Ga2O3 BASED SINGLE CRYSTAL SUBSTRATE AND CRYSTAL LAMINATED STRUCTURE

PROBLEM TO BE SOLVED: To provide a -GaObased single crystal substrate in which variation of donor concentration is suppressed under a reduction atmosphere or an inert gas atmosphere, and a crystal laminated structure capable of epitaxially growing a high quality crystal film having small variation i...

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Hauptverfasser: UJIIE TAKEKAZU, YAMAOKA MASARU
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YAMAOKA MASARU
description PROBLEM TO BE SOLVED: To provide a -GaObased single crystal substrate in which variation of donor concentration is suppressed under a reduction atmosphere or an inert gas atmosphere, and a crystal laminated structure capable of epitaxially growing a high quality crystal film having small variation in quality under the reduction atmosphere or the inert gas atmosphere.SOLUTION: The -GaObased single crystal substrate has a donor concentration corresponding to an added concentration of Si, Hf, Ge,Sn, Ti or Zr as an IV group element or an added concentration of two or more kinds of the IV group elements, the donor concentration increasing along a linear straight line having a predetermined inclination according to increase of the concentration of the IV group element in logarithm rectangular coordinates using the concentration of the IV group element as a horizontal axis and using the donor concentration as a vertical axis. The crystal laminated structure includes a GaN based epitaxial crystal film formed on the -GaObased single crystal substrate. 【課題】還元雰囲気や不活性ガス雰囲気下におけるドナー濃度の変化が抑えられたβ−Ga2O3系単結晶基板、及び還元雰囲気や不活性ガス雰囲気下において品質のばらつきの小さい高品質な結晶膜をエピタキシャル成長させることのできる結晶積層構造体を提供する。【解決手段】IV族元素としてのSi、Hf、Ge、Sn、Ti、あるいはZrが添加された濃度、あるいは2種以上の前記IV族元素が添加された濃度に応じたドナー濃度を有するβ−Ga2O3系単結晶基板であって、前記IV族元素の濃度を横軸に取り、前記ドナー濃度を縦軸に取った対数直交座標において、前記ドナー濃度が、前記IV族元素の濃度の増加に応じて所定の傾斜を有した正比例直線に沿って増加されたβ−Ga2O3系単結晶基板、及び前記β−Ga2O3系単結晶基板上に形成されたGaN系エピタキシャル結晶膜を含む結晶積層構造体を提供する。【選択図】図1
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fullrecord <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_JP2014210707A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>JP2014210707A</sourcerecordid><originalsourceid>FETCH-epo_espacenet_JP2014210707A3</originalsourceid><addsrcrecordid>eNrjZHBxTzTyN1Zwcgx2dVEI9vRz93FVcA6KDA5x9FEIDnUKDglyDHFVcPRzgYv6OPp6-gEFgcpDgkKdQ0KDXHkYWNMSc4pTeaE0N4OSm2uIs4duakF-fGpxQWJyal5qSbxXgJGBoYmRoYG5gbmjMVGKAK49LEA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>Ga2O3 BASED SINGLE CRYSTAL SUBSTRATE AND CRYSTAL LAMINATED STRUCTURE</title><source>esp@cenet</source><creator>UJIIE TAKEKAZU ; YAMAOKA MASARU</creator><creatorcontrib>UJIIE TAKEKAZU ; YAMAOKA MASARU</creatorcontrib><description>PROBLEM TO BE SOLVED: To provide a -GaObased single crystal substrate in which variation of donor concentration is suppressed under a reduction atmosphere or an inert gas atmosphere, and a crystal laminated structure capable of epitaxially growing a high quality crystal film having small variation in quality under the reduction atmosphere or the inert gas atmosphere.SOLUTION: The -GaObased single crystal substrate has a donor concentration corresponding to an added concentration of Si, Hf, Ge,Sn, Ti or Zr as an IV group element or an added concentration of two or more kinds of the IV group elements, the donor concentration increasing along a linear straight line having a predetermined inclination according to increase of the concentration of the IV group element in logarithm rectangular coordinates using the concentration of the IV group element as a horizontal axis and using the donor concentration as a vertical axis. The crystal laminated structure includes a GaN based epitaxial crystal film formed on the -GaObased single crystal substrate. 【課題】還元雰囲気や不活性ガス雰囲気下におけるドナー濃度の変化が抑えられたβ−Ga2O3系単結晶基板、及び還元雰囲気や不活性ガス雰囲気下において品質のばらつきの小さい高品質な結晶膜をエピタキシャル成長させることのできる結晶積層構造体を提供する。【解決手段】IV族元素としてのSi、Hf、Ge、Sn、Ti、あるいはZrが添加された濃度、あるいは2種以上の前記IV族元素が添加された濃度に応じたドナー濃度を有するβ−Ga2O3系単結晶基板であって、前記IV族元素の濃度を横軸に取り、前記ドナー濃度を縦軸に取った対数直交座標において、前記ドナー濃度が、前記IV族元素の濃度の増加に応じて所定の傾斜を有した正比例直線に沿って増加されたβ−Ga2O3系単結晶基板、及び前記β−Ga2O3系単結晶基板上に形成されたGaN系エピタキシャル結晶膜を含む結晶積層構造体を提供する。【選択図】図1</description><language>eng ; jpn</language><subject>AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUSPOLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE ; APPARATUS THEREFOR ; BASIC ELECTRIC ELEMENTS ; CHEMICAL SURFACE TREATMENT ; CHEMISTRY ; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATIONOR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL ; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY IONIMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL ; COATING MATERIAL WITH METALLIC MATERIAL ; COATING METALLIC MATERIAL ; CRYSTAL GROWTH ; DIFFUSION TREATMENT OF METALLIC MATERIAL ; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR ; ELECTRICITY ; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION INGENERAL ; METALLURGY ; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE ; REFINING BY ZONE-MELTING OF MATERIAL ; SEMICONDUCTOR DEVICES ; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE ; SINGLE-CRYSTAL-GROWTH ; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THESURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION ; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL ORUNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL</subject><creationdate>2014</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20141113&amp;DB=EPODOC&amp;CC=JP&amp;NR=2014210707A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20141113&amp;DB=EPODOC&amp;CC=JP&amp;NR=2014210707A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>UJIIE TAKEKAZU</creatorcontrib><creatorcontrib>YAMAOKA MASARU</creatorcontrib><title>Ga2O3 BASED SINGLE CRYSTAL SUBSTRATE AND CRYSTAL LAMINATED STRUCTURE</title><description>PROBLEM TO BE SOLVED: To provide a -GaObased single crystal substrate in which variation of donor concentration is suppressed under a reduction atmosphere or an inert gas atmosphere, and a crystal laminated structure capable of epitaxially growing a high quality crystal film having small variation in quality under the reduction atmosphere or the inert gas atmosphere.SOLUTION: The -GaObased single crystal substrate has a donor concentration corresponding to an added concentration of Si, Hf, Ge,Sn, Ti or Zr as an IV group element or an added concentration of two or more kinds of the IV group elements, the donor concentration increasing along a linear straight line having a predetermined inclination according to increase of the concentration of the IV group element in logarithm rectangular coordinates using the concentration of the IV group element as a horizontal axis and using the donor concentration as a vertical axis. The crystal laminated structure includes a GaN based epitaxial crystal film formed on the -GaObased single crystal substrate. 【課題】還元雰囲気や不活性ガス雰囲気下におけるドナー濃度の変化が抑えられたβ−Ga2O3系単結晶基板、及び還元雰囲気や不活性ガス雰囲気下において品質のばらつきの小さい高品質な結晶膜をエピタキシャル成長させることのできる結晶積層構造体を提供する。【解決手段】IV族元素としてのSi、Hf、Ge、Sn、Ti、あるいはZrが添加された濃度、あるいは2種以上の前記IV族元素が添加された濃度に応じたドナー濃度を有するβ−Ga2O3系単結晶基板であって、前記IV族元素の濃度を横軸に取り、前記ドナー濃度を縦軸に取った対数直交座標において、前記ドナー濃度が、前記IV族元素の濃度の増加に応じて所定の傾斜を有した正比例直線に沿って増加されたβ−Ga2O3系単結晶基板、及び前記β−Ga2O3系単結晶基板上に形成されたGaN系エピタキシャル結晶膜を含む結晶積層構造体を提供する。【選択図】図1</description><subject>AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUSPOLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE</subject><subject>APPARATUS THEREFOR</subject><subject>BASIC ELECTRIC ELEMENTS</subject><subject>CHEMICAL SURFACE TREATMENT</subject><subject>CHEMISTRY</subject><subject>COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATIONOR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL</subject><subject>COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY IONIMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL</subject><subject>COATING MATERIAL WITH METALLIC MATERIAL</subject><subject>COATING METALLIC MATERIAL</subject><subject>CRYSTAL GROWTH</subject><subject>DIFFUSION TREATMENT OF METALLIC MATERIAL</subject><subject>ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR</subject><subject>ELECTRICITY</subject><subject>INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION INGENERAL</subject><subject>METALLURGY</subject><subject>PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE</subject><subject>REFINING BY ZONE-MELTING OF MATERIAL</subject><subject>SEMICONDUCTOR DEVICES</subject><subject>SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE</subject><subject>SINGLE-CRYSTAL-GROWTH</subject><subject>SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THESURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION</subject><subject>UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL ORUNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2014</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZHBxTzTyN1Zwcgx2dVEI9vRz93FVcA6KDA5x9FEIDnUKDglyDHFVcPRzgYv6OPp6-gEFgcpDgkKdQ0KDXHkYWNMSc4pTeaE0N4OSm2uIs4duakF-fGpxQWJyal5qSbxXgJGBoYmRoYG5gbmjMVGKAK49LEA</recordid><startdate>20141113</startdate><enddate>20141113</enddate><creator>UJIIE TAKEKAZU</creator><creator>YAMAOKA MASARU</creator><scope>EVB</scope></search><sort><creationdate>20141113</creationdate><title>Ga2O3 BASED SINGLE CRYSTAL SUBSTRATE AND CRYSTAL LAMINATED STRUCTURE</title><author>UJIIE TAKEKAZU ; YAMAOKA MASARU</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_JP2014210707A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; jpn</language><creationdate>2014</creationdate><topic>AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUSPOLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE</topic><topic>APPARATUS THEREFOR</topic><topic>BASIC ELECTRIC ELEMENTS</topic><topic>CHEMICAL SURFACE TREATMENT</topic><topic>CHEMISTRY</topic><topic>COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATIONOR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL</topic><topic>COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY IONIMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL</topic><topic>COATING MATERIAL WITH METALLIC MATERIAL</topic><topic>COATING METALLIC MATERIAL</topic><topic>CRYSTAL GROWTH</topic><topic>DIFFUSION TREATMENT OF METALLIC MATERIAL</topic><topic>ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR</topic><topic>ELECTRICITY</topic><topic>INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION INGENERAL</topic><topic>METALLURGY</topic><topic>PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE</topic><topic>REFINING BY ZONE-MELTING OF MATERIAL</topic><topic>SEMICONDUCTOR DEVICES</topic><topic>SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE</topic><topic>SINGLE-CRYSTAL-GROWTH</topic><topic>SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THESURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION</topic><topic>UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL ORUNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL</topic><toplevel>online_resources</toplevel><creatorcontrib>UJIIE TAKEKAZU</creatorcontrib><creatorcontrib>YAMAOKA MASARU</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>UJIIE TAKEKAZU</au><au>YAMAOKA MASARU</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Ga2O3 BASED SINGLE CRYSTAL SUBSTRATE AND CRYSTAL LAMINATED STRUCTURE</title><date>2014-11-13</date><risdate>2014</risdate><abstract>PROBLEM TO BE SOLVED: To provide a -GaObased single crystal substrate in which variation of donor concentration is suppressed under a reduction atmosphere or an inert gas atmosphere, and a crystal laminated structure capable of epitaxially growing a high quality crystal film having small variation in quality under the reduction atmosphere or the inert gas atmosphere.SOLUTION: The -GaObased single crystal substrate has a donor concentration corresponding to an added concentration of Si, Hf, Ge,Sn, Ti or Zr as an IV group element or an added concentration of two or more kinds of the IV group elements, the donor concentration increasing along a linear straight line having a predetermined inclination according to increase of the concentration of the IV group element in logarithm rectangular coordinates using the concentration of the IV group element as a horizontal axis and using the donor concentration as a vertical axis. The crystal laminated structure includes a GaN based epitaxial crystal film formed on the -GaObased single crystal substrate. 【課題】還元雰囲気や不活性ガス雰囲気下におけるドナー濃度の変化が抑えられたβ−Ga2O3系単結晶基板、及び還元雰囲気や不活性ガス雰囲気下において品質のばらつきの小さい高品質な結晶膜をエピタキシャル成長させることのできる結晶積層構造体を提供する。【解決手段】IV族元素としてのSi、Hf、Ge、Sn、Ti、あるいはZrが添加された濃度、あるいは2種以上の前記IV族元素が添加された濃度に応じたドナー濃度を有するβ−Ga2O3系単結晶基板であって、前記IV族元素の濃度を横軸に取り、前記ドナー濃度を縦軸に取った対数直交座標において、前記ドナー濃度が、前記IV族元素の濃度の増加に応じて所定の傾斜を有した正比例直線に沿って増加されたβ−Ga2O3系単結晶基板、及び前記β−Ga2O3系単結晶基板上に形成されたGaN系エピタキシャル結晶膜を含む結晶積層構造体を提供する。【選択図】図1</abstract><oa>free_for_read</oa></addata></record>
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subjects AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUSPOLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE
APPARATUS THEREFOR
BASIC ELECTRIC ELEMENTS
CHEMICAL SURFACE TREATMENT
CHEMISTRY
COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATIONOR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY IONIMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
COATING MATERIAL WITH METALLIC MATERIAL
COATING METALLIC MATERIAL
CRYSTAL GROWTH
DIFFUSION TREATMENT OF METALLIC MATERIAL
ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
ELECTRICITY
INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION INGENERAL
METALLURGY
PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE
REFINING BY ZONE-MELTING OF MATERIAL
SEMICONDUCTOR DEVICES
SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITHDEFINED STRUCTURE
SINGLE-CRYSTAL-GROWTH
SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THESURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION
UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL ORUNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL
title Ga2O3 BASED SINGLE CRYSTAL SUBSTRATE AND CRYSTAL LAMINATED STRUCTURE
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