NICKEL-HYDROGEN STORAGE BATTERY

PROBLEM TO BE SOLVED: To provide a nickel-hydrogen storage battery in which degradation of discharge capacity is low by suppressing elution of cobalt into an electrolytic solution and by suppressing elution of manganese into the electrolytic solution even if charge and discharge are repeated under h...

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Hauptverfasser: IMOTO TERUHIKO, MORIKAWA ARINORI
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MORIKAWA ARINORI
description PROBLEM TO BE SOLVED: To provide a nickel-hydrogen storage battery in which degradation of discharge capacity is low by suppressing elution of cobalt into an electrolytic solution and by suppressing elution of manganese into the electrolytic solution even if charge and discharge are repeated under high temperature atmosphere. SOLUTION: As for this nickel-hydrogen storage battery, either or both of W compound or Ta compound is added into the positive electrode active material which contains nickel hydroxide covered by Co compound as the main component in the positive electrode, and the negative electrode contains hydrogen storage alloy of CaCu5type expressed as MmNiaCobMncAld, and the sum of composition of Ni, Co, Mn, and Al (a+b+c+d) is 4.4 ≤ a+b+c+d ≤ 5.4, and composition of Mn (c) has a relationship of 0.05 ≤ c ≤ 0.2. By this, the elution of Co into the electrolytic solution is suppressed even if the charge and the discharge are repeated under the high temperatures, and collapse of electric conduction network can be prevented, thereby prevention of a situation becomes possible that the discharge capacity is degraded. COPYRIGHT: (C)2004,JPO
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SOLUTION: As for this nickel-hydrogen storage battery, either or both of W compound or Ta compound is added into the positive electrode active material which contains nickel hydroxide covered by Co compound as the main component in the positive electrode, and the negative electrode contains hydrogen storage alloy of CaCu5type expressed as MmNiaCobMncAld, and the sum of composition of Ni, Co, Mn, and Al (a+b+c+d) is 4.4 ≤ a+b+c+d ≤ 5.4, and composition of Mn (c) has a relationship of 0.05 ≤ c ≤ 0.2. By this, the elution of Co into the electrolytic solution is suppressed even if the charge and the discharge are repeated under the high temperatures, and collapse of electric conduction network can be prevented, thereby prevention of a situation becomes possible that the discharge capacity is degraded. 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SOLUTION: As for this nickel-hydrogen storage battery, either or both of W compound or Ta compound is added into the positive electrode active material which contains nickel hydroxide covered by Co compound as the main component in the positive electrode, and the negative electrode contains hydrogen storage alloy of CaCu5type expressed as MmNiaCobMncAld, and the sum of composition of Ni, Co, Mn, and Al (a+b+c+d) is 4.4 ≤ a+b+c+d ≤ 5.4, and composition of Mn (c) has a relationship of 0.05 ≤ c ≤ 0.2. By this, the elution of Co into the electrolytic solution is suppressed even if the charge and the discharge are repeated under the high temperatures, and collapse of electric conduction network can be prevented, thereby prevention of a situation becomes possible that the discharge capacity is degraded. 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SOLUTION: As for this nickel-hydrogen storage battery, either or both of W compound or Ta compound is added into the positive electrode active material which contains nickel hydroxide covered by Co compound as the main component in the positive electrode, and the negative electrode contains hydrogen storage alloy of CaCu5type expressed as MmNiaCobMncAld, and the sum of composition of Ni, Co, Mn, and Al (a+b+c+d) is 4.4 ≤ a+b+c+d ≤ 5.4, and composition of Mn (c) has a relationship of 0.05 ≤ c ≤ 0.2. By this, the elution of Co into the electrolytic solution is suppressed even if the charge and the discharge are repeated under the high temperatures, and collapse of electric conduction network can be prevented, thereby prevention of a situation becomes possible that the discharge capacity is degraded. COPYRIGHT: (C)2004,JPO</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects ALLOYS
BASIC ELECTRIC ELEMENTS
CHEMISTRY
ELECTRICITY
FERROUS OR NON-FERROUS ALLOYS
METALLURGY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
TREATMENT OF ALLOYS OR NON-FERROUS METALS
title NICKEL-HYDROGEN STORAGE BATTERY
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