Procedure for the photochlorination of alkyl-aromatic compounds

An alkyl-aromatic compound is selectively photochlorinated in the side chain in a cyclic reaction system wherein said compound is continuously circulated between a container (1) and photochlorination reactor (2). The compound is partially chlorinated after each passage through the photochlorination...

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Hauptverfasser: RIBALDO, CARLO, MESSORI, VITTORIO, CONTARDI, GIUSEPPE
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creator RIBALDO, CARLO
MESSORI, VITTORIO
CONTARDI, GIUSEPPE
description An alkyl-aromatic compound is selectively photochlorinated in the side chain in a cyclic reaction system wherein said compound is continuously circulated between a container (1) and photochlorination reactor (2). The compound is partially chlorinated after each passage through the photochlorination reactor (2), the number of passages depending on the degree of chlorination required. The procedure is particularly useful for the preparation of benzyl chloride, benzal chloride and benzotrichloride, and the corresponding halogen-substituted derivatives of the nucleus.
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The compound is partially chlorinated after each passage through the photochlorination reactor (2), the number of passages depending on the degree of chlorination required. 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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Procedure for the photochlorination of alkyl-aromatic compounds
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