EXHAUST GAS PURIFICATION THREE-WAY CATALYST

PROBLEM TO BE SOLVED: To provide an exhaust gas purification three-way catalyst having an excellent three-way purification performance in a wide temperature window range from a low temperature region to a high temperature region without using an expensive noble metal which is a rare metal compared w...

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Hauptverfasser: HASHIMOTO MASASATO, MATSUZONO YOSHIAKI, NAKATSUJI TADAO
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creator HASHIMOTO MASASATO
MATSUZONO YOSHIAKI
NAKATSUJI TADAO
description PROBLEM TO BE SOLVED: To provide an exhaust gas purification three-way catalyst having an excellent three-way purification performance in a wide temperature window range from a low temperature region to a high temperature region without using an expensive noble metal which is a rare metal compared with a conventional three way catalyst, which is brought into contact with combustion exhaust gas containing carbon monoxide, hydrocarbons, and a nitrogen oxide generated by combustion of a fuel near the stoichiometric mixing ratio of air and a fuel to catalytically purify the three components.SOLUTION: There is provided a first catalyst which comprises (A) 1 to 20 wt.% of copper, (B) 0.1 to 10 wt.% of at least one element selected from zirconium, tin, silicon, yttrium, lanthanum, praseodymium and gadolinium and (C) γ-alumina, based on the total weight of catalyst components. There is provided a second catalyst which comprises 1 to 20 wt.% of copper and iron (provided that the atomic ratio Fe/Cu is in the range of 0.1 to 1) instead of 1 to 20 wt.% of the copper.SELECTED DRAWING: None 【課題】空気と燃料の量論混合比近傍において、燃料の燃焼によって生成する一酸化炭素、炭化水素類及び窒素酸化物を含有する燃焼排ガスを接触させて、上記3成分を接触的に浄化するための三元触媒であって、これまでの三元触媒に比べて、希少金属である高価な貴金属を用いることなく、それでいて、低温域から高温域にわたって広い温度ウィンドウ範囲ですぐれた三元浄化性能を有する排ガス浄化三元触媒を提供する。【解決手段】本発明による第1の触媒は、触媒成分の全重量に基づいて、(A)銅1〜20重量%、(B)ジルコニウム、スズ、ケイ素、イットリウム、ランタン、プラセオジム及びガドリニウムから選ばれる少なくとも1種の元素0.1〜10重量%及び(C)γ−アルミナを含む。第2の触媒は、上記銅1〜20重量%に代えて、銅1〜20重量%と鉄(但し、Fe/Cu原子比は0.1〜1の範囲である。)を含む。【選択図】なし
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There is provided a second catalyst which comprises 1 to 20 wt.% of copper and iron (provided that the atomic ratio Fe/Cu is in the range of 0.1 to 1) instead of 1 to 20 wt.% of the copper.SELECTED DRAWING: None 【課題】空気と燃料の量論混合比近傍において、燃料の燃焼によって生成する一酸化炭素、炭化水素類及び窒素酸化物を含有する燃焼排ガスを接触させて、上記3成分を接触的に浄化するための三元触媒であって、これまでの三元触媒に比べて、希少金属である高価な貴金属を用いることなく、それでいて、低温域から高温域にわたって広い温度ウィンドウ範囲ですぐれた三元浄化性能を有する排ガス浄化三元触媒を提供する。【解決手段】本発明による第1の触媒は、触媒成分の全重量に基づいて、(A)銅1〜20重量%、(B)ジルコニウム、スズ、ケイ素、イットリウム、ランタン、プラセオジム及びガドリニウムから選ばれる少なくとも1種の元素0.1〜10重量%及び(C)γ−アルミナを含む。第2の触媒は、上記銅1〜20重量%に代えて、銅1〜20重量%と鉄(但し、Fe/Cu原子比は0.1〜1の範囲である。)を含む。【選択図】なし</description><language>eng ; jpn</language><subject>BLASTING ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; ENGINE PLANTS IN GENERAL ; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNALCOMBUSTION ENGINES ; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES ORENGINES IN GENERAL ; HEATING ; LIGHTING ; MACHINES OR ENGINES IN GENERAL ; MECHANICAL ENGINEERING ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; SEPARATION ; STEAM ENGINES ; THEIR RELEVANT APPARATUS ; TRANSPORTING ; WEAPONS</subject><creationdate>2016</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20160901&amp;DB=EPODOC&amp;CC=JP&amp;NR=2016155049A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25544,76292</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20160901&amp;DB=EPODOC&amp;CC=JP&amp;NR=2016155049A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>HASHIMOTO MASASATO</creatorcontrib><creatorcontrib>MATSUZONO YOSHIAKI</creatorcontrib><creatorcontrib>NAKATSUJI TADAO</creatorcontrib><title>EXHAUST GAS PURIFICATION THREE-WAY CATALYST</title><description>PROBLEM TO BE SOLVED: To provide an exhaust gas purification three-way catalyst having an excellent three-way purification performance in a wide temperature window range from a low temperature region to a high temperature region without using an expensive noble metal which is a rare metal compared with a conventional three way catalyst, which is brought into contact with combustion exhaust gas containing carbon monoxide, hydrocarbons, and a nitrogen oxide generated by combustion of a fuel near the stoichiometric mixing ratio of air and a fuel to catalytically purify the three components.SOLUTION: There is provided a first catalyst which comprises (A) 1 to 20 wt.% of copper, (B) 0.1 to 10 wt.% of at least one element selected from zirconium, tin, silicon, yttrium, lanthanum, praseodymium and gadolinium and (C) γ-alumina, based on the total weight of catalyst components. There is provided a second catalyst which comprises 1 to 20 wt.% of copper and iron (provided that the atomic ratio Fe/Cu is in the range of 0.1 to 1) instead of 1 to 20 wt.% of the copper.SELECTED DRAWING: None 【課題】空気と燃料の量論混合比近傍において、燃料の燃焼によって生成する一酸化炭素、炭化水素類及び窒素酸化物を含有する燃焼排ガスを接触させて、上記3成分を接触的に浄化するための三元触媒であって、これまでの三元触媒に比べて、希少金属である高価な貴金属を用いることなく、それでいて、低温域から高温域にわたって広い温度ウィンドウ範囲ですぐれた三元浄化性能を有する排ガス浄化三元触媒を提供する。【解決手段】本発明による第1の触媒は、触媒成分の全重量に基づいて、(A)銅1〜20重量%、(B)ジルコニウム、スズ、ケイ素、イットリウム、ランタン、プラセオジム及びガドリニウムから選ばれる少なくとも1種の元素0.1〜10重量%及び(C)γ−アルミナを含む。第2の触媒は、上記銅1〜20重量%に代えて、銅1〜20重量%と鉄(但し、Fe/Cu原子比は0.1〜1の範囲である。)を含む。【選択図】なし</description><subject>BLASTING</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>ENGINE PLANTS IN GENERAL</subject><subject>GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNALCOMBUSTION ENGINES</subject><subject>GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES ORENGINES IN GENERAL</subject><subject>HEATING</subject><subject>LIGHTING</subject><subject>MACHINES OR ENGINES IN GENERAL</subject><subject>MECHANICAL ENGINEERING</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>SEPARATION</subject><subject>STEAM ENGINES</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><subject>WEAPONS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2016</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZNB2jfBwDA0OUXB3DFYICA3ydPN0dgzx9PdTCPEIcnXVDXeMVAAKOPpEBofwMLCmJeYUp_JCaW4GJTfXEGcP3dSC_PjU4oLE5NS81JJ4rwAjA0MzQ1NTAxNLR2OiFAEA0YwljQ</recordid><startdate>20160901</startdate><enddate>20160901</enddate><creator>HASHIMOTO MASASATO</creator><creator>MATSUZONO YOSHIAKI</creator><creator>NAKATSUJI TADAO</creator><scope>EVB</scope></search><sort><creationdate>20160901</creationdate><title>EXHAUST GAS PURIFICATION THREE-WAY CATALYST</title><author>HASHIMOTO MASASATO ; MATSUZONO YOSHIAKI ; NAKATSUJI TADAO</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_JP2016155049A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; jpn</language><creationdate>2016</creationdate><topic>BLASTING</topic><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>ENGINE PLANTS IN GENERAL</topic><topic>GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNALCOMBUSTION ENGINES</topic><topic>GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES ORENGINES IN GENERAL</topic><topic>HEATING</topic><topic>LIGHTING</topic><topic>MACHINES OR ENGINES IN GENERAL</topic><topic>MECHANICAL ENGINEERING</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>SEPARATION</topic><topic>STEAM ENGINES</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><topic>WEAPONS</topic><toplevel>online_resources</toplevel><creatorcontrib>HASHIMOTO MASASATO</creatorcontrib><creatorcontrib>MATSUZONO YOSHIAKI</creatorcontrib><creatorcontrib>NAKATSUJI TADAO</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>HASHIMOTO MASASATO</au><au>MATSUZONO YOSHIAKI</au><au>NAKATSUJI TADAO</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>EXHAUST GAS PURIFICATION THREE-WAY CATALYST</title><date>2016-09-01</date><risdate>2016</risdate><abstract>PROBLEM TO BE SOLVED: To provide an exhaust gas purification three-way catalyst having an excellent three-way purification performance in a wide temperature window range from a low temperature region to a high temperature region without using an expensive noble metal which is a rare metal compared with a conventional three way catalyst, which is brought into contact with combustion exhaust gas containing carbon monoxide, hydrocarbons, and a nitrogen oxide generated by combustion of a fuel near the stoichiometric mixing ratio of air and a fuel to catalytically purify the three components.SOLUTION: There is provided a first catalyst which comprises (A) 1 to 20 wt.% of copper, (B) 0.1 to 10 wt.% of at least one element selected from zirconium, tin, silicon, yttrium, lanthanum, praseodymium and gadolinium and (C) γ-alumina, based on the total weight of catalyst components. There is provided a second catalyst which comprises 1 to 20 wt.% of copper and iron (provided that the atomic ratio Fe/Cu is in the range of 0.1 to 1) instead of 1 to 20 wt.% of the copper.SELECTED DRAWING: None 【課題】空気と燃料の量論混合比近傍において、燃料の燃焼によって生成する一酸化炭素、炭化水素類及び窒素酸化物を含有する燃焼排ガスを接触させて、上記3成分を接触的に浄化するための三元触媒であって、これまでの三元触媒に比べて、希少金属である高価な貴金属を用いることなく、それでいて、低温域から高温域にわたって広い温度ウィンドウ範囲ですぐれた三元浄化性能を有する排ガス浄化三元触媒を提供する。【解決手段】本発明による第1の触媒は、触媒成分の全重量に基づいて、(A)銅1〜20重量%、(B)ジルコニウム、スズ、ケイ素、イットリウム、ランタン、プラセオジム及びガドリニウムから選ばれる少なくとも1種の元素0.1〜10重量%及び(C)γ−アルミナを含む。第2の触媒は、上記銅1〜20重量%に代えて、銅1〜20重量%と鉄(但し、Fe/Cu原子比は0.1〜1の範囲である。)を含む。【選択図】なし</abstract><oa>free_for_read</oa></addata></record>
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subjects BLASTING
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
ENGINE PLANTS IN GENERAL
GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNALCOMBUSTION ENGINES
GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES ORENGINES IN GENERAL
HEATING
LIGHTING
MACHINES OR ENGINES IN GENERAL
MECHANICAL ENGINEERING
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
STEAM ENGINES
THEIR RELEVANT APPARATUS
TRANSPORTING
WEAPONS
title EXHAUST GAS PURIFICATION THREE-WAY CATALYST
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