MULTILAYERED SHRINK FILM
PROBLEM TO BE SOLVED: To provide a multilayered shrink film in which a degree of shrinkage at normal temperature is controlled, and a degree of heat shrinkage (shrink ratio) is enhanced, and further feeling is good. SOLUTION: The film includes at least each one layer of a saponified ethylene-vinyles...
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creator | TANIGUCHI MASAHIKO TANABE TAKAMICHI |
description | PROBLEM TO BE SOLVED: To provide a multilayered shrink film in which a degree of shrinkage at normal temperature is controlled, and a degree of heat shrinkage (shrink ratio) is enhanced, and further feeling is good. SOLUTION: The film includes at least each one layer of a saponified ethylene-vinylester-based copolymer (A) layer having a structural unit expressed by general formula (1), and polyamide-based resin (B) layer containing a structural unit in which carbon numbers between amide bonds are 10-20. In a structural unit expressed by the general formula (1), R1-R6are each hydrogen atom or monovalent organic group, and may be same or different with each other. Especially, all of R1-R6are preferably hydrogen atoms from a point of copolymerization reactivity and industrial handleability of monomers in a production stage. However, at least a part of R1-R6may be organic groups, within the limits where a resin characteristic is not considerably damaged. As the organic group, a C1-4 alkyl group, e.g., methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, is preferable. X is preferably a single bond from a point of heat stability during production, a point of structural stability under a high temperature-acidity condition, a point of not excessively reducing crystallinity of EVOH, or the like. Wherein, that X is a single bond means that X per se is a bond. COPYRIGHT: (C)2010,JPO&INPIT |
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SOLUTION: The film includes at least each one layer of a saponified ethylene-vinylester-based copolymer (A) layer having a structural unit expressed by general formula (1), and polyamide-based resin (B) layer containing a structural unit in which carbon numbers between amide bonds are 10-20. In a structural unit expressed by the general formula (1), R1-R6are each hydrogen atom or monovalent organic group, and may be same or different with each other. Especially, all of R1-R6are preferably hydrogen atoms from a point of copolymerization reactivity and industrial handleability of monomers in a production stage. However, at least a part of R1-R6may be organic groups, within the limits where a resin characteristic is not considerably damaged. As the organic group, a C1-4 alkyl group, e.g., methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, is preferable. X is preferably a single bond from a point of heat stability during production, a point of structural stability under a high temperature-acidity condition, a point of not excessively reducing crystallinity of EVOH, or the like. Wherein, that X is a single bond means that X per se is a bond. 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SOLUTION: The film includes at least each one layer of a saponified ethylene-vinylester-based copolymer (A) layer having a structural unit expressed by general formula (1), and polyamide-based resin (B) layer containing a structural unit in which carbon numbers between amide bonds are 10-20. In a structural unit expressed by the general formula (1), R1-R6are each hydrogen atom or monovalent organic group, and may be same or different with each other. Especially, all of R1-R6are preferably hydrogen atoms from a point of copolymerization reactivity and industrial handleability of monomers in a production stage. However, at least a part of R1-R6may be organic groups, within the limits where a resin characteristic is not considerably damaged. As the organic group, a C1-4 alkyl group, e.g., methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, is preferable. X is preferably a single bond from a point of heat stability during production, a point of structural stability under a high temperature-acidity condition, a point of not excessively reducing crystallinity of EVOH, or the like. Wherein, that X is a single bond means that X per se is a bond. 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SOLUTION: The film includes at least each one layer of a saponified ethylene-vinylester-based copolymer (A) layer having a structural unit expressed by general formula (1), and polyamide-based resin (B) layer containing a structural unit in which carbon numbers between amide bonds are 10-20. In a structural unit expressed by the general formula (1), R1-R6are each hydrogen atom or monovalent organic group, and may be same or different with each other. Especially, all of R1-R6are preferably hydrogen atoms from a point of copolymerization reactivity and industrial handleability of monomers in a production stage. However, at least a part of R1-R6may be organic groups, within the limits where a resin characteristic is not considerably damaged. As the organic group, a C1-4 alkyl group, e.g., methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, is preferable. X is preferably a single bond from a point of heat stability during production, a point of structural stability under a high temperature-acidity condition, a point of not excessively reducing crystallinity of EVOH, or the like. Wherein, that X is a single bond means that X per se is a bond. COPYRIGHT: (C)2010,JPO&INPIT</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS,e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES,DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS CONVEYING HANDLING THIN OR FILAMENTARY MATERIAL LAYERED PRODUCTS LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT ORNON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM PACKAGES PACKAGING ELEMENTS PACKING PERFORMING OPERATIONS STORING TRANSPORTING |
title | MULTILAYERED SHRINK FILM |
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