PROCESS FOR SELECTIVE HYDROGENATION OF HYDROFORMYLATED MIXTURE

PROBLEM TO BE SOLVED: To selectively hydrogenate the reaction mixture from the hydroformylation of a specific olefin with a specific catalyst to sufficiently convert the specific accompanying substance to desired alcohols as much as possible and reduce the hydrogenation of unreacting olefins as litt...

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Hauptverfasser: SCHULER JOACHIM DR, SCHOLZ BERNHARD DR, BUESCHKEN WILFRIED DR, DROSTE WILHELM, KAIZIK ALFRED DR
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creator SCHULER JOACHIM DR
SCHOLZ BERNHARD DR
BUESCHKEN WILFRIED DR
DROSTE WILHELM
KAIZIK ALFRED DR
description PROBLEM TO BE SOLVED: To selectively hydrogenate the reaction mixture from the hydroformylation of a specific olefin with a specific catalyst to sufficiently convert the specific accompanying substance to desired alcohols as much as possible and reduce the hydrogenation of unreacting olefins as little as possible. SOLUTION: The reaction mixture resulting from the hydroformylation of a 5-24C olefin is catalytically hydrogenated by using a supported catalyst containing copper, nickel and chromium as active components [preferably containing 0.3-15 wt.%; of copper and nickel, respectively; 0.05-3.5 wt.% of chromium and 0.01-1.6 wt.% of an alkali metal component], preferably at 120-220 deg.C under a pressure of 5-30 bar, particularly at 140-180 deg.C under 15-25 bar.
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SOLUTION: The reaction mixture resulting from the hydroformylation of a 5-24C olefin is catalytically hydrogenated by using a supported catalyst containing copper, nickel and chromium as active components [preferably containing 0.3-15 wt.%; of copper and nickel, respectively; 0.05-3.5 wt.% of chromium and 0.01-1.6 wt.% of an alkali metal component], preferably at 120-220 deg.C under a pressure of 5-30 bar, particularly at 140-180 deg.C under 15-25 bar.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
CRACKING HYDROCARBON OILS
FUELS
GENERAL METHODS OF ORGANIC CHEMISTRY
LUBRICANTS
METALLURGY
MINERAL WAXES
ORGANIC CHEMISTRY
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR RELEVANT APPARATUS
TRANSPORTING
title PROCESS FOR SELECTIVE HYDROGENATION OF HYDROFORMYLATED MIXTURE
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