ETHYLENE/alpha-OLEFIN/NON-CONJUGATED POLYENE COPOLYMER
PROBLEM TO BE SOLVED: To provide a process for producing an ethylene/α-olefin/non-conjugated polyene copolymer with high conversion of a non-conjugated polyene and good polymerization activity, whereby unreacted monomers and a hydrocarbon solvent can be removed from a solution containing the copolym...
Gespeichert in:
Hauptverfasser: | , , , , , |
---|---|
Format: | Patent |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext bestellen |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | |
container_start_page | |
container_title | |
container_volume | |
creator | SAITO JUNJI MATSUI NARIKAZU MATSUURA SADAHIKO MURAKAMI HIDETATSU USADA TAKAHIRO FUJITA TERUNORI |
description | PROBLEM TO BE SOLVED: To provide a process for producing an ethylene/α-olefin/non-conjugated polyene copolymer with high conversion of a non-conjugated polyene and good polymerization activity, whereby unreacted monomers and a hydrocarbon solvent can be removed from a solution containing the copolymer obtained by copolymerization using a transition metal compound catalyst in the hydrocarbon solvent without removing the residual catalyst. SOLUTION: The copolymer comprising ethylene, a 3-20C α-olefin and a norbornene skeleton-having non-conjugated polyene is produced by using the polymerization catalyst containing a transition metal compound composed of (A) a transition metal compound having a specific structure and (B) at least one compound selected from the following (B-1)-(B-3): (B-1) an organometallic compound, (B-2) an organic aluminum oxy compound and (B-3) a compound to form an ion pair by reacting with the transition metal compound (A). The copolymer is characterized by the followings: (i) the Mooney viscosity ML at 100°C is in a specific range, or the intrinsic viscosity [η] in decalin at 135°C is in a specific range; (ii) the content ratio of the ethylene, α-olefin and non-conjugated polyolefin is in a specific range; and (iii) the ethylene molar fraction, ethylene/α-olefin diad molar fraction, ethylene/non-conjugated polyene diad molar fraction, α-olefin molar fraction and non-conjugated polyene molar fraction satisfy a specific relation. COPYRIGHT: (C)2011,JPO&INPIT |
format | Patent |
fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_JP2011052231A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>JP2011052231A</sourcerecordid><originalsourceid>FETCH-epo_espacenet_JP2011052231A3</originalsourceid><addsrcrecordid>eNrjZDBzDfGI9HH1c9VPzCnISNT193F18_TT9_P303X29_MKdXcMcXVRCPD3iQSqUXD2B7F8XYN4GFjTEnOKU3mhNDeDkptriLOHbmpBfnxqcUFicmpeakm8V4CRgaGhgamRkbGhozFRigDWtSkx</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>ETHYLENE/alpha-OLEFIN/NON-CONJUGATED POLYENE COPOLYMER</title><source>esp@cenet</source><creator>SAITO JUNJI ; MATSUI NARIKAZU ; MATSUURA SADAHIKO ; MURAKAMI HIDETATSU ; USADA TAKAHIRO ; FUJITA TERUNORI</creator><creatorcontrib>SAITO JUNJI ; MATSUI NARIKAZU ; MATSUURA SADAHIKO ; MURAKAMI HIDETATSU ; USADA TAKAHIRO ; FUJITA TERUNORI</creatorcontrib><description>PROBLEM TO BE SOLVED: To provide a process for producing an ethylene/α-olefin/non-conjugated polyene copolymer with high conversion of a non-conjugated polyene and good polymerization activity, whereby unreacted monomers and a hydrocarbon solvent can be removed from a solution containing the copolymer obtained by copolymerization using a transition metal compound catalyst in the hydrocarbon solvent without removing the residual catalyst. SOLUTION: The copolymer comprising ethylene, a 3-20C α-olefin and a norbornene skeleton-having non-conjugated polyene is produced by using the polymerization catalyst containing a transition metal compound composed of (A) a transition metal compound having a specific structure and (B) at least one compound selected from the following (B-1)-(B-3): (B-1) an organometallic compound, (B-2) an organic aluminum oxy compound and (B-3) a compound to form an ion pair by reacting with the transition metal compound (A). The copolymer is characterized by the followings: (i) the Mooney viscosity ML at 100°C is in a specific range, or the intrinsic viscosity [η] in decalin at 135°C is in a specific range; (ii) the content ratio of the ethylene, α-olefin and non-conjugated polyolefin is in a specific range; and (iii) the ethylene molar fraction, ethylene/α-olefin diad molar fraction, ethylene/non-conjugated polyene diad molar fraction, α-olefin molar fraction and non-conjugated polyene molar fraction satisfy a specific relation. COPYRIGHT: (C)2011,JPO&INPIT</description><language>eng</language><subject>CHEMISTRY ; COMPOSITIONS BASED THEREON ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>2011</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20110317&DB=EPODOC&CC=JP&NR=2011052231A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20110317&DB=EPODOC&CC=JP&NR=2011052231A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>SAITO JUNJI</creatorcontrib><creatorcontrib>MATSUI NARIKAZU</creatorcontrib><creatorcontrib>MATSUURA SADAHIKO</creatorcontrib><creatorcontrib>MURAKAMI HIDETATSU</creatorcontrib><creatorcontrib>USADA TAKAHIRO</creatorcontrib><creatorcontrib>FUJITA TERUNORI</creatorcontrib><title>ETHYLENE/alpha-OLEFIN/NON-CONJUGATED POLYENE COPOLYMER</title><description>PROBLEM TO BE SOLVED: To provide a process for producing an ethylene/α-olefin/non-conjugated polyene copolymer with high conversion of a non-conjugated polyene and good polymerization activity, whereby unreacted monomers and a hydrocarbon solvent can be removed from a solution containing the copolymer obtained by copolymerization using a transition metal compound catalyst in the hydrocarbon solvent without removing the residual catalyst. SOLUTION: The copolymer comprising ethylene, a 3-20C α-olefin and a norbornene skeleton-having non-conjugated polyene is produced by using the polymerization catalyst containing a transition metal compound composed of (A) a transition metal compound having a specific structure and (B) at least one compound selected from the following (B-1)-(B-3): (B-1) an organometallic compound, (B-2) an organic aluminum oxy compound and (B-3) a compound to form an ion pair by reacting with the transition metal compound (A). The copolymer is characterized by the followings: (i) the Mooney viscosity ML at 100°C is in a specific range, or the intrinsic viscosity [η] in decalin at 135°C is in a specific range; (ii) the content ratio of the ethylene, α-olefin and non-conjugated polyolefin is in a specific range; and (iii) the ethylene molar fraction, ethylene/α-olefin diad molar fraction, ethylene/non-conjugated polyene diad molar fraction, α-olefin molar fraction and non-conjugated polyene molar fraction satisfy a specific relation. COPYRIGHT: (C)2011,JPO&INPIT</description><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2011</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZDBzDfGI9HH1c9VPzCnISNT193F18_TT9_P303X29_MKdXcMcXVRCPD3iQSqUXD2B7F8XYN4GFjTEnOKU3mhNDeDkptriLOHbmpBfnxqcUFicmpeakm8V4CRgaGhgamRkbGhozFRigDWtSkx</recordid><startdate>20110317</startdate><enddate>20110317</enddate><creator>SAITO JUNJI</creator><creator>MATSUI NARIKAZU</creator><creator>MATSUURA SADAHIKO</creator><creator>MURAKAMI HIDETATSU</creator><creator>USADA TAKAHIRO</creator><creator>FUJITA TERUNORI</creator><scope>EVB</scope></search><sort><creationdate>20110317</creationdate><title>ETHYLENE/alpha-OLEFIN/NON-CONJUGATED POLYENE COPOLYMER</title><author>SAITO JUNJI ; MATSUI NARIKAZU ; MATSUURA SADAHIKO ; MURAKAMI HIDETATSU ; USADA TAKAHIRO ; FUJITA TERUNORI</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_JP2011052231A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2011</creationdate><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>SAITO JUNJI</creatorcontrib><creatorcontrib>MATSUI NARIKAZU</creatorcontrib><creatorcontrib>MATSUURA SADAHIKO</creatorcontrib><creatorcontrib>MURAKAMI HIDETATSU</creatorcontrib><creatorcontrib>USADA TAKAHIRO</creatorcontrib><creatorcontrib>FUJITA TERUNORI</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>SAITO JUNJI</au><au>MATSUI NARIKAZU</au><au>MATSUURA SADAHIKO</au><au>MURAKAMI HIDETATSU</au><au>USADA TAKAHIRO</au><au>FUJITA TERUNORI</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>ETHYLENE/alpha-OLEFIN/NON-CONJUGATED POLYENE COPOLYMER</title><date>2011-03-17</date><risdate>2011</risdate><abstract>PROBLEM TO BE SOLVED: To provide a process for producing an ethylene/α-olefin/non-conjugated polyene copolymer with high conversion of a non-conjugated polyene and good polymerization activity, whereby unreacted monomers and a hydrocarbon solvent can be removed from a solution containing the copolymer obtained by copolymerization using a transition metal compound catalyst in the hydrocarbon solvent without removing the residual catalyst. SOLUTION: The copolymer comprising ethylene, a 3-20C α-olefin and a norbornene skeleton-having non-conjugated polyene is produced by using the polymerization catalyst containing a transition metal compound composed of (A) a transition metal compound having a specific structure and (B) at least one compound selected from the following (B-1)-(B-3): (B-1) an organometallic compound, (B-2) an organic aluminum oxy compound and (B-3) a compound to form an ion pair by reacting with the transition metal compound (A). The copolymer is characterized by the followings: (i) the Mooney viscosity ML at 100°C is in a specific range, or the intrinsic viscosity [η] in decalin at 135°C is in a specific range; (ii) the content ratio of the ethylene, α-olefin and non-conjugated polyolefin is in a specific range; and (iii) the ethylene molar fraction, ethylene/α-olefin diad molar fraction, ethylene/non-conjugated polyene diad molar fraction, α-olefin molar fraction and non-conjugated polyene molar fraction satisfy a specific relation. COPYRIGHT: (C)2011,JPO&INPIT</abstract><oa>free_for_read</oa></addata></record> |
fulltext | fulltext_linktorsrc |
identifier | |
ispartof | |
issn | |
language | eng |
recordid | cdi_epo_espacenet_JP2011052231A |
source | esp@cenet |
subjects | CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
title | ETHYLENE/alpha-OLEFIN/NON-CONJUGATED POLYENE COPOLYMER |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T07%3A11%3A15IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-epo_EVB&rft_val_fmt=info:ofi/fmt:kev:mtx:patent&rft.genre=patent&rft.au=SAITO%20JUNJI&rft.date=2011-03-17&rft_id=info:doi/&rft_dat=%3Cepo_EVB%3EJP2011052231A%3C/epo_EVB%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |