RARE EARTH OXIDE POWDER

To provide a rare earth oxide fine powder capable of: being easily dispersed without an intense crushing process; forming a thin coating film; or obtaining a highly dispersed slurry without the use of a dispersing agent, thereby maintaining a stable transparency.SOLUTION: The present invention relat...

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Hauptverfasser: DAN MINAMI, KUBO MASAFUMI, NAGANO YUTARO
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KUBO MASAFUMI
NAGANO YUTARO
description To provide a rare earth oxide fine powder capable of: being easily dispersed without an intense crushing process; forming a thin coating film; or obtaining a highly dispersed slurry without the use of a dispersing agent, thereby maintaining a stable transparency.SOLUTION: The present invention relates to powder of oxides of a rare earth element other than Ce, which satisfies (a) or (b). (a) A primary particle diameter is 10 to 60 nm, satisfying (I) or (II). (I) D100 measured by ultrasonic dispersion is 1 to 10 μm. (II) When the true density is ρ, a difference between porosity PAD(%) calculated from the initial bulk density AD and porosity PTD(%) calculated from the tapped bulk density TD is 2.0 to 5.0%. PAD=(1-AD/ρ)×100 PTD=(1-TD/ρ)×100 (b). A primary particle size is 10 nm or larger and smaller than 100 nm, satisfying (III) and (IV). (III) A value obtained by multiplying a pore volume of 0.005 to 100 μm in pore diameter by the true density is 3 to 14. (IV) A value obtained by multiplying a pore volume of 5 to 50 nm in pore diameter by the true density is 0 to 2.0.SELECTED DRAWING: None 【課題】強度の解砕処理がなくても容易に分散でき、薄膜の塗膜が形成可能、或いは、分散剤を用いずに高分散スラリーが得られ透明度を安定維持できる、希土類酸化物微粉末を提供する。【解決手段】(a)又は(b)を満たす、Ce以外の希土類元素の酸化物の粉末。(a)一次粒子径が10~60nmで、(I)又は(II)を満たす。(I)超音波分散して測定したD100が1~10μm。(II)真密度をρとしたとき、初期嵩密度ADから算出される空隙率PAD(%)と、タップ嵩密度TDから算出される空隙率PTD(%)の差が2.0~5.0%。PAD=(1-AD/ρ)×100PTD=(1-TD/ρ)×100(b)一次粒子径が10nm以上100nm未満で、(III)及び(IV)を満たす。(III)細孔直径0.005~100μmの細孔容積に真密度を掛けた値が3~14。(IV)細孔直径5~50nmの細孔容積に真密度を掛けた値が0~2.0。【選択図】なし
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(a) A primary particle diameter is 10 to 60 nm, satisfying (I) or (II). (I) D100 measured by ultrasonic dispersion is 1 to 10 μm. (II) When the true density is ρ, a difference between porosity PAD(%) calculated from the initial bulk density AD and porosity PTD(%) calculated from the tapped bulk density TD is 2.0 to 5.0%. PAD=(1-AD/ρ)×100 PTD=(1-TD/ρ)×100 (b). A primary particle size is 10 nm or larger and smaller than 100 nm, satisfying (III) and (IV). (III) A value obtained by multiplying a pore volume of 0.005 to 100 μm in pore diameter by the true density is 3 to 14. (IV) A value obtained by multiplying a pore volume of 5 to 50 nm in pore diameter by the true density is 0 to 2.0.SELECTED DRAWING: None 【課題】強度の解砕処理がなくても容易に分散でき、薄膜の塗膜が形成可能、或いは、分散剤を用いずに高分散スラリーが得られ透明度を安定維持できる、希土類酸化物微粉末を提供する。【解決手段】(a)又は(b)を満たす、Ce以外の希土類元素の酸化物の粉末。(a)一次粒子径が10~60nmで、(I)又は(II)を満たす。(I)超音波分散して測定したD100が1~10μm。(II)真密度をρとしたとき、初期嵩密度ADから算出される空隙率PAD(%)と、タップ嵩密度TDから算出される空隙率PTD(%)の差が2.0~5.0%。PAD=(1-AD/ρ)×100PTD=(1-TD/ρ)×100(b)一次粒子径が10nm以上100nm未満で、(III)及び(IV)を満たす。(III)細孔直径0.005~100μmの細孔容積に真密度を掛けた値が3~14。(IV)細孔直径5~50nmの細孔容積に真密度を掛けた値が0~2.0。【選択図】なし</description><language>eng ; jpn</language><subject>CHEMISTRY ; COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM,CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THERARE-EARTH METALS ; INORGANIC CHEMISTRY ; METALLURGY</subject><creationdate>2024</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20240709&amp;DB=EPODOC&amp;CC=JP&amp;NR=2024094356A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20240709&amp;DB=EPODOC&amp;CC=JP&amp;NR=2024094356A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>DAN MINAMI</creatorcontrib><creatorcontrib>KUBO MASAFUMI</creatorcontrib><creatorcontrib>NAGANO YUTARO</creatorcontrib><title>RARE EARTH OXIDE POWDER</title><description>To provide a rare earth oxide fine powder capable of: being easily dispersed without an intense crushing process; forming a thin coating film; or obtaining a highly dispersed slurry without the use of a dispersing agent, thereby maintaining a stable transparency.SOLUTION: The present invention relates to powder of oxides of a rare earth element other than Ce, which satisfies (a) or (b). 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(a) A primary particle diameter is 10 to 60 nm, satisfying (I) or (II). (I) D100 measured by ultrasonic dispersion is 1 to 10 μm. (II) When the true density is ρ, a difference between porosity PAD(%) calculated from the initial bulk density AD and porosity PTD(%) calculated from the tapped bulk density TD is 2.0 to 5.0%. PAD=(1-AD/ρ)×100 PTD=(1-TD/ρ)×100 (b). A primary particle size is 10 nm or larger and smaller than 100 nm, satisfying (III) and (IV). (III) A value obtained by multiplying a pore volume of 0.005 to 100 μm in pore diameter by the true density is 3 to 14. (IV) A value obtained by multiplying a pore volume of 5 to 50 nm in pore diameter by the true density is 0 to 2.0.SELECTED DRAWING: None 【課題】強度の解砕処理がなくても容易に分散でき、薄膜の塗膜が形成可能、或いは、分散剤を用いずに高分散スラリーが得られ透明度を安定維持できる、希土類酸化物微粉末を提供する。【解決手段】(a)又は(b)を満たす、Ce以外の希土類元素の酸化物の粉末。(a)一次粒子径が10~60nmで、(I)又は(II)を満たす。(I)超音波分散して測定したD100が1~10μm。(II)真密度をρとしたとき、初期嵩密度ADから算出される空隙率PAD(%)と、タップ嵩密度TDから算出される空隙率PTD(%)の差が2.0~5.0%。PAD=(1-AD/ρ)×100PTD=(1-TD/ρ)×100(b)一次粒子径が10nm以上100nm未満で、(III)及び(IV)を満たす。(III)細孔直径0.005~100μmの細孔容積に真密度を掛けた値が3~14。(IV)細孔直径5~50nmの細孔容積に真密度を掛けた値が0~2.0。【選択図】なし</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMISTRY
COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM,CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THERARE-EARTH METALS
INORGANIC CHEMISTRY
METALLURGY
title RARE EARTH OXIDE POWDER
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