HYDROPHILIC SUPPORT MATERIAL FOR SOLID ELECTROLYTIC FILM

PROBLEM TO BE SOLVED: To reduce the electric resistance of a solid electrolytic film without damaging the mechanical strength of the film by constituting a support material for solid electrolytic film by use of a perfluorocarbon polymer system having a surface water contact angle of a specified valu...

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Hauptverfasser: OKUYAMA KAZUO, OSAKI AKIKO
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OSAKI AKIKO
description PROBLEM TO BE SOLVED: To reduce the electric resistance of a solid electrolytic film without damaging the mechanical strength of the film by constituting a support material for solid electrolytic film by use of a perfluorocarbon polymer system having a surface water contact angle of a specified value. SOLUTION: As a support material such as woven fabric or nonwoven fabric, a fluorinated compound having large electric negative degree and satisfactory heat resistance and solvent resistance by small atom diameter, particularly, a perfluorocarbon polymer system such as polytetrafluoroethylene having high strength and chemical inactivity is used. Its surface water contact angle is set to 0-90 deg. by a surface treatment, for example, corona discharge or plasma emission to improve the hydrophilicity. This support is embedded between layers to form a laminated film of two layers or more. It is firmly bonded to a fluorine-containing polymer having a functional group such as sulfonic group or carboxylic group to retain the mechanical strength, and the ion conductivity on the surface is enhanced because of the improvement in wettability with electrolyte and the retaining of an ion-exchange group. A temporary reinforcing member such as general fiber which is removable with any bad influence may added thereto.
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subjects BASIC ELECTRIC ELEMENTS
CABLES
CHEMISTRY
COMPOSITIONS BASED THEREON
CONDUCTORS
ELECTRICITY
INSULATORS
INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MEASURING
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PHYSICS
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING ORDIELECTRIC PROPERTIES
TESTING
THEIR PREPARATION OR CHEMICAL WORKING-UP
title HYDROPHILIC SUPPORT MATERIAL FOR SOLID ELECTROLYTIC FILM
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