METHOD OF PRODUCING HYDROXYALKYLSILANE COMPOUND

METHOD OF PRODUCING HYDROXYALKYLSILANE COMPOUND

To provide a method of producing a hydroxyalkylsilane compound in good yield with a mild condition.SOLUTION: A method of producing a hydroxyalkylsilane compound includes the processes of: performing nucleophilic substitution reaction between a compound (1) and a compound (2) to obtain a compound (3)...

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Hauptverfasser: KIYOMORI AYUMI, AOKI SHOTARO
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ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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AOKI SHOTARO
description To provide a method of producing a hydroxyalkylsilane compound in good yield with a mild condition.SOLUTION: A method of producing a hydroxyalkylsilane compound includes the processes of: performing nucleophilic substitution reaction between a compound (1) and a compound (2) to obtain a compound (3); performing hydrolysis reaction by mixing water having a pH of 1-7 to obtain a mixture containing the compound (3); removing a by-product by distillation; and performing desilylation reaction by mixing a mixture after distillation with water or an alcohol compound to obtain a compound (4). X is a halogen atom, R1 is a 1-10C linear or branched-chain bivalent hydrocarbon group, m is each independently 0 or 1, M is Li when m is 0, M is Mg when m is 1, R2-R4 are each independently H, or a 1-10 C linear, branched-chain or cyclic univalent hydrocarbon group, and Y is a halogen atom, or a 1-6C alkoxy group.SELECTED DRAWING: None 【課題】ヒドロキシアルキルシラン化合物を、温和な条件で収率良く製造できる方法を提供する。【解決手段】化合物（１）と化合物（２）との求核置換反応を行い化合物（３）を得る工程、次いでｐＨ１～７の水を混合し加水分解反応を行い化合物（３）を含む混合物を得る工程、蒸留により副生成物を除去する工程、蒸留後の混合物と水又はアルコール化合物を混合して脱シリル化反応を行い化合物（４）を得る工程を含む。TIFF2022171026000017.tif1067TIFF2022171026000018.tif667TIFF2022171026000019.tif967TIFF2022171026000020.tif967（Ｘはハロゲン原子；Ｒ１はＣ１～１０の直鎖状又は分岐鎖状の２価炭化水素基；ｍは各々独立に０又は１；ｍが０の場合ＭはＬｉ；ｍが１の場合ＭはＭｇ；Ｒ２～Ｒ４は各々独立にＨ又はＣ１～１０の直鎖状、分岐鎖状もしくは環状の１価炭化水素基；Ｙはハロゲン原子又はＣ１～６のアルコキシ基）【選択図】なし
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title METHOD OF PRODUCING HYDROXYALKYLSILANE COMPOUND
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