROSHI OGAWARA KENSUKE |
| description | In a process for producing poly (p-phenylenesulfide) from an alkali metal sulfide and a p-dihalobenzene, a product polymer of an advantageously increased molecular weight is obtained by: providing a mixture comprising an alkali metal sulfide, a polar aprotic solvent, a sodium salt of an aliphatic carboxylic acid represented by the general formula: RCOONa (where R is an aliphtic hydrocarbon group having 1 - 20 carbon atoms), the content of water present in said mixture apart from any water of hydration or crystallization which may be contained in said sulfide and sodium salt being in the range of 5 to 20 moles per mole of said sulfide; removing at least part of the water from said mixture, preferably so as to at least partially dehydrate the said sulphide component; and then contacting the resulting dehydrated mixture with a p-dihalobenzene. |
| format | Patent |
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| subjects | CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
| title | JP2575430B |
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