COMPOUND WITH CYCLIC MOLECULE FUSED WITH AXIAL MOLECULE, [C2]DAISY-CHAIN ROTAXANE, AND POLYMER COMPRISING [C2]DAISY-CHAIN ROTAXANE, AND METHOD FOR PRODUCING THE SAME

To provide a polymer containing [c2]daisy-chain rotaxane with superior compression resistance, a compound therefor where a novel cyclic molecule has been fused with an axial molecule, and [c2]daisy-chain rotaxane.SOLUTION: By utilizing a thiol-ene reaction between [c2]daisy-chain rotaxane containing...

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Hauptverfasser:	KAMOTO RISAKO, YAMABUKI KAZUHIRO
Format:	Patent
Sprache:	eng ; jpn
Schlagworte:	CHEMISTRY COMPOSITIONS BASED THEREON HETEROCYCLIC COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP
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Zusammenfassung:	To provide a polymer containing [c2]daisy-chain rotaxane with superior compression resistance, a compound therefor where a novel cyclic molecule has been fused with an axial molecule, and [c2]daisy-chain rotaxane.SOLUTION: By utilizing a thiol-ene reaction between [c2]daisy-chain rotaxane containing a compound where a cyclic molecule with a double bond introduced at the end of an axial molecule has been fused with the axial molecule, and a crosslinker containing a thiol group at the end, a polymer containing the [c2]daisy-chain rotaxane is synthesized, thereby forming a gel-like solid of a network polymer with compression resistance.SELECTED DRAWING: Figure 2 【課題】耐圧縮性に優れた挿し違い型ロタキサンを含むポリマー、そのための新規環状分子と軸状分子とが一体となった化合物、及び挿し違い型ロタキサンを提供する。【解決手段】軸状分子の末端に二重結合を導入した環状分子と軸状分子とが一体となった化合物を含む挿し違い型ロタキサンと、末端にチオール基を有する架橋剤とのチオール－エン反応により、挿し違い型ロタキサンを含むポリマーを合成し、耐圧縮性を備える網目状ポリマーのゲル状固体を形成する。【選択図】図２