FLUOROALKYL GROUP-CONTAINING PHOSPHINIC ACID ORIGOMER AND ITS PRODUCTION, AND ANTIMICROBIAL AGENT, SURFACTANT AND RESIN COMPOSITION EACH CONTAINING THE SAME

PROBLEM TO BE SOLVED: To obtain a new compound having excellent antimicrobial activity, water/oil-repelling properties and highly surface-active performance, and useful as an antimicrobial agent or surfactant. SOLUTION: This new compound is represented by formula I R1 and R2 are each a group (CF2)nY...

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Hauptverfasser: SUGIYA TADASHI, SAWADA HIDEO, INABA YOSHIKO, TATSUTANI EIICHI, HARA YOSHIFUSA
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creator SUGIYA TADASHI
SAWADA HIDEO
INABA YOSHIKO
TATSUTANI EIICHI
HARA YOSHIFUSA
description PROBLEM TO BE SOLVED: To obtain a new compound having excellent antimicrobial activity, water/oil-repelling properties and highly surface-active performance, and useful as an antimicrobial agent or surfactant. SOLUTION: This new compound is represented by formula I R1 and R2 are each a group (CF2)nY, or CF(CF3)-[OCF2CF(CF3)]p-OC3F7; Y is H, fluorine or chlorine; n is 1-10; p is 0-8; R3 and R4 are each H or methyl; R5 is a 1-18C alkyl; A is a group COOH or CON(R6)R7; R6 and R7 are each H or a 1-6C alkyl; Z is an alkylene; m is 1-1,000; the molar ratio a:b is (1:99) to (99:1)}. The compound of formula I is obtained by reaction between a compound of formula II (e.g. diperfluoro-2-methyl-3-oxahexanoyl peroxide), a compound of formula III [e.g. n-butyl(3-acryloyloxypropyl)phosphicinic acid] and a compound of formula IV (e.g. acrylic acid) pref. at 0-100 deg.C for 3-10 h.
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SOLUTION: This new compound is represented by formula I R1 and R2 are each a group (CF2)nY, or CF(CF3)-[OCF2CF(CF3)]p-OC3F7; Y is H, fluorine or chlorine; n is 1-10; p is 0-8; R3 and R4 are each H or methyl; R5 is a 1-18C alkyl; A is a group COOH or CON(R6)R7; R6 and R7 are each H or a 1-6C alkyl; Z is an alkylene; m is 1-1,000; the molar ratio a:b is (1:99) to (99:1)}. The compound of formula I is obtained by reaction between a compound of formula II (e.g. diperfluoro-2-methyl-3-oxahexanoyl peroxide), a compound of formula III [e.g. n-butyl(3-acryloyloxypropyl)phosphicinic acid] and a compound of formula IV (e.g. acrylic acid) pref. at 0-100 deg.C for 3-10 h.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
ADHESIVES
AGRICULTURE
ANIMAL HUSBANDRY
BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES
CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
DYES
FISHING
FORESTRY
HUMAN NECESSITIES
HUNTING
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
PEST REPELLANTS OR ATTRACTANTS
PLANT GROWTH REGULATORS
POLISHES
PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF
THEIR PREPARATION OR CHEMICAL WORKING-UP
TRAPPING
title FLUOROALKYL GROUP-CONTAINING PHOSPHINIC ACID ORIGOMER AND ITS PRODUCTION, AND ANTIMICROBIAL AGENT, SURFACTANT AND RESIN COMPOSITION EACH CONTAINING THE SAME
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