PROCESS FOR MAKING POLYAMINOPOLYPHENYL METHANES USING A MIXED SOLID ACID CATALYST SYSTEM

PROCESS FOR MAKING POLYAMINOPOLYPHENYL METHANES USING A MIXED SOLID ACID CATALYST SYSTEM

A method for preparing aromatic polyamines comprising (1) preparing a non-aqueous aminal solution; (2) contacting the non-aqueous aminal solution and an acidic siliceous catalyst to form a benzylamine intermediate; (3) contacting the benzylamine intermediate and an ion exchange resin catalyst based...

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Hauptverfasser: CHEN, Lao-Jer, JIMENEZ, Jorge
Format: Patent
Sprache:eng ; hun
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CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
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creator CHEN, Lao-Jer
JIMENEZ, Jorge
description A method for preparing aromatic polyamines comprising (1) preparing a non-aqueous aminal solution; (2) contacting the non-aqueous aminal solution and an acidic siliceous catalyst to form a benzylamine intermediate; (3) contacting the benzylamine intermediate and an ion exchange resin catalyst based on a styrene-divinylbenzene copolymer to form an aromatic polyamine reaction mixture containing a polyaminopolyphenyl methane product; and (4) recovering the polyaminopolyphenyl methane product from the aromatic polyamine reaction mixture. The method, which may be practiced continuously, offers high 4,4′-methylene dianiline yield, reduced impurities, extended catalyst life, and, therefore, improved economics, when compared with many conventional methods to prepare polyaminopolyphenyl methanes.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title PROCESS FOR MAKING POLYAMINOPOLYPHENYL METHANES USING A MIXED SOLID ACID CATALYST SYSTEM
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